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15.3: Common Bases and Their Uses

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    358801
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    ⚙️ Learning Objectives

    • Identify sources and uses of common bases.


    Bases are less common as foods, but they are nonetheless present in many household products. Many cleaners contain ammonia, a base. Sodium hydroxide is found in drain cleaner. Antacids, which combat excess stomach acid, are comprised of bases such as magnesium hydroxide or sodium hydrogen carbonate. Several common bases and their corresponding uses are described below.
     

    Sodium Hydroxide

    Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with formula NaOH. It is a white solid ionic compound consisting of sodium cations , Na+, and hydroxide anions, OH.
     

    Figure \(\PageIndex{1}\): A sample of sodium hydroxide as pellets in a watch glass. (Public Domain; Walkerma.)


    Dissolution of solid sodium hydroxide in water is a highly exothermic reaction:

    \(\mathrm{NaOH}\;(s)\;\xrightarrow{{\mathrm H}_2\mathrm O}\;\mathrm{Na}^+\;(aq)\;+\;\mathrm{OH}^-\;(aq)\)

    The resulting solution is colorless and odorless and feels slippery when it comes in contact with skin.
     

    Potassium Hydroxide

    Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash. Along with sodium hydroxide, NaOH, this colorless solid is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. Its dissolution in water is strongly exothermic.

    \(\mathrm{KOH}\;(s)\;\xrightarrow{{\mathrm H}_2\mathrm O}\;\mathrm{K}^+\;(aq)\;+\;\mathrm{OH}^-\;(aq)\)

    A concentrated aqueous solution is sometimes called potash lye.
     

    Magnesium Hydroxide

    Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. Magnesium hydroxide is a common component of antacids, such as milk of magnesia, as well as laxatives.
     

    Figure \(\PageIndex{2}\): Bottle of antacid tablets. (CC BY 2.5; Midnightcomm).


    It is a white solid with low solubility in water. Combining a solution of many magnesium salts with basic water induces precipitation of solid Mg(OH)2. However, a weak concentration of dissociated ions can be found in solution:

    Mg(OH)2 (s) ⇌ Mg2+ (aq) + 2 OH (aq)
     

    Calcium Hydroxide

    Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, or pickling lime. Calcium hydroxide is used in many applications, including food preparation. Limewater is the common name for a saturated solution of calcium hydroxide.

    Calcium hydroxide is relatively insoluble in water, but is large enough that its solutions are basic according to the following reaction:

    Ca(OH)2 (s) ⇌ Ca2+ (aq) + 2 OH (aq)
     

    Ammonia

    Ammonia is a compound of nitrogen and hydrogen with the formula NH3 and is a colorless gas with a characteristic pungent smell. It is the active product of “smelling salts,” and can quickly revive the faint of heart and light of head. Although common in nature and in wide use, ammonia is both caustic and hazardous in its concentrated form.

    Figure \(\PageIndex{3}\): Jsmol rendering of the ammonia molecule.


    In aqueous solution, ammonia acts as a base, acquiring hydrogen ions from H2O to yield ammonium and hydroxide ions:

    NH3 (g) + H2O (l) ⇌ NH4+ (aq) + OH (aq)

    Ammonia is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products.
     

    Summary

    Table \(\PageIndex{1}\): Common Bases and Their Uses
    Chemical Name
    Common Name Uses

    sodium hydroxide, NaOH
     
    lye or caustic soda Used in the manufacture of soaps and detergents, and as the main ingredient in oven and drain cleaners.

    potassium hydroxide, KOH
     
    lye or caustic potash Used in the production of liquid soaps and soft soaps. Used in alkaline batteries.

    magnesium hydroxide, Mg(OH)2
     
    milk of magnesia Used as an ingredient in laxatives, antacids, and deodorants. Also used in the neutralization of acidic wastewater.

    calcium hydroxide, Ca(OH)2
     
    slaked lime Used in the manufacture of cement and lime water. Also added to neutralize acidic soil.

    ammonia, NH3
     
      Used as a building block for the synthesis of many pharmaceutical products and in many commercial cleaning products. Used in the manufacture of fertilizers.

     

     


    This page is shared under a CK-12 license and was authored, remixed, and/or curated by Melissa Alviar-Agnew, Henry Agnew, and Lance S. Lund (Anoka-Ramsey Community College). Original source: https://www.ck12.org/c/chemistry/.

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    15.3: Common Bases and Their Uses is shared under a not declared license and was authored, remixed, and/or curated by LibreTexts.

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