30.2: Thermodynamic Data of Organic Substances at 298 K
| Formula: | Name: | \(\Delta_{\text{f}} H^{-\kern-6pt{\ominus}\kern-6pt-}\) \(\scriptstyle{\text{[kJ/mol]}}\) | \(\Delta_{\text{f}} G^{-\kern-6pt{\ominus}\kern-6pt-}\) \(\scriptstyle{\text{[kJ/mol]}}\) | \(S^{-\kern-6pt{\ominus}\kern-6pt-}\) \(\scriptstyle{\text{[J/(mol K)]}}\) | \(C_P\) \(\scriptstyle{\text{[J/(mol K)]}}\) |
|---|---|---|---|---|---|
| CHBr 3 | Bromoform(g) | 25 | 16 | 331 | 71 |
| CHCl 3 | Chloroform(l) | –134.1 | –73.7 | 201.7 | 114.2 |
| CHCl 3 | Chloroform(g) | –102.7 | 6.0 | 295.7 | 65.7 |
| CH 2 O 2 | Formic acid(l) | –425 | –361.4 | 129 | 99 |
| CH 2 O 2 | Formic acid(g) | –378.7 | |||
| CH 3 | Methyl(g) | 145.7 | 47.9 | 194.2 | 38.7 |
| CH 3 Br | Bromomethane(l) | –59.8 | |||
| CH 3 Br | Bromomethane(g) | –35.4 | –26.3 | 246.4 | 42.4 |
| CH 3 Cl | Chloromethane(g) | –81.9 | –63 | 234.6 | 40.8 |
| CH 3 F | Fluormethane(g) | –234 | –210 | 222.9 | 37.5 |
| CH 3 I | Iodomethane(l) | –13.6 | 136.2 | 126 | |
| CH 3 I | Iodomethane(g) | 14.4 | 16 | 254.1 | 44.1 |
| CH 3 NO 2 | Nitromethane(l) | –112.6 | –14.4 | 171.8 | 106.6 |
| CH 3 NO2 | Nitromethane(g) | –80.8 | –7 | 282.9 | 55.5 |
| CH 4 | Methane(g) | –74.6 | –50.5 | 186.3 | 35.7 |
| CH 4 O | Methanol(l) | –239.2 | –166.6 | 126.8 | 81.1 |
| CH 4 O | Methanol(g) | –201 | –162.3 | 239.9 | 44.1 |
| CH 5 N | Methylamine(l) | –47.3 | 35.7 | 150.2 | 102.1 |
| CH 5 N | Methylamine(g) | –22.5 | 32.7 | 242.9 | 50.1 |
| C 2 H 2 | Ethyne (acetylene)(g) | 226.9 | 209 | 201 | 44 |
| C 2 H 4 | Ethene(g) | 52.5 | 68.4 | 219.3 | 42.9 |
| C 2 H4O 2 | Acetic acid(l) | –484.3 | –389.9 | 159.8 | 123.3 |
| C 2 H4O 2 | Acetic acid(g) | –432.2 | –374.2 | 283.5 | 63.4 |
| C 2 H 5 Br | Bromoethane(l) | –90.5 | –25.8 | 198.7 | 100.8 |
| C 2 H 5 Br | Bromoethane(g) | –61.9 | –23.9 | 286.7 | 64.5 |
| C 2 H 5 Cl | Chloroethane(l) | –136.8 | –59.3 | 190.8 | 104.3 |
| C 2 H 5 Cl | Chloroethane(g) | –112.1 | –60.4 | 276 | 62.8 |
| C2H 5 NO 2 | Nitroethane(l) | –143.9 | 134.4 | ||
| C2H 5 NO 2 | Nitroethane(g) | –103.8 | –5 | 320.5 | 79 |
| C 2 H 6 | Ethane(g) | –84 | –32 | 229.2 | 52.5 |
| C 2 H 6 O | Ethanol(l) | –277.6 | –174.8 | 160.7 | 112.3 |
| C 2 H 6 O | Ethanol(g) | –234.8 | –167.9 | 281.6 | 65.6 |
| C 2 H 6 O | Methoxymethane(l) | –203,3 | |||
| C 2 H 6 O | Methoxymethane(g) | –184.1 | –112.6 | 266.4 | |
| C 2 H 7 N | Ethylamine(l) | –74.1 | 130 | ||
| C 2 H 7 N | Ethylamine(g) | –47.5 | 36.3 | 283.8 | 71.5 |
| C 3 H 4 | Cyclopropene(g) | 277.1 | 286 | 244 | 53 |
| C 3 H 4 | Propyne(g) | 185 | 194 | 248 | 61 |
| C 3 H 6 | Cyclopropane(l) | 35.2 | |||
| C 3 H 6 | Cyclopropane(g) | 53.3 | 104.5 | 237.5 | 55.6 |
| C 3 H 6 | Propene(g) | 20 | 62 | 267 | 64 |
| C 3 H 6 O | Acetone(l) | –248.4 | 199.8 | 126.3 | |
| C 3 H 6 O | Acetone(g) | –217.1 | –152.7 | 295.3 | 74.5 |
| C 3 H 6 O 2 | Propanoic acid(l) | –510.7 | 191 | 152.8 | |
| C 3 H 6 O 2 | Propanoic acid(g) | –455.7 | |||
| C 3 H 8 | Propane(l) | –120.9 | |||
| C 3 H 8 | Propane(g) | –103.8 | –23.4 | 270.3 | 73.6 |
| C 3 H 8 O | 1-Propanol(l) | –302.6 | 193.6 | 143.9 | |
| C 3 H 8 O | 1-Propanol(g) | –255.1 | 322.6 | 85.6 | |
| C 3 H 8 O | 2-Propanol(l) | –318.1 | 181.1 | 156.5 | |
| C 3 H 8 O | 2-Propanol(g) | –272.6 | 309.2 | 89.3 | |
| C 3 H 9 N | 1-Propanamine(g) | –72 | 40 | 324 | |
| C 4 H 6 | 1-Butyne(l) | 141.4 | |||
| C 4 H 6 | 1-Butyne(g) | 165.2 | 202 | 291 | 81 |
| C 4 H 6 | 2-Butyne(l) | 119.1 | |||
| C 4 H 6 | 2-Butyne(g) | 145.7 | 185 | 283 | 78 |
| C 4 H 6 | Cyclobutene(g) | 156.7 | 175 | 64 | 64 |
| C 4 H 8 | 2-Methyl–1-propene(g) | –17 | 58 | 294 | 89 |
| C 4 H 8 | 1-Butene(l) | –20.8 | 227 | 118 | |
| C 4 H 8 | 1-Butene(g) | 0.1 | 71 | 306 | 86 |
| C 4 H 8 | Cyclobutane(l) | 3.7 | |||
| C 4 H 8 | Cyclobutane(g) | 27.7 | 110 | 265 | |
| C 4 H 8 O 2 | Butanoic acid(l) | –533.8 | 222.2 | 178.6 | |
| C 4 H 8 O 2 | Butanoic acid(g) | –475.9 | |||
| C 4 H 10 | 2-Methylpropane(g) | –135 | –21 | 295 | 97 |
| C 4 H 10 | Butane(l) | –147.3 | 140.9 | ||
| C 4 H 10 | Butane(g) | –125.7 | –17 | 310 | 98 |
| C 4 H 10 O | 1-Butanol(l) | –327.3 | 225.8 | 177.2 | |
| C 4 H 10 O | 1-Butanol(g) | –274.9 | |||
| C 4 H 10 O | 2-Butanol(l) | –342.6 | 214.9 | 196.9 | |
| C 4 H 10 O | 2-Butanol(g) | –292.8 | 359.5 | 112.7 | |
| C 5 H 8 | 1-Pentyne(g) | 144 | 210 | 330 | 105 |
| C 5 H 8 | 2-Pentyne(g) | 129 | 194 | 332 | 99 |
| C 5 H 8 | Cyclopentene(l) | 4.3 | 201.2 | 122.4 | |
| C 5 H 8 | Cyclopentene(g) | 34 | 111 | 290 | 75 |
| C 5 H 10 | 1-Pentene(l) | –46.9 | 262.6 | 154 | |
| C 5 H 10 | 1-Pentene(g) | –21.1 | 79 | 346 | 110 |
| C 5 H 10 | 2-Methyl–1-butene(g) | –35.2 | 66 | 340 | 112 |
| C 5 H 10 | 2-Methyl–1-butene(l) | –61.1 | 254 | 157.2 | |
| C 5 H 10 | Cyclopentane(l) | –105.1 | 204.5 | 128.8 | |
| C 5 H 10 | Cyclopentane(g) | –76.4 | 39 | 293 | 83 |
| C 5 H 10 O 2 | Pentanoic acid(l) | –559.4 | 259.8 | 210.3 | |
| C 5 H 10 O 2 | Pentanoic acid(g) | –491.9 | |||
| C 5 H 12 | 2,2-Dimethylpropane(g) | –166 | –15 | 306 | 122 |
| C 5 H 12 | 2-Methylbutane(g) | –155 | –15 | 344 | 119 |
| C 5 H 12 | Pentane(l) | –173.5 | 167.2 | ||
| C 5 H 12 | Pentane(g) | –146.9 | –8 | 349 | 120 |
| C 5 H 12 O | 1-Pentanol(l) | –351.6 | 208.1 | ||
| C 5 H 12 O | 1-Pentanol(g) | –294.6 | |||
| C 5 H 12 O | 2-Pentanol(l) | –365.2 | |||
| C 5 H 12 O | 2-Pentanol(g) | –311 | |||
| C 5 H 12 O | 3-Pentanol(l) | –368.9 | 239.7 | ||
| C 5 H 12 O | 3-Pentanol(g) | –314.9 | |||
| C 5 H 12 O | Methyl tert-butyl ether(l) | –313.6 | 265.3 | 187.5 | |
| C 5 H 12 O | Methyl tert-butyl ether(g) | –283.7 | |||
| C 6 H 6 | Benzene(l) | 49.1 | 124.5 | 173.4 | 136 |
| C 6 H 6 | Benzene(g) | 82.9 | 129.7 | 269.2 | 82.4 |
| C 6 H 7 N | Aniline(l) | 191.9 | |||
| C 6 H 7 N | Aniline(g) | 87.5 | –7 | 317.9 | 107.9 |
| C 6 H 10 | 1-Hexyne(g) | 124 | 219 | 369 | 128 |
| C 6 H 10 | Cyclohexene(l) | –28.5 | 214.6 | 148.3 | |
| C 6 H 10 | Cyclohexene(g) | –5 | 107 | 311 | 105 |
| C 6 H 12 | 1-Hexene(l) | –74.2 | 295.2 | 183.3 | |
| C 6 H 12 | 1-Hexene(g) | –43.5 | 87 | 385 | 132 |
| C 6 H 12 | 2-Methyl–1-pentene(g) | –59.4 | |||
| C 6 H 12 | 2-Methyl–1-pentene(l) | –90 | |||
| C 6 H 12 | Cyclohexane(l) | –156.4 | 154.9 | ||
| C 6 H 12 | Cyclohexane(g) | –123.4 | 32 | 298 | 106 |
| C 6 H 12 | Methylcyclopentane(g) | –106.2 | |||
| C 6 H 12 | Methylcyclopentane(l) | –137.9 | |||
| C 6 H 12 O 2 | Hexanoic acid(l) | –583.8 | |||
| C 6 H 12 O 2 | Hexanoic acid(g) | –511.9 | |||
| C 6 H 14 | 2,2-Dimethylbutane(g) | –185.9 | –10 | 358 | 142 |
| C 6 H 14 | 2,2-Dimethylbutane(l) | –213.8 | 272.5 | 191.9 | |
| C 6 H 14 | 2-Methylpentane(g) | –174.6 | –5 | 381 | 144 |
| C 6 H 14 | 2-Methylpentane(l) | –204.6 | 290.6 | 193.7 | |
| C 6 H 14 | 3-Methylpentane(g) | –171.9 | –2 | 380 | 143 |
| C 6 H 14 | 3-Methylpentane(l) | –202.4 | 292.5 | 190.7 | |
| C 6 H 14 | Hexane(l) | –198.7 | 195.6 | ||
| C 6 H 14 | Hexane(g) | –166.9 | –0.3 | 388 | 143 |
| C 6 H 14 O | 1-Hexanol(l) | –377.5 | 287.4 | 240.4 | |
| C 6 H 14 O | 1-Hexanol(g) | 315.9 | |||
| C 6 H 14 O | 2-Hexanol(l) | –392 | |||
| C 6 H 14 O | 2-Hexanol(g) | –333.5 | |||
| C 7 H 6 O | Phenol(s) | –165.1 | 144 | 127.4 | |
| C 7 H 6 O | Phenol(g) | –96.4 | –33 | 316 | 104 |
| C 7 H 8 | Methylbenzene(l) | 12.0 | 220 | 156 | |
| C 7 H 8 | Methylbenzene(g) | 50.0 | 122 | 321 | 104 |
| C 7 H 14 | 1-Heptene(l) | –97.9 | 327.6 | 211.8 | |
| C 7 H 14 | 1-Heptene(g) | –62.3 | 96 | 424 | 15 |
| C 7 H 14 | Cycloheptane(l) | –156.6 | |||
| C 7 H 14 | Cycloheptane(g) | –118.1 | |||
| C 7 H 14 | Ethylcyclopentane(l) | –163.4 | 279.9 | ||
| C 7 H 14 | Ethylcyclopentane(g) | –126.9 | |||
| C 7 H 14 | Methylcyclohexane(g) | –154.7 | |||
| C 7 H 14 | Methylcyclohexane(l) | –190.1 | 184.8 | ||
| C 7 H 14 O 2 | Heptanoic acid(l) | –610.2 | 265.4 | ||
| C 7 H 14 O 2 | Heptanoic acid(g) | –536.2 | |||
| C 7 H 16 | 2,2-Dimethylpentane(g) | –205.7 | |||
| C 7 H 16 | 2,2-Dimethylpentane(l) | –238.3 | 300.3 | 221.1 | |
| C 7 H 16 | 2-Methylhexane(g) | –194.5 | |||
| C 7 H 16 | 2-Methylhexane(l) | –229.5 | 323.3 | 222.9 | |
| C 7 H 16 | 3-Methylhexane(g) | –191.3 | |||
| C 7 H 16 | 3-Methylhexane(l) | –226.4 | |||
| C 7 H 16 | Heptane(l) | –224.2 | 224.7 | ||
| C 7 H 16 | Heptane(g) | –187.6 | 8 | 428 | 166 |
| C 7 H 16 O | 1-Heptanol(l) | –403.3 | 272.1 | ||
| C 7 H 16 O | 1-Heptanol(g) | –336.5 | |||
| C 8 H 10 | Ethylbenzene(l) | –12.3 | 183.2 | ||
| C 8 H 10 | Ethylbenzene(g) | 29.9 | 131 | 361 | 128 |
| C 8 H 16 | 1-Octene(l) | –124.5 | 241 | ||
| C 8 H 16 | 1-Octene(g) | –81.3 | 104 | 463 | 178 |
| C 8 H 16 | Cyclooctane(l) | –167.7 | |||
| C 8 H 16 | Cyclooctane(g) | –124.4 | |||
| C 8 H 16 | Ethylcyclohexane(l) | –212.1 | 280.9 | 211.8 | |
| C 8 H 16 | Ethylcyclohexane(g) | –171.5 | |||
| C 8 H 16 O 2 | Octanoic acid(l) | –636 | 297.9 | ||
| C 8 H 16 O 2 | Octanoic acid(g) | –554.3 | |||
| C 8 H 18 | 2-Methylheptane(g) | –215.3 | |||
| C 8 H 18 | 2-Methylheptane(l) | –255 | 356.4 | 252 | |
| C 8 H 18 | 3-Methylheptane(g) | –212.5 | |||
| C 8 H 18 | 3-Methylheptane(l) | –252.3 | 362.6 | 250.2 | |
| C 8 H 18 | Octane(l) | –250.1 | 254.6 | ||
| C 8 H 18 | Octane(g) | –208.5 | 16 | 467 | 189 |
| C 8 H 18 O | 1-Octanol(l) | –426.5 | 305.2 | ||
| C 8 H 18 O | 1-Octanol(g) | –355.6 | |||
| C 8 H 19 | 2,2-Dimethylhexane(g) | –224.5 | |||
| C 8 H 19 | 2,2-Dimethylhexane(l) | –261.9 | |||
| C 9 H 18 | Propylcyclohexane(g) | –192 | 420 | 242 | |
| C 9 H 12 | Propylbenzene(g) | 8 | 137 | 401 | 154 |
| C 9 H 16 | 1-Nonyne(l) | 16.3 | |||
| C 9 H 16 | 1-Nonyne(g) | 62.3 | |||
| C 9 H 18 O 2 | Nonanoic acid(l) | –659.7 | 362.4 | ||
| C 9 H 18 O 2 | Nonanoic acid(g) | –577.3 | |||
| C 9 H 20 | 2,2-Dimethylheptane(g) | –246 | |||
| C 9 H 20 | 2,2-Dimethylheptane(l) | –288.1 | |||
| C 9 H 20 | Nonane(l) | –274.7 | 284.4 | ||
| C 9 H 20 | Nonane(g) | –228.2 | 25 | 506 | 212 |
| C 9 H 20 O | 1-Nonanol(l) | –453.4 | |||
| C 9 H 20 O | 1-Nonanol(g) | –376.5 | |||
| C 10 H 8 | Naphthalene(g) | 151 | 224 | 336 | |
| C 10 H 14 | Butylbenzene(l) | –63.2 | 321.2 | 243.4 | |
| C 10 H 14 | Butylbenzene(g) | –11.8 | |||
| C 10 H 20 | 1-Decene(l) | –173.8 | 425 | 300.8 | |
| C 10 H 20 | 1-Decene(g) | –123.3 | 301 | ||
| C 10 H 20 | Butylcyclohexane(l) | –263.1 | 345 | 271 | |
| C 10 H 20 | Butylcyclohexane(g) | –213.7 | |||
| C 10 H 20 O 2 | Decanoic acid(s) | –713.7 | |||
| C 10 H 20 O 2 | Decanoic acid(l) | –684.3 | |||
| C 10 H 20 O 2 | Decanoic acid(g) | –594.9 | |||
| C 10 H 22 | 2-Methylnonane(g) | –260.2 | |||
| C 10 H 22 | 2-Methylnonane(l) | –309.8 | 420.1 | 313.3 | |
| C 10 H 22 | Decane(l) | –300.9 | 314.4 | ||
| C 10 H 22 | Decane(g) | –249.5 | 33 | 545 | 235 |
| C 10 H 22 O | 1-Decanol(l) | –478.1 | 370.6 | ||
| C 10 H 22 O | 1-Decanol(g) | –396.6 | |||
| C 11 H 10 | 1-Methylnaphthalene(l) | 56.3 | 254.8 | 224.4 | |
| C 11 H 10 | 2-Methylnaphthalene(s) | 44.9 | 220 | 196 | |
| C 11 H 10 | 2-Methylnaphthalene(g) | 106.7 | |||
| C 11 H 22 | 1-Undecene(g) | 344.9 | |||
| C 11 H 24 | Undecane(l) | –327.2 | 344.9 | ||
| C 11 H 24 | Undecane(g) | –270.8 | 42 | 584 | 257 |
| C 11 H 24 O | 1-Undecanol(l) | –504.8 | |||
| C 12 H 24 | 1-Dodecene(l) | –226.2 | 484.8 | 360.7 | |
| C 12 H 24 | 1-Dodecene(g) | –165.4 | |||
| C 12 H 24 O 2 | Dodecanoic acid(s) | –774.6 | 404.3 | ||
| C 12 H 24 O 2 | Dodecanoic acid(l) | –737.9 | |||
| C 12 H 24 O 2 | Dodecanoic acid(g) | 642 | |||
| C 12 H 26 | Dodecane(l) | –350.9 | 375.8 | ||
| C 12 H 26 | Dodecane(g) | –289.4 | 50 | 623 | 280 |
| C 12 H 26 O | 1-Dodecanol(l) | –528.5 | 438.1 | ||
| C 12 H 26 O | 1-Dodecanol(g) | –436.6 | |||
| C 14 H 10 | Anthracene(g) | 231 | |||
| C 14 H 10 | Phenantrene(g) | 207 | |||
| C 15 H 30 | Decylcyclopentane(l) | –367.3 | |||
| C 16 H 26 | Decylbenzene(l) | –218.3 | |||
| C 16 H 26 | Decylbenzene(g) | –138.6 | |||
| C 16 H 32 | 1-Hexadecene(l) | –328.7 | 587.9 | 488.9 | |
| C 16 H 32 | 1-Hexadecene(g) | –248.4 | |||
| C 16 H 32 O 2 | Hexadecanoic acid(s) | –891.5 | 452.4 | 460.7 | |
| C 16 H 32 O 2 | Hexadecanoic acid(l) | –838.1 | |||
| C 16 H 32 O 2 | Hexadecanoic acid(g) | –737.1 | |||
| C 16 H 34 | N-hexadecane(l) | –456.1 | 501.6 | ||
| C 16 H 34 | N-hexadecane(g) | –374.8 | |||
| C 18 H 12 | Chrysene(s) | 145.3 | |||
| C 18 H 12 | Chrysene(g) | 269.8 |