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- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Analytical_Chemistry_2.1_(Harvey)/16%3A_Appendix/16.12%3A_Formation_ConstantsThe page contains a table of stability constants for various metal-ligand complexes, categorized by different ligands such as acetate, ammonia, chloride, etc. The data, sourced from Martell and Smith'...The page contains a table of stability constants for various metal-ligand complexes, categorized by different ligands such as acetate, ammonia, chloride, etc. The data, sourced from Martell and Smith's "Critical Stability Constants," provides values at 25 ??C and zero ionic strength, though deviations are noted for certain entries. The constants are represented in logarithmic form, indicating the strength of interaction between metal ions like Cu, Ni, Ag, etc.
- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Analytical_Chemistry_2.1_(Harvey)/06%3A_Equilibrium_Chemistry/6.06%3A_Ladder_DiagramsThe page discusses the importance of considering chemical interactions, like pH and solubility, when developing or evaluating analytical methods. It critiques the inappropriate use of NH3 in precipita...The page discusses the importance of considering chemical interactions, like pH and solubility, when developing or evaluating analytical methods. It critiques the inappropriate use of NH3 in precipitating AgCl due to its solubility-increasing effect. Key analytical errors often stem from overlooking chemical interferences. Ladder diagrams are introduced as tools for visualizing equilibrium chemistry, aiding in understanding reaction dynamics and evaluating changes in solution conditions.
- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Analytical_Chemistry_2.1_(Harvey)/06%3A_Equilibrium_Chemistry/6.04%3A_Equilibrium_Constants_for_Chemical_ReactionsThe document provides an in-depth overview of several essential chemical reactions relevant to analytical chemistry, such as precipitation, acid-base, complexation, and oxidation-reduction (redox) rea...The document provides an in-depth overview of several essential chemical reactions relevant to analytical chemistry, such as precipitation, acid-base, complexation, and oxidation-reduction (redox) reactions. It explains the concepts of equilibrium constants like Ksp for precipitation reactions, Ka and Kb for acid-base reactions, and Kf for complexation reactions. The text discusses strong and weak acids and bases, amphiprotic species, the dissociation of water, and the pH scale.
