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Chemistry LibreTexts

Acid/Base Reactions

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An acid–base reaction is a chemical reaction that occurs between an acid and a base. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called acid–base theories, for example, Brønsted–Lowry acid–base theory. Their importance becomes apparent in analyzing acid–base reactions for gaseous or liquid species, or when acid or base character may be somewhat less apparent.

  • Hydrolysis
    When weak acids and bases react, the relative strength of the conjugated acid-base pair in the salt determines the pH of its solutions. The salt, or its solution, so formed can be acidic, neutral or basic. A salt formed between a strong acid and a weak base is an acid salt.
  • Neutralization
    A neutralization reaction is when an acid and a base react to form water and a salt and involves the combination of H+ ions and OH- ions to generate water. The neutralization of a strong acid and strong base has a pH equal to 7. The neutralization of a strong acid and weak base will have a pH of less than 7, and conversely, the resulting pH when a strong base neutralizes a weak acid will be greater than 7.
  • Predicting the Direction of Acid/Base Reactions
    The ability to predict the outcomes of acid-base reactions, which are very common in chemistry, is extremely beneficial. Many different things can change the outcome of an acid-base reaction including heat and pressure. Knowing the Ka (acid dissociation constant) and the Kb (base association constant) is the best way to predict the direction of an Acid-Base Reaction.
  • The Fall of the Proton - Viewing Acid/Base Chemistry from a Thermodynamic Perspective
    An acid, being a proton donor, can only act as an acid if there is a suitable base present to accept the proton. What do we mean by "suitable'' in this context? Simply that a base, in order to accept a proton, must provide a lower-energy resting place for the proton.  Thus you can view an acid-base reaction as the "fall" of the proton from a higher potential energy to a lower potential energy-- the same as a book will fall only downward, to a position of lower (gravitational) potential energy.
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Thumbnail: Warning picture used with dangerous acids and dangerous bases. Bases are the opposites of acids. (Public Domain).


Acid/Base Reactions is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.

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