12: Thermodynamic Processes and Thermochemistry
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This chapter introduces you to thermochemistry, a branch of chemistry that describes the energy changes that occur during chemical reactions. In some situations, the energy produced by chemical reactions is actually of greater interest to chemists than the material products of the reaction. For example, the controlled combustion of organic molecules, primarily sugars and fats, within our cells provides the energy for physical activity, thought, and other complex chemical transformations that occur in our bodies. Similarly, our energy-intensive society extracts energy from the combustion of fossil fuels, such as coal, petroleum, and natural gas, to manufacture clothing and furniture, heat your home in winter and cool it in summer, and power the car or bus that gets you to class and to the movies.
- 12.1: Systems, States, and Processes
- All forms of energy can be interconverted. Three things can change the energy of an object: the transfer of heat, work performed on or by an object, or some combination of heat and work.
- 12.2: The First Law of Thermodynamics - Internal Energy, Work, and Heat
- Heat is the amount of energy that is transferred from one system to its surroundings because of a temperature difference.
- 12.3: Heat Capacity, Enthalpy, and Calorimetry
- Hess's law is that the overall enthalpy change for a series of reactions is the sum of the enthalpy changes for the individual reactions. For a chemical reaction, the enthalpy of reaction (ΔH) is the difference in enthalpy between products and reactants; the units of ΔHrxn are kilojoules per mole. Reversing a chemical reaction reverses the sign of ΔH.
- 12.E: Thermodynamic Processes (Exercises)
- These are homework exercises to accompany the Textmap created for "Principles of Modern Chemistry" by Oxtoby et al. Complementary General Chemistry question banks can be found for other Textmaps and can be accessed here. In addition to these publicly available questions, access to private problems bank for use in exams and homework is available to faculty only on an individual basis; please contact Delmar Larsen for an account with access permission.