11: Combined Problems 1
- Page ID
- 332811
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Combined Spectral Problems: IR, 13C & 1H*
* All spectra are either from SDBS (Japan National Institute of Advanced Industrial Science and Technology) or simulated.
- Propose structures for the following problems. Use the tables on the following pages to show your work.
A. C6H12O2
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
B. C5H10O2
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
C. C6H12O2
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
D. C5H8O4
Note: OH peaks are not showing up in 1H-NMR because they have been exchanged with the solvent.
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
E. C4H6O2
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
F. C7H14O2
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
G. C9H12
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
H. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
I. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
J. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
K. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
L. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |
M. C10H12O
MF: DU:
Frequency | Functional Group |
---|---|
Chemical Shift | Type of Bonding Environment |
---|---|
Chemical Shift | Integration | Multiplicity | Interpretation |
---|---|---|---|
Proposed Structure: |