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Structure of Organic Molecules

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    Here you will learn how to understand, write, draw, and talk-the-talk of organic molecules. Why were different drawing techniques developed? Organic molecules can get complicated and large. It is a tedious to have to constantly draw out every detail, especially when not necessary, so the o-chemist of the past developed these techniques to make it more convenient and easy. In addition, some of these shorthand ways of drawing molecules give us insight into the bond angles, relative positions of atoms in the molecule, and some eliminate the numerous hydrogens that can get in the way of looking at the backbone of the structure.


    Observe the following drawings of the structure of Retinol, the most common form of vitamin A. The first drawing follows the straight-line (a.k.a. Kekulé) structure which is helpful when you want to look at every single atom; however, showing all of the hydrogen atoms makes it difficult to compare the overall structure with other similar molecules and makes it difficult to focus in on the double bonds and OH group.

    vitamin A kekule.jpg

    Retinol: Kekulé straight-line drawing

    The following is a bond-line (a.k.a. zig-zag) formula for retinol. With this simiplified representation, one can easily see the carbon-carbon bonds, double bonds, OH group, and CH3 groups sticking off of the the main ring and chain. Also, it is much quicker to draw this than the one above. You will learn to appreciate this type of formula writing after drawing a countless number of organic molecules.

    vitamin A zig zag.jpg

    Retinol: Bond-line or zig-zag formula

    Importance of Structure

    Learning and practicing the basics of Organic Chemistry will help you immensely in the long run as you learn new concepts and reactions. Some people say that Organic Chemistry is like another language, and in some aspects, it is. At first it may seem difficult or overwhelming, but the more you practice looking at and drawing organic molecules, the more familiar you will become with the structures and formulas. Another good idea is to get a model kit and physically make the molecules that you have trouble picturing in your head.

    Through general chemistry, you may have already experienced looking at molecular structure. The different ways to draw organic molecules include Kekulé (straight-line), Condensed Formulas, and Bond-Line Formulas (zig-zag). It will be more helpful if you become comfortable going from one style of drawing to another, and look at drawings and understanding what they mean, than knowing which kind of drawing is named what.

    An example of a drawing that incorporates all three ways to draw organic molecules would be the following additional drawing of Retinol. The majority of the drawing is Bond-line (zig-zag) formula, but the -CH3 are written as condensed formulas, and the -OH group is written in Kekulé form.


    A widely used way of showing the 3D structure of molecules is the use of dashes, wedges, and straight lines. This drawing method is essential because the placement of different atoms could yield different molecules even if the molecular formulas were exactly the same. Below are two drawings of a 4-carbon molecule with two chlorines and two bromines attached.

    stick1.jpg stick2.jpg

    4-carbon molecule with 2 chlorines and 2 bromines 4-carbon molecule with 2 chlorines and 2 bromines

    Both drawings look like they represent the same molecule; however, if we add dashes and wedged we will see that two different molecules could be depicted:


    The two molecules above are different, prove this to yourself by building a model. An easier way to compare the two molecules is to rotate one of the bonds (here, it is the bond on the right):

    dashwedge2 (1).jpg

    Notice how the molecule on the right has both bromines on the same side and chlorines on the same side, whereas the first molecule is different. Read about Dashed-Wedged Line structures, bottom of page, to understand what has been introduced above. You will learn more about the importance of atomic connectivity in molecules as you continue on to learn about Stereochemistry.

    Drawing the Structure of Organic Molecules

    Although larger molecules may look complicated, they can be easily understood by breaking them down and looking at their smaller components.

    All atoms want to have their valence shell full, a "closed shell." Hydrogen wants to have 2 e- whereas carbon, oxygen, and nitrogen want to have 8 e-. When looking at the different representations of molecules, keep in mind the Octet Rule. Also remember that hydrogen can bond one time, oxygen can bond up to two times, nitrogen can bond up to three times, and carbon can bond up to four times.

    possible bonds (1).jpg

    Kekulé (a.k.a. Straight-Line Structures)

    Kekulé structures are similar to Lewis Structures, but instead of covalent bonds being represented by electron dots, the two shared electrons are shown by a line.

    (A) A kekule.jpg(B)B kekule.jpg(C)C kekule.jpg

    Lone pairs remain as two electron dots, or are sometimes left out even though they are still there. Notice how the three lone pairs of electrons were not draw in around chlorine in example B.

    Condensed Formulas

    A condensed formula is made up of the elemental symbols. The order of the atoms suggests the connectivity. Condensed formulas can be read from either direction and H3C is the same as CH3, although the latter is more common because Look at the examples below and match them with their identical molecule under Kekulé structures and bond-line formulas.


    Let's look closely at example B. As you go through a condensed formula, you want to focus on the carbons and other elements that aren't hydrogen. The hydrogen's are important, but are usually there to complete octets. Also, notice the -OCH3 is in written in parentheses which tell you that it not part of the main chain of carbons. As you read through a a condensed formula, if you reach an atom that doesn't have a complete octet by the time you reach the next hydrogen, then it's possible that there are double or triple bonds. In example C, the carbon is double bonded to oxygen and single bonded to another oxygen. Notice how COOH means C(=O)-O-H instead of CH3-C-O-O-H because carbon does not have a complete octet and oxygens.

    Bond-Line (a.k.a. zig-zag) Formulas

    The name gives away how this formula works. This formula is full of bonds and lines, and because of the typical (more stable) bonds that atoms tend to make in molecules, they often end up looking like zig-zag lines. If you work with a molecular model kit you will find it difficult to make stick straight molecules (unless they contain sp triple bonds) whereas zig-zag molecules and bonds are much more feasible.

    (A) A zig zag.jpg (B)B zig zag.jpg (C)C zig zag.jpg

    These molecules correspond to the exact same molecules depicted for Kekulé structures and condensed formulas. Notice how the carbons are no longer drawn in and are replaced by the ends and bends of a lines. In addition, the hydrogens have been omitted, but could be easily drawn in (see practice problems). Although we do not usually draw in the H's that are bonded to carbon, we do draw them in if they are connected to other atoms besides carbon (example is the OH group above in example A) . This is done because it is not always clear if the non-carbon atom is surrounded by lone pairs or hydrogens. Also in example A, notice how the OH is drawn with a bond to the second carbon, but it does not mean that there is a third carbon at the end of that bond/ line.

    Dashed-Wedged Line Structure

    As you may have guessed, the Dashed-Wedged Line structure is all about lines, dashes, and wedges. At first it may seem confusing, but with practice, understanding dash-wedged line structures will become like second nature. The following are examples of each, and how they can be used together.


    Above are 4-carbon chains with attached OH groups or Cl and Br atoms. Remember that each line represents a bond and that the carbons and hydrogens have been omitted. When you look at or draw these structures, the straight lines illustrate atoms and bonds that are in the same plane, the plane of the paper (in this case, computer screen). Dashed lines show atoms and bonds that go into the page, behind the plane, away from you. In the above example, the OH group is going into the plane, while at the same time a hydrogen comes out (wedged).


    Blue bead= OH group; White bead=H

    Wedged lines illustrate bonds and atoms that come out of the page, in front of the plane, toward you. In the 2D diagram above, the OH group is coming out of the plane of the paper, while a hydrogen goes in (dashed).


    Blue bead= OH group; White bead=H

    As stated before, straight lines illustrate atoms and bonds that are in the same plane as the paper, but in the 2D example, the straight line bond for OH means that it it unsure or irrelevant whether OH is going away or toward you. It is also assumed that hydrogen is also connected to the same carbon that OH is on.


    Blue bead= OH group; H is not shown

    Try using your model kit to see that the OH group cannot lie in the same plane at the carbon chain (don't forget your hydrogens!). In the final 2Dexample, both dashed and wedged lines are used because the attached atoms are not hydrogens (although dashed and wedged lines can be used for hydrogens).The chlorine is coming out the page while bromine is going into the page.


    Blue bead=Cl; Red bead=Br

    Practice Problems

    1. How many carbons are in the following drawing? How many hydrogens?
      prob 1q.jpg
    2. How many carbons are in the following drawing? How many hydrogens?
      prob 2q.jpg
    3. How many carbons are in the following drawing? How many hydrogens?
      prob 3q.jpg
    4. Look at the following molecule of vitamin A and draw in the hidden hydrogens and electron pairs.
      vitamin C zig zag.jpg
      (hint: Do all of the carbons have 4 bonds? Do all the oxygens have a full octet?)
    5. How many bonds can hydrogen make?
    6. How many bonds can chlorine make?
    7. Dashed lines means the atomic bond goes ___________(away/toward) you.
    8. Draw ClCH2CH2CH(OCH3)CH3 in Kekuléand zig-zag form.
    9. Extra practice problems can be found ______?


    1. Remember the octet rule and how many times carbons and hydrogens are able to bond to other atoms.
      prob 1a.jpg

    2. prob 2a (1).jpg

    3. prob 3a (1).jpg
    4. Electron pairs drawn in blue and hydrogens draw in red.
      vitamine C zig zag ans.jpg
    5. Hygrogen can make one bond.
    6. Chlorine can make one bond.
    7. Away
    8. See (B) under Kekulé and Bond-line (zig-zag) formulas.
    9. Extra practice problems can be found: in your textbook, homework, lecture notes, online, reference books, and more. Try making up some of your own molecules, they may exist!


    1. Vollhardt, K. Peter C., and Neil E. Schore. Organic Chemistry: Structure and Function. 5th ed. New York: W. H. Freeman Company, 2007. 38-40.
    2. Klein, David R. Organic Chemistry I As a Second Language. 2nd ed. Hoboken, NJ: John Wiley & Sons, Inc, 2007. 1-14.


    • Choo, Ezen (2009, UCD '11)

    Structure of Organic Molecules is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.

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