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- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/17%3A_Boltzmann_Factor_and_Partition_Functions/17.E%3A_Boltzmann_Factor_and_Partition_Functions_(Exercises)This page presents a series of homework problems from Chapter 17 of "Physical Chemistry: A Molecular Approach," focusing on energy, heat capacity, and partition functions for various gas models, inclu...This page presents a series of homework problems from Chapter 17 of "Physical Chemistry: A Molecular Approach," focusing on energy, heat capacity, and partition functions for various gas models, including ideal and van der Waals gases. It details derivations for pressure and molar heat capacity through partition function evaluations.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/15%3A_Lasers_Laser_Spectroscopy_and_Photochemistry/15.E%3A_Lasers_Laser_Spectroscopy_and_Photochemistry_(Exercises)This page includes summaries of exercises from Chapter 15 of McQuarrie and Simon's "Physical Chemistry," covering topics like Einstein coefficients and atomic transitions. It encompasses calculations ...This page includes summaries of exercises from Chapter 15 of McQuarrie and Simon's "Physical Chemistry," covering topics like Einstein coefficients and atomic transitions. It encompasses calculations related to laser pulses, including radiant power, energy per pulse, and photon output for lasers of various wavelengths.
- https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Introductory_Chemistry_(CK-12)/01%3A_Introduction_to_Chemistry/1.04%3A_Areas_of_ChemistryThis page outlines the five main disciplines of modern chemistry: Physical, Organic, Inorganic, Analytical, and Biochemistry. It explains that Physical chemistry investigates both macroscopic and micr...This page outlines the five main disciplines of modern chemistry: Physical, Organic, Inorganic, Analytical, and Biochemistry. It explains that Physical chemistry investigates both macroscopic and microscopic properties, while Organic chemistry centers on carbon compounds. Inorganic chemistry focuses on non-carbon compounds, Analytical chemistry studies matter composition, and Biochemistry explores chemical processes in living organisms.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/13%3A_Molecular_SpectroscopyThis page discusses spectroscopy, focusing on its role in understanding electromagnetic radiation's interaction with atoms and molecules. It covers aspects including vibrational, rotational transition...This page discusses spectroscopy, focusing on its role in understanding electromagnetic radiation's interaction with atoms and molecules. It covers aspects including vibrational, rotational transitions, and electronic spectra, highlighting principles such as the Franck-Condon Principle and selection rules. Group theory is mentioned for its predictive power in IR and Raman activity, while the characteristics of molecular spectra are linked to factors like normal modes and rotational inertia.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/zz%3A_Back_Matter
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(Fleming)/06%3A_Putting_the_Second_Law_to_Work/6.08%3A_The_Difference_between_Cp_and_CvThe document explains the derivation of an expression for the difference between constant pressure and constant volume heat capacities (C_p - C_V). It begins by defining these capacities in terms of e...The document explains the derivation of an expression for the difference between constant pressure and constant volume heat capacities (C_p - C_V). It begins by defining these capacities in terms of enthalpy (H) and internal energy (U), then manipulates these definitions using the properties of various thermodynamic quantities (??, ?????, etc.).
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/16%3A_The_Properties_of_Gases/16.E%3A_The_Properties_of_Gases_(Exercises)This page covers homework exercises from Chapter 16 of McQuarrie and Simon's "Physical Chemistry," focusing on calculations involving gas mixtures, ideal gas laws, and various equations of state like ...This page covers homework exercises from Chapter 16 of McQuarrie and Simon's "Physical Chemistry," focusing on calculations involving gas mixtures, ideal gas laws, and various equations of state like van der Waals and Redlich-Kwong. It includes problems on gas behavior, critical properties, and the application of the Newton-Raphson method for solving cubic equations.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/13%3A_Molecular_Spectroscopy/13.E%3A_Molecular_Spectroscopy_(Exercises)This page outlines Chapter 13 homework exercises from McQuarrie and Simon's "Physical Chemistry," focusing on molecular spectroscopy involving diatomic molecules. It covers vibrational energy levels, ...This page outlines Chapter 13 homework exercises from McQuarrie and Simon's "Physical Chemistry," focusing on molecular spectroscopy involving diatomic molecules. It covers vibrational energy levels, dissociation energies, and practical calculations for molecules like H2, Na2, and O2. Key concepts include the harmonic oscillator model, anharmonicity, and moments of inertia, illustrating how molecular structure affects rotational dynamics.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(Fleming)/07%3A_Mixtures_and_Solutions/7.02%3A_Partial_Molar_VolumeThe page discusses the concept of partial molar volume in a mixture of two compounds, A and B. It explains how the change in volume for the mixture can be described using the total differential and by...The page discusses the concept of partial molar volume in a mixture of two compounds, A and B. It explains how the change in volume for the mixture can be described using the total differential and by integrating terms related to each component's amount and partial molar volume.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/14%3A_Nuclear_Magnetic_Resonance_Spectroscopy/14.E%3A_Nuclear_Magnetic_Resonance_Spectroscopy_(Exercises)This page includes exercises on magnetic dipole moments, nuclear spin operators, and their relationships to angular momentum. It covers quantum mechanics principles for a two-spin system, including He...This page includes exercises on magnetic dipole moments, nuclear spin operators, and their relationships to angular momentum. It covers quantum mechanics principles for a two-spin system, including Hermitian operators, energy corrections, resonance frequencies, and orthogonality of spin states. The text derives equations for energy differences, highlighting the influence of spin states on energy levels.
- https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Physical_Chemistry_(LibreTexts)/18%3A_Partition_Functions_and_Ideal_Gases/18.E%3A_Partition_Functions_and_Ideal_Gases_(Exercises)This page features homework exercises from Chapter 18 of "Physical Chemistry: A Molecular Approach" by McQuarrie and Simon. Key topics include spin degeneracy of nuclei, thermodynamic functions from p...This page features homework exercises from Chapter 18 of "Physical Chemistry: A Molecular Approach" by McQuarrie and Simon. Key topics include spin degeneracy of nuclei, thermodynamic functions from partition functions, calculations for diatomic and polyatomic molecules, equilibrium constants for chemical reactions, and the impacts of anharmonicity and centrifugal distortion on molecular energy. It also addresses the fraction of atoms in excited states at different temperatures.
