8: Further Reactions of Haloalkanes: Unimolecular Substitution and Pathways of Elimination Last updated Save as PDF Page ID201156 An organic chemistry Textmap organized around the textbook Organic Chemistry by Peter Vollhardt and Neil Schore 8.1: Solvolysis of Tertiary and Secondary Haloalkanes8.2: Unimolecular Nucleophilic Substitution8.3: Stereochemical Consequences of SN1 Reactions8.4: Effects of Solvent, Leaving Group, and Nucleophile on Unimolecular Substitution8.5: Effect of the Alkyl Group on the SN 1 Reaction: Carbocation Stability8.6: Unimolecular Elimination: E18.7: Bimolecular Elimination: E28.8: Keys to Success: Substitution Versus Elimination-Structure Determines Function8.9: Summary of Reactivity of Haloalkanes8.E: Further Reactions of Haloalkanes: Unimolecular Substitution (Exercises)