3.23: A Simple Electrostatic Critique of VSEPR
- Page ID
- 154236
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)In a previous tutorial [1] it was shown that the reason methane is tetrahedral (Td) rather than square planar (D4h) is because electron-nucleus attractions are greater for the tetrahedral geometry. VSEPR teaches (incorrectly) that minimization of electron-electron potential energy drives molecular geometry. However, the previous variational calculation showed that electron-electron repulsion is actually higher in Td methane than it is in the D4h molecule.
In what follows a simple electrostatic calculation will be presented which reaches the same conclusion as the more elaborate and rigorous variational calculation based on Henry Bent’s [2] Tangent Spheres Model (TSM) of chemical bonding and molecular geometry. This calculation was suggested to the author in a private communication from Henry Bent.
A simple ionic model is proposed for the bonding in methane. The +4 carbon kernel (nucleus and nonvalence electrons) is treated as a point charge which interacts electrostatically with four unpolarized hydride anions of unit diameter in either a square planar or tetrahedral arrangement. In tetrahedral methane the +4 kernel occupies the tetrahedral hole and is not visible in the diagram shown below.
Rudimentary geometrical considerations provide the necessary molecular parameters in the following table.
Molecular Parameter | D4h | Td |
Hydride-Hydride Distance | 4 @ 1 and 2 @ √2 | 6 @ 1 |
Hydride-Nucleus Distance | 4 @ √2/2 | 4 @ √(3/8) |
From an electrostatic perspective a hydride anion is equivalent to an electron. Therefore, the calculation of the potential energy will be expressed in terms of electron-electron potential energy and electronnucleus potential energy. Using the molecular parameters listed in the table above we calculate the potential energy contributions for both geometries as follows.
Square Planar Methane
\[ \begin{pmatrix} V_{ee} = 4 \frac{(-1)(-1)}{1} + 2 \frac{(-1)(-1)}{ \sqrt{2}} = 5.41 \\ V_{en} = 4 \frac{(-1)(+4)}{ \frac{ \sqrt{2}}{2}} = -22.63 \end{pmatrix} \nonumber \]
Tetrahedral Methane
\[ \begin{matrix} V_{ee} = 6 \frac{(-1)(-1)}{1} = 6.00 \\ V_{en} = 4 \frac{(-1)(+4)}{ \sqrt{ \frac{3}{8}}} = -26.13 \end{matrix} \nonumber \]
These results are summarized in the following table.
Energy Contribution | D4h | Td |
Vee | 5.41 | 6.00 |
Ven | -22.63 | -26.13 |
Vtot | -17.22 | -20.13 |
The results of this simple electrostatic calculation contradict the VSEPR model in two significant ways:
- Electron-electron repulsions are greater for tetrahedral geometry than they are for square planar geometry.
- Td is favored over D4h because of electron-nucleus attractions. In other words, electron-nuclear attractions are the most important energy contribution in determining molecular geometry.
The latter conclusion should not be surprising. There are four types of energy contributions in a molecule under the Born-Oppenheimer approximation: (1) electron kinetic energy; (2) electron-nucleus potential energy; (3) electron-electron potential energy; (4) nucleus-nucleus potential energy. Electronnucleus potential energy is the only attractive term, and electron-electron potential energy is the smallest of the “repulsive” terms. Clearly electron-nucleus attraction is the single most important term in determining molecular geometry.
Furthermore, this guarantees that electron-electron potential energy will track in the opposite direction. Electron domains get closer to nuclei in two ways: by adopting a close-packed geometry (Td versus D4h) and by shrinking in size. Both lead to larger electron-electron potential energy and lower (more negative) electron-nucleus potential energy.
For the reasons enumerated above, chemical educators should recall VSEPR. It is not a valid model for molecular geometry and takes up space in textbooks that would be better devoted to viable quantum mechanical models of molecular geometry such as TSM [1, 2] or molecular orbital theory. Even in those textbooks in which it is juxtaposed with more credible models it distracts attention from them because of its specious predictive methodology.
- Rioux, F. http://www.users.csbsju.edu/~frioux/vsepr/NVSEPR.htm
- Bent, H. A. J. Chem. Educ. 40, 446-452 (1963).