Agenda
- Page ID
- 59630
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)First Semester
FIRST UNIT: ATOMIC STRUCTURE
FIRST WEEK
First Lecture: Mathematical review, units significant figures
SI units length: Mass, time, temperature, derived units: Volume, density
Uncertainty in measurement
Units and dimensional analysis (Factor label method)
Second Lecture: Discovery of the atom
Old atomic theory
Dalton’s atomic theory
Some comments on historical basis
Atomic symbols
The role of models in science
Structure of the atom
Electron properties
Rutherford model
Nuclear structure
Protons, neutrons Isotopes
SECOND WEEK
Third Lecture: Quantum theory of the atom
Wave nature of light
Relationship between wavelength and frequency
Planck’s quantization of energy
Black body problem
Photoelectric effect
Bohr theory of the hydrogen atom
Atomic line spectra
Bohr’s postulates
Transitions between energy levels
Quantum mechanics
de Broglie relation
Uncertainty principle
Wave function
Fourth Lecture: Wave functions
Quantum numbers and atomic orbitals
Atomic orbital shapes
Pauli exclusion principle
THIRD WEEK
Fifth Lecture: Electron configurations
Electron configurations
Sixth Lecture: Periodic Table
Historical development of the periodic table
Electron configuration and the Periodic Table
Effective nuclear charge
Size of Atoms and Ions
Ionization energy
Electron affinity
FOURTH WEEK
Seventh Lecture: Periodic properties
Metals, Non Metals and Metalloids
Group trends for groups 1 and 2
Group trends for non metals
Review
FIRST TEST
SECOND UNIT: Molecular Bonding
FIFTH WEEK
Eighth Lecture: Chemical bonding
Chemical bonds,
Lewis symbols and the octet rule
Ionic bonding
Covalent bonding
Bond polarity and negativity
Ninth Lecture: Lewis structures
Drawing Lewis structure
Resonance structures
SIXTH WEEK
Tenth Lecture: More bonding structures
Exceptions to the Octet Rule
Strengths of Covalent Bonds
Eleventh Lecture: Molecular Geometry
Molecular Shapes
The VSEPR model
Molecular shape and molecular polarity
SEVENTH WEEK
Twelfth Lecture: Covalent bonding
Covalent bonding and orbital overlap
Hybrid orbitals
Multiple Bonds
Thirteenth Lecture: Molecular Orbitals
Molecular orbitals
Review
SECOND TEST
THIRD UNIT: Descriptive Chemistry
EIGHTH WEEK
Fourteenth Lecture: States of matter
States of matter
Physical state and chemical composition
Solids, liquids and gases
Elements, compounds and mixtures
Properties of Matter
Fifteenth Lecture: Nomenclature
Chemical formulae
Molecular formula
Ions, cation, anion
Ionic compounds, empirical formulas
Binary ionic compound nomenclature - prefixes
Stock system
Traditional system
Polyatomic ions, ite, ate, hypo, per
Acids, Hydrates
Simple Organic Compounds
Nomenclature assignment for Spring Break
TENTH WEEK
Sixteenth Lecture: Calculations with Chemical Formulas and Equations
Chemical equations
Patterns of reactivity
Formula weights
Why do we need the concept of formula weight?
Mole concept (bridge between atomic and human scales)
Mole calculation moles to grams, grams to moles
Empirical formulas
ELEVENTH WEEK
Seventeenth and Eighteenth Lecture: Stolichiometry
Combining chemical equations and the mole concept
Limiting reactants
Theoretical yield
TWELFTH WEEK
Nineteenth Lecture: Aqueous reactions and solution stoichiometry
Aqueous solutions and the properties of water Electrolytes, solubility rules
Precipitation reactions
Acid-Base reactions
Oxidation-Reduction Reactions
Twentieth Lecture: Solutions
Concentration of solutions
Writing reactions in molecular/ionic forms
Complete ionic reactions Net ionic reactions
Review
THIRD TEST
FOURTH UNIT: Thermochemistry
THIRTEENTH WEEK
Twenty-first Lecture: Thermochemistry
The nature of energy Kinetic and potential energy Internal energy Heat (Thermal energy)
First Law of Thermodynamics
Enthalpy
Calorimetry
FOURTEENTH WEEK
Twenty-second Lecture: Enthalpy of reaction
Enthalpy of reaction
Hess’s Law
Enthaply of Formation
Twenty-third Lecture: Gases
Characteristics of gases
Pressure and units of pressure
Gas Laws
Ideal gas equation
FIFTEENTH WEEK
Twenty-fourth Lecture: Gases
Stoichiometry and the ideal gas law
Gas Mixtures and partial pressures
Real gases
Twenty-fifth Lecture: Statistical mechanics
Kinetic theory of gases
Molecular effusion and diffusion
Review
FINAL
SECOND SEMESTER
First lecture: Chapter 11 States of Matter
Properties of liquids, surface tension and viscosity
Intermolecular forces
Phase transitions
Phase diagrams and cooling curve
SECOND WEEK
Second lecture: Chapter 11 Liquids
Third lecture: Chapter 11 Solids
Classifications of solids by intermolecular forces
Crystal lattices and Unit Cells
Crystal Structure
THIRD WEEK
Fourth lecture: Chapter 12 Solutions
Types of solutions
Effects of temperature and pressure on solubility
Concentration units
Fifth Lecture: Chapter 12 Colligative properties
Vapor pressure of a solution
Boiling point elevation/Freezing point depression
FIRST TEST
FOURTH WEEK
Sixth Lecture: Chapter 14 Chemical Kinetics
Definition of reaction rate
Experimental determination of the rate of reaction
Dependence of rate on concentration
Seventh Lecture: Chapter 14 Change of concentration with time
Change of concentration with time
Temperature and rate, collision and transition state theories
Arrhenius equation
FIFTH WEEK
Eighth Lecture: Chapter 14 Reaction Mechanisms
Elementary reactions
Rate laws and mechanisms
Ninth Lecture: Chapter 15 Chemical equilibrium
The nature of the chemical equilibrium
The equilibrium constant
Heterogeneous equilibria
Qualitative interpretation of the equilibrium constant
SIXTH WEEK
Tenth Lecture: Chapter 15 Using the equilibrium constant
Predicting the direction of reaction
Calculating equilibrium constant
Eleventh Lecture: Chapter 15 LeChatelier’s principle
Removing or adding reactants
What happens when pressure or temperature change
Effect of a catalyst.
SECOND TEST
SEVENTH WEEK
Twelfth Lecture: Chapter 16 Concepts of acids and bases
Arrhenius concept of acids and bases
Bronsted Lowry concept of acids and bases
Lewis concept of acids and bases
Relative strengths of acids and bases
Molecular basis of acid/base strength
Thirteenth Lecture: Chapter 17 pH
Self ionization of water
Solutions of strong acids and bases
The pH of a solution
EIGHTH WEEK
Fourteenth Lecture: Chapter 17 Solutions of weak acids
Acid ionization equilibria
Polyprotic acids
Fifteenth Lecture: Chapter 17 Solutions of weak bases
Base ionization equilibria
Acid base properties of a salt solution
NINTH WEEK
Sixteenth Lecture: Chapter 17 Common ion effect and buffers
Common ion effect
Acid-base titration.
Seventeenth Lecture: Chapter 18
The solubility product
Solubility and the common ion effect
Precipitation calculations
TEST 3
TENTH WEEK
Eighteenth Lecture: Chapter 19 The laws of thermodynamics
The first law and enthalpy
Entropy and the second law of thermodynamics
Standard entropies and the third law of thermodynamics
Nineteenth Lecture: Chapter 19 Free energy
Free energy and spontaneity
Interpretations of free energy
ELEVETH WEEK
Twentieth Lecture: Chapter 19 Free energy and equilibrium
Relating DGo to the equilibrium constant
Change of free energy with temperature
Twenty first Lecture: Chapter 20 Oxidation-reduction reactions
Balancing oxidation reduction reactions in acidic and basic solutions
TWELFTH WEEK
Twenty second Lecture: Chapter 20 Voltaic cells
Construction of Voltaic Cells
Notation for voltaic cells
Electromotive force
Twenty third Lecture: Chapter 20 Voltaic cells
Standard emfs and electrode potentials
Equilibrium concentrations from emfs.
Dependence of emf on concentration
TEST 4
THIRTEENTH WEEK
Twenty fourth Lecture: Chapter 22 Main Group Elements
General observations
Group IA the alkali metals
Group IIA the alkaline earth metals
Twenty fifth Lecture: Chapter 22 Chemistry of the nonmetals
Group IVA the carbon family
Group VIIA the halogens
FOURTEENTH WEEK
Twenty sixth Lecture: Chapter 23 The transition elements
Periodic trends
The chemistry of copper and chromium
Twenty seventh Lecture: Chapter 23 Coordination compounds
Structure of complexes
Naming coordination compounds
Structure and isomers of coordination compounds
FIFTEENTH WEEK
Twenty eighth Lecture: Chapter 24 Organic chemistry
The bonding of carbon
Alkanes and cycloalkaned
Alkenes and Alkynes
Twenty ninth Lecture: Chapter 24 Organic chemistry
Aromatic hydrocarbons
FIFTH TEST