Chemistry of the Main Group Elements (Barron)
- Page ID
- 212608
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)The main group (s- and p-block) elements are among the most diverse in the Periodic Table. Ranging from non-metallic gases (e.g., hydrogen and fluorine), through semi-metals (e.g., metalloids such as silicon) to highly reactive metals (e.g., sodium and potassium). The study of the main group elements is important for a number of reasons. On an academic level they exemplify the trends and predictions in structure and reactivity that are the key to the Periodic Table. They represent the diversity of inorganic chemistry, and the fundamental aspects of structure and bonding that are also present for the transition metal, lanthanide and actinide elements.
- 1: General Concepts and Trends
- 1.1: Fundamental Properties - Oxidation State
- 1.2: Fundamental Properties - Ionization Energy
- 1.3: Fundamental Properties - Electron Affinity
- 1.4: Fundamental Properties - Electronegativity
- 1.5: Structure and Bonding - Valence Shell Electron Pair Repulsion (VSEPR) Theory
- 1.6: Structure and Bonding - Crystal Structure
- 1.7: Structure and Bonding - Stereochemistry
- 1.8: Acids, Bases, and Solvents - Choosing a Solvent
- 1.9: Chemical Reactivity - The Basics of Combustion
- 1.10: Periodic Trends for the Main Group Elements
- 6: Group 13
- 6.1: The Group 13 Elements
- 6.2: Trends for the Group 13 Compounds
- 6.3: Borides
- 6.4: Boron Hydrides
- 6.5: Wade’s Rules
- 6.6: Trends for the Oxides of the Group 13 Elements
- 6.7: Boron Oxides, Hydroxides, and Oxyanions
- 6.8: Aluminum Oxides, Hydroxides, and Hydrated Oxides
- 6.9: Ceramic Processing of Alumina
- 6.10: Boron Compounds with Nitrogen Donors
- 6.11: Properties of Gallium Arsenide
- 6.12: Electronic Grade Gallium Arsenide
- 6.13: Chalcogenides of Aluminum, Gallium, and Indium
- 6.14: Group 13 Halides
- 7: Group 14
- 7.1: The Group 14 Elements
- 7.2: Carbon Black- From Copying to Communication
- 7.3: Carbon Nanomaterials
- 7.4: Nitrogen Compounds of Carbon
- 7.5: Carbon Monoxide
- 7.6: Carbon Dioxide
- 7.7: Suboxides of Carbon
- 7.8: Carbon Halides
- 7.9: Comparison Between Silicon and Carbon
- 7.10: Semiconductor Grade Silicon
- 7.11: Oxidation of Silicon
- 7.12: Applications for Silica Thin Films