15.7: Modern Applications of Laser Spectroscopy
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A Quick Overview
Laser light offers valuable tools to researchers who wish to use the interaction of light with matter to interrogate atomic and molecular systems. Most laser light is characterized by its near monochromaticity (relative to light from other sources), directionality, and coherence . Those characteristics are used in modern laser spectroscopy. The monochromaticity of laser light allows it to be used to probe specific energy changes in atoms and molecules. This ability to select specific wavelengths allows scientists to focus on chosen components in mixtures, including complex reaction mixtures. For example, Park et. al. tracked the dynamics of the reaction of ground state oxygen with ethyl radical by using a 355 nm laser beam to track one of the products of this reaction . Parsons et. al. used near monochromatic laser light sources to achieve state-selective ionization for the study of the products of a photodissociation reaction of atmospheric relevance . Laser monochromaticity can be used to quantify the amount of greenhouse gases in the atmosphere . Even when the samples are not mixtures, monochromaticity allows researchers to gather detailed information about atomic and/or molecular structure. Applications of this type are extremely numerous, including detailed studies of atomic systems , semiconductor materials , single molecules , and biological molecules . Lasers find research applications in art and archeology, where the property of monochromaticity allows specific energies to be probed and laser beam directionality and small spot size curtail destruction of samples [9,10].
Other laser applications focus on the ability of pulsed lasers to provide short pulses. Short-pulsed lasers offer myriad tools for exploring chemical kinetics at a range of timescales, including very short ones. Short-pulse lasers open the opportunity for time-resolved studies of molecular processes such as reaction processes [2,11] and biological processes [12 - 15], and the properties of excited states . Some research applications take advantage of the ability of certain lasers to produce high intensity light. One such application is laser-induced break down spectroscopy (LIBS), in which the high intensity of the laser creates a plasma from solid or liquid samples; that plasma can subsequently be probed . Other techniques that exploit high laser intensities are the nonlinear spectroscopies, where the high intensities of some lasers can produce behaviors in samples that lower-power sources cannot sufficiently stimulate [18,19]. Although most lasers are monochromatic and coherent, some researchers have modified laser light to obtain information from broadband, incoherent laser light [20 – 22], which allows them to probe the response of samples to light that more resembles sunlight (incoherent) than do traditional laser sources [22, 23]. Another possibility is to probe multiple wavelengths with broadband laser sources that are coherent .
This brief overview has only skimmed the surface of the vast field of laser spectroscopy. The examples given here are a very small, somewhat arbitrary, and significantly biased subset of the enormous library of published laser-based experiments. References have been chosen to give examples of the topics covered here and have not been extensively reviewed by the author.
Overall, lasers are especially useful as light sources when one or more of the following properties are desired for light in an experiment:
- A high degree of monochromaticity
- A well-known central wavelength for a light source
- A tunable light source
- Spatial coherence
- Phase coherence
- High intensity
- Tight focus
- Short pulses
A particular laser type will not necessarily have all the properties in the list above; however, the menu of available laser types allows a researcher to choose a laser system or systems with the characteristics needed for a particular experiment. New applications of laser spectroscopy and new spectroscopic techniques employing laser light continue to be invented.
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Stephanie Schaertel (Grand Valley State University)
(Thank you to Tom Neils (Grand Rapids Community College) for editing the references)