2: Reaction Kinetics
- Page ID
- 401758
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- In this chapter, we will expand on the concepts of chemical reaction rates by exploring what the rate law implies about the mechanistic pathways that reactions actually follow to proceed from reactants to products. Typically, one determines a rate law that describes a chemical reaction, and then suggests a mechanism that can be (or might not be!) consistent with the observed kinetics.
- 2.3.1: A Mechanism is a Sequence of Elementary Reactions
- 2.3.2: The Principle of Detailed Balance
- 2.3.3: Multiple Mechanisms are often Indistinguishable
- 2.3.4: The Steady-State Approximation
- 2.3.5: Rate Laws Do Not Imply Unique Mechanism
- 2.3.6: The Lindemann Mechanism
- 2.3.7: Some Reaction Mechanisms Involve Chain Reactions
- 2.3.8: A Catalyst Affects the Mechanism and Activation Energy
- 2.3.9: The Michaelis-Menten Mechanism for Enzyme Catalysis
- 2.3.10: Predicting Rate Laws from Proposed Mechanisms
- 2.3.E: Chemical Kinetics II- Reaction Mechanisms (Exercises)