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Chemistry LibreTexts

19.08: Nuclear Reactors

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    178269
  • A nuclear reactor is a device in which nuclear reactions are generated, and the chain reaction is controlled to release large amount of steady heat, thereby producing energy.

    Introduction

    Nuclear fission is the process in which the nucleus of an atom is split, forming nuclei of lighter atoms and neutrons. The mass of these products is less than the original mass. According to Einstein's equation \(E=mc^2\), the small amount of missing mass is converted into a large amount of energy.

    Figure 1: http://www.atomicarchive.com/Fission/Fission1.shtml

    A chain reaction, shown in the above figure, occurs when the neutrons released in fission collide with at least one other nuclei, causing the fission of another nuclei. The process then repeats. In today's nuclear reactors, Uranium-235 is commonly used. During each U235/92 fission, 2.5 neutrons are released on average. Note here; Uranium 235 is used because it has a fairly large nucleus which facilitates the process of fission. An explosion could only occur if the reaction becomes uncontrolled. When one mass of U-235 exceeds the mass of U-235 that is large enough to hold down a chain reaction, also known as critical mass, an explosion occurs. A great example of this phenomenon would be a nuclear bomb. In uncontrolled reactions, neutrons escape too quickly to maintain a chain reaction. This rapid release of nuclear energy causes an explosion. However, in a nuclear reactor, energy is being produced at a controlled, constant rate; a nuclear explosion is unlikely to occur.


    reacctor.jpg

    Figure 3

    The opposite of a nuclear explosion, nuclear reactors are the controlled release of fission energy. They serve the purpose of converting “nuclear energy” to heat. To produce energy, a nuclear reactor contains several major components: fuel elements (or rods), control rods, and coolant/moderator, besides the vessel itself containing everything. The fuel elements contains the fissile material, typically uranium or plutonium, which is used as the fuel to undergo fission and provide the nuclear energy. The fissile material is encased in a solid cladding, made of Zircalloy (alloy of zirconium, having low capacity to absorb neutrons), to contain both the fuel and the resulting fission products and keep then from escaping into the moderator, coolant, or anywhere outside the cladding. The moderator and coolant flows between the fuel elements (or rods) moderating the neutrons and carrying away the heat. The region inside the nuclear reactor where the fuel elements undergo fission to generate heat is called the nuclear reactor core. The control rods, usually made of cadmium metal, absorb neutrons in order to control the rate of fission. By raising or lowering the control rods in the reactor, the concentration of neutrons, called the neutron flux, in the core increases or decreases respectively. The other component is the coolant. Since the process of fission produces large amounts of heat, the coolant is used to carry away the heat. The heat carried away causes incoming cooler water to turn into steam. This steam spins a turbine, which then powers an electric generator. Generally speaking, water is used, however; helium gas and liquid sodium can be used as substitutes. A pressurized water reactor (PWR) is a common design of a nuclear reactor. In a PWR, water functions as a coolant and as a moderator. A moderator slows down the neutrons, because slower moving neutrons are better at causing fission to occur. A moderator is usually water; however, graphite and heavy water can also be used. A boiling water reactor (BWR) is another common design of current nuclear reactor plants in commercial use. In a BWR, water also functions as both a coolant and moderator. Another type of reactor used in civilian power plants in the former Soviet Union called an RBMK reactor used graphite (carbon) as a moderator, but is considered insufficiently safe.

    Most of the power from nuclear fission reactors comes directly from the fission, which can be rapidly stopped by a shutdown of the reactor. However, about 7% comes from heat of decay of highly radioactive fission products, which cannot be stopped by shutting down the reactor, and must continue to be removed from the reactor to prevent overheating and damage to the reactor core. Therefore, coolant pumps must continue to be run for many hours after the reactor is shutdown to remove the decay heat, which over the course of hours eventually decreases. If the coolant pumps do not work, emergency cooling methods must be used to remove decay heat to prevent damage to the core, possible meltdown or release of highly radioactive fission products to where they should not be.

    Nuclear Safety

    There have been three major accidents involving full-scale civilian nuclear power plants.

    • The first occurred in 1979 at Three Mile Island Unit 2 in Pennsylvania. Due mechanical failure, the main water pumps stopped running, leading to a partial meltdown of the fuel rods. Excessive heat caused a fracture in one of the reactors, allowing a small amount of radioactive steam into the atmosphere. Fortunately, no one was killed or even injured. This incident also lead to heightened regulation and safety precautions of nuclear reactors in the United States.
    • On April 26, 1986, the worst accident in nuclear history occurred in Chernobyl, Ukraine. During a routine test, an uncontrollable power surge burned the control rods, and massive amounts of radioactive smoke were released. 237 people suffered from acute radiation sickness, and 31 died within the first three months of the accident. Other effects of the radiation included an increase in down's syndrome, chromosomal aberrations, neural tube defects, and thyroid cancer. Perhaps the most important effect was psychological as the accident caused severe anxiety for the survivors and a general lack of trust in the government.

    chernobyl.jpgchernobyl2.jpg

    • Due to a severe earthquake and tsunami in Japan in March 11, 2011, several BWR (Boiling Water Reactor) nuclear reactors at the Fukushima power plant lost electrical power for cooling, underwent explosions, and suffered reactor core damage from post-shutdown decay heat coming from highly radioactive fission products. Workers eventually pumped seawater into the reactors to cool them down and limit any further damage.

    Problems

    1. What is the function of control rods in a nuclear reactor?
    2. True or False? The accident at Three Mile Island led to the radiation poisoning of possibly hundreds of thousands of people.
    3. How does nuclear fission lead to a chain reaction?
    4. What two functions can water serve in a nuclear reactor?
    5. What is critical mass? What will occur if the mass of a reaction surpasses its critical mass?

    Answers

    1. In a fission reactor, control rods absorb neutrons to control the rate of a reaction. Lowering the rods into the reactor decreases the rate of fission and removing them increases the rate.
    2. False. The accident at Three Mile Island was only minor and no one was killed or injured.
    3. When a neutron strikes a fissile material breaking it into smaller fragments, more neutrons are released (2.5 on average). These neutrons then collide with other fissile atoms producing even more neutrons, which continue the chain reaction either in a stable manner (reactor) or violently (atomic bomb).
    4. In a fission reactor, water serves as a moderator (slows down highly energetic neutrons to the appropriate thermal energy for a reaction) and produces steam by coming into contact with the hot water near the reactor and transferring heat. This steam can then power turbines to generate electricity.
    5. The critical mass of a fission reactor is the mass of fissile material required to maintain a chain reaction. If the mass of a reaction surpasses its critical mass, the result is an uncontrolled chain reaction that culminates in a large explosion (this is how an atomic bomb works).

    Breeder Reactors

    Because \(\ce{_{92}^{235}U}\) is only 0.7 percent of naturally occurring uranium, its supply is fairly limited and could well only last for about 50 years of full-scale use. The other 99 percent of the uranium can also be utilized if it is first converted into plutonium by neutron bombardment:

    \[\ce{_{92}^{238}U + _{0}^{1}n -> _{94}^{239}Pu + 2 _{-1}^{0} e}\]

    \(\ce{_{94}^{239}Pu}\) is also fissionable, and so it could be used in a nuclear reactor as well as \(\ce{_{92}^{235}U}\).

    The production of plutonium can be carried out in a breeder reactor which not only produces energy like other reactors but is designed to allow some of the fast neutrons to bombard the \(\ce{_{92}^{235}U}\), producing plutonium at the same time. More fuel is then produced than is consumed.

    Breeder reactors present additional safety hazards to those already outlined. They operate at higher temperatures and use very reactive liquid metals such as sodium in their cooling systems, and so the possibility of a serious accident is higher. In addition the large quantities of plutonium which would be produced in a breeder economy would have to be carefully safeguarded. Plutonium is an α emitter and is very dangerous if taken internally. Its half-life is 24,000 years, and so it will remain in the environment for a long time if dispersed. Moreover, \(\ce{_{94}^{239} Pu}\) can be separated chemically (not by the much more expensive gaseous diffusion used to concentrate \(\ce{_{92}^{ 235}U}\) from fission products and used to make bombs. Such a material will obviously be attractive to terrorist groups, as well as to countries which are not currently capable of producing their own atomic weapons.

    Contributors

    References

    1. Petrucci, Ralph H., et al. “Nuclear Reactors.” General Chemistry: Principles & Modern Applications. New Jersey: Pearson Education, Inc, 2007. 1057-1058.
    2. Bloomfield, Louis A. How Things Work: The Physics of Everyday Life, Second Edition. New York: John Wiley&Sons Inc, 2001. 445.
    3. AJ Software & Multimedia. Nuclear Fission: Basics. 1998-2008. <http://www.atomicarchive.com/Fission/Fission1.shtml>. United States Nuclear Regulatory Commission. Backgrounder on the Three Mile Island Accident. 11 August 2009. 29 November 2009 <http://www.nrc.gov/reading-rm/doc-co...mile-isle.html>.
    4. World Nuclear Association. Chernobyl Accident. November 2009. 2009 November 2009 <http://www.world-nuclear.org/info/ch...byl/inf07.html>.
    5. International Thermonuclear Experimental Reactor (ITER). "What is Fusion?" November 22 2010. Web. 26 May 2011.
    6. Nuclear Power Education. "Everything You Want to Know about Nuclear Power." September 3 2010. Web. 26 May 2011.

    Contributors

    • Anna Becker (UCD)
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