4: Covalent Bonding and Simple Molecular Compounds
- Page ID
- 15923
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)
\( \newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\)
( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\)
\( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)
\( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\)
\( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)
\( \newcommand{\Span}{\mathrm{span}}\)
\( \newcommand{\id}{\mathrm{id}}\)
\( \newcommand{\Span}{\mathrm{span}}\)
\( \newcommand{\kernel}{\mathrm{null}\,}\)
\( \newcommand{\range}{\mathrm{range}\,}\)
\( \newcommand{\RealPart}{\mathrm{Re}}\)
\( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)
\( \newcommand{\Argument}{\mathrm{Arg}}\)
\( \newcommand{\norm}[1]{\| #1 \|}\)
\( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)
\( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\AA}{\unicode[.8,0]{x212B}}\)
\( \newcommand{\vectorA}[1]{\vec{#1}} % arrow\)
\( \newcommand{\vectorAt}[1]{\vec{\text{#1}}} % arrow\)
\( \newcommand{\vectorB}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vectorC}[1]{\textbf{#1}} \)
\( \newcommand{\vectorD}[1]{\overrightarrow{#1}} \)
\( \newcommand{\vectorDt}[1]{\overrightarrow{\text{#1}}} \)
\( \newcommand{\vectE}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{\mathbf {#1}}}} \)
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)
\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Ionic bonding results from the transfer of electrons among atoms or groups of atoms. In this chapter, we will consider another type of bonding—covalent bonding. We will examine how atoms share electrons to form these bonds, and we will begin to explore how the resulting compounds, such as cholesterol, are different from ionic compounds.
- 4.0: Prelude to Covalent Bonding and Simple Molecular Compounds
- This page discusses cholesterol, a necessary substance for animal cell membranes and hormone production, produced by the liver. It highlights the dangers of excessive cholesterol intake from animal products, leading to heart disease risks. Recommendations include a low-cholesterol diet and medical interventions like blood tests and medications to manage cholesterol levels effectively.
- 4.1: Covalent Bonds
- This page explains covalent bonding and the octet rule, highlighting the difference between covalent and ionic bonds. It uses examples like H2 and F2 to demonstrate electron sharing for stable valence shells and includes Lewis diagrams for visual aid. The text also addresses exceptions to the octet rule, particularly regarding hydrogen and transition elements, using examples like OF2 and NCl3 to illustrate bond counting and octet conformity.
- 4.2: Covalent Compounds - Formulas and Names
- This page explains the differences between covalent and ionic compounds, detailing bond formation, polyatomic ion structure, and characteristics like melting points and conductivity. It also discusses naming conventions for simple covalent compounds, highlighting specific examples such as water, ammonia, and methane, while noting the distinct nomenclature system for organic compounds. The content emphasizes the relationship between a compound's name and its chemical formula.
- 4.3: Drawing Lewis Structures
- This page details the process for creating Lewis structures and recognizing molecules with multiple covalent bonds. It offers a step-by-step guide that includes calculating valence electrons, atom arrangement, and electron distribution to satisfy the octet rule. Examples like OF2, HCN, and CO2 demonstrate these principles.
- 4.4: Characteristics of Covalent Bonds
- This page covers covalent bond characteristics, emphasizing bond length, polarity, and electronegativity. It explains how bond lengths vary with bond type and strength, decreasing with increased strength. Electronegativity measures an atom's electron attraction, classifying bonds as nonpolar, polar, or ionic based on differences in electronegativity (EN). The overall molecular polarity results from bond polarity and geometry, impacting properties like boiling points.
- 4.5: Characteristics of Molecules
- This page explains molecular mass, shape, and polarity of covalent molecules, emphasizing molecular mass calculation and VSEPR theory for determining molecular geometry. It highlights that a molecule is polar if polar bonds do not cancel, using water as an example of polarity due to its bent shape, in contrast to nonpolar CO2 and BF3.
- 4.6: Organic Chemistry
- This page covers organic chemistry, emphasizing carbon compounds and their bonding properties, including hydrocarbons and functional groups like hydroxyl and carboxyl. It explains how these factors affect molecule reactivity and health. Additionally, it addresses the role of forensic chemists, who analyze materials and testify in court, requiring effective communication and a solid chemistry foundation.
- 4.E: Covalent Bonding and Simple Molecular Compounds (Exercises)
- This page offers a comprehensive overview of covalent bonds, their formation, and their role in satisfying the octet rule, including exercises on Lewis diagrams and naming covalent compounds. It also covers bond lengths, electronegativity, and organic chemistry fundamentals, highlighting key concepts and providing exercises for molecular mass calculations and identifying functional groups.
- 4.S: Covalent Bonding and Simple Molecular Compounds (Summary)
- This page explains covalent bonds formed by atoms sharing valence electrons, leading to full valence shells. It defines molecules and their molecular formulas, describes bond types (single, double, triple), and distinguishes between polar and nonpolar covalent bonds based on electron sharing. The molecular mass is the total of atomic masses. Additionally, it highlights organic chemistry's focus on carbon compounds, including hydrocarbons and functional groups like alcohols and carboxylic acids.