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- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/19%3A_Organometallic_Bonding_(Epic_Ligand_Survey)/19.07%3A_Metal_HydridesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/06%3A_Catalysis/6.04%3A_Survey_of_Organometallic_Ligands/6.4.03%3A_Hydrides_and_Dihydrogen_ComplexesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
- https://chem.libretexts.org/Courses/Earlham_College/CHEM_361%3A_Inorganic_Chemistry_(Watson)/06%3A_Organometallic_Chemistry/6.02%3A_Synthesis_and_Stability/6.2.03%3A_Metal_HydridesMetal hydrides occupy an important place in transition metal organometallic chemistry as the M−H bonds can undergo insertion reactions with a variety of unsaturated organic substrates yielding numerou...Metal hydrides occupy an important place in transition metal organometallic chemistry as the M−H bonds can undergo insertion reactions with a variety of unsaturated organic substrates yielding numerous organometallic compounds with M−C bonds. Not only the metal hydrides are needed as synthetic reagents for preparing the transition metal organometallic compounds but they also are required for important hydride insertion steps in many catalytic processes.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/02%3A_Organometallic_Ligands/2.06%3A_Metal_HydridesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Introduction_to_Organometallic_Chemistry_(Ghosh_and_Balakrishna)/07%3A_Metal_Alkyls_and_Metal_Hydrides/7.02%3A_Metal_HydridesMetal hydrides occupy an important place in transition metal organometallic chemistry as the M−H bonds can undergo insertion reactions with a variety of unsaturated organic substrates yielding numerou...Metal hydrides occupy an important place in transition metal organometallic chemistry as the M−H bonds can undergo insertion reactions with a variety of unsaturated organic substrates yielding numerous organometallic compounds with M−C bonds. Not only the metal hydrides are needed as synthetic reagents for preparing the transition metal organometallic compounds but they also are required for important hydride insertion steps in many catalytic processes.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.01%3A_Survey_of_Organometallic_Ligands/10.2.1.03%3A_Hydrides_and_Dihydrogen_ComplexesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.04%3A_Survey_of_Organometallic_Ligands/6.4.03%3A_Hydrides_and_Dihydrogen_ComplexesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/13%3A_Organometallic_Chemistry/13.04%3A_Survey_of_Organometallic_Ligands/13.4.03%3A_Hydrides_and_Dihydrogen_ComplexesMetal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polari...Metal-hydrogen bonds are ubiquitous X-type ligands in organometallic chemistry. There is much more than meets the eye to most M-H bonds: although they’re simple to draw, they vary enormously in polarization and pKa. They may be acidic or hydridic or both, depending on the nature of the metal center and the reaction conditions. In this post, we’ll develop some heuristics for predicting the behavior of M-H bonds and discuss their major modes of reactivity.
