7: Acid and Base Equilibria
- Page ID
- 221507
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)- 7.1: Arrhenius Acids and Bases
- An Arrhenius acid is a compound that increases the H+ ion concentration in aqueous solution. An Arrhenius base is a compound that increases the OH− ion concentration in aqueous solution. The reaction between an Arrhenius acid and an Arrhenius base is called neutralization and results in the formation of water and a salt.
- 7.2: Brønsted-Lowry Acids and Bases
- A Brønsted-Lowry acid is a proton donor; a Brønsted-Lowry base is a proton acceptor. Acid-base reactions include two sets of conjugate acid-base pairs.
- 7.3: Names and Formulas of Acids
- An acid can be defined in several ways. The most straightforward definition is that an acid is a molecular compound that contains one or more hydrogen atoms and produces hydrogen ions when dissolved in water.
- 7.4: Names and Formulas of Bases
- Bases can also be defined in several ways. The most common type of bases are compounds that contain one or more hydroxide ions. Some other bases do not contain hydroxide, but they accept H+.
- 7.5: Autoionization of Water
- In any aqueous solution at room temperature, the product of \([H^+]\) and \([OH^−]\) equals \(1.0 \times 10^{−14}\).
- 7.6: The pH and pOH Scales
- pH is a logarithmic function of [H+]. [H+] can be calculated directly from pH. pOH is related to pH and can be easily calculated from pH.
- 7.14: Calculating pH of Strong Acid and Base Solutions
- Acids and bases that are completely ionized when dissolved in water are called strong acids and strong bases There are only a few strong acids and bases, and everyone should know their names and properties. These acids are often used in industry and everyday life. The concentrations of acids and bases are often expressed in terms of pH, and as an educated person, you should have the skill to convert concentrations into pH and pOH. The pH is an indication of the hydrogen ion concentration, [H+].
- 7.16: Polyprotic Acids
- An acid that contains more than one ionizable proton is a polyprotic acid. The protons of these acids ionize in steps. The differences in the acid ionization constants for the successive ionizations of the protons in a polyprotic acid usually vary by roughly five orders of magnitude. As long as the difference between the successive values of Ka of the acid is significant, it is a good estimation to only consider the first dissociation constant to calculate pH
- 7.23: Buffers
- A buffer is a solution that resists sudden changes in pH.
- 7.24: Calculating pH of Buffer Solutions- Henderson-Hasselbalch equation
- Buffers allow chemists to maintain a specific pH range for a reaction. Buffers utilize conjugate acid-base pairs to function. Read on to learn more about the specifics and calculations of buffers.