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13.S: Unsaturated and Aromatic Hydrocarbons (Summary)

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    16061
    • Anonymous
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    To ensure that you understand the material in this chapter, you should review the meanings of the bold terms in the following summary and ask yourself how they relate to the topics in the chapter.

    Any hydrocarbon containing either a double or triple bond is an unsaturated hydrocarbon. Alkenes have a carbon-to-carbon double bond. The general formula for alkenes with one double bond is CnH2n. Alkenes can be straight chain, branched chain, or cyclic. Simple alkenes often have common names, but all alkenes can be named by the system of the International Union of Pure and Applied Chemistry.

    Cis-trans isomers (or geometric isomers) are characterized by molecules that differ only in their configuration around a rigid part of the structure, such as a carbon–to-carbon double bond or a ring. The molecule having two identical (or closely related) atoms or groups on the same side is the cis isomer; the one having the two groups on opposite sides is the trans isomer.

    The physical properties of alkenes are quite similar to those of alkanes. Like other hydrocarbons, alkenes are insoluble in water but soluble in organic solvents.

    More reactive than alkanes, alkenes undergo addition reactions across the double bond:

    • Addition of hydrogen (hydrogenation):

    CH2=CH2 + H2 → CH3CH3

    • Addition of halogen (halogenation):

    CH2=CH2 + X2XCH2CH2X

    where X = F, Cl, Br, or I.

    • Addition of water (hydration):

    CH2=CH2 + HOH → HCH2CH2OH

    Alkenes also undergo addition polymerization, molecules joining together to form long-chain molecules.

    …CH2=CH2 + CH2=CH2 + CH2=CH2 +…→…CH2CH2–CH2CH2–CH2CH2–…

    The reactant units are monomers, and the product is a polymer.

    Alkynes have a carbon-to-carbon triple bond. The general formula for alkynes is CnH2n − 2. The properties of alkynes are quite similar to those of alkenes. They are named much like alkenes but with the ending -yne.

    The cyclic hydrocarbon benzene (C6H6) has a ring of carbon atoms. The molecule seems to be unsaturated, but it does not undergo the typical reactions expected of alkenes. The electrons that might be fixed in three double bonds are instead delocalized over all six carbon atoms.

    A hydrocarbon containing one or more benzene rings (or other similarly stable electron arrangements) is an aromatic hydrocarbon, and any related substance is an aromatic compound. One or more of the hydrogen atoms on a benzene ring can be replaced by other atoms. When two hydrogen atoms are replaced, the product name is based on the relative position of the replacement atoms (or atom groups). A 1,2-disubstituted benzene is designated as an ortho (o-) isomer; 1,3-, a meta (m-) isomer; and 1,4-, a para (p-) isomer. An aromatic group as a substituent is called an aryl group.

    A polycyclic aromatic hydrocarbon (PAH) has fused benzene rings sharing a common side.


    This page titled 13.S: Unsaturated and Aromatic Hydrocarbons (Summary) is shared under a CC BY-NC-SA 3.0 license and was authored, remixed, and/or curated by Anonymous via source content that was edited to the style and standards of the LibreTexts platform.