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Named Reagents

Last updated

Jan 23, 2023
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- Mukaiyama aldol addition
- Negishi cross-coupling

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Named reagent	Structure	Formula	Other Name	CAS number
Adam's catalyst		PtO₂	Platinum(IV) oxide	1314-15-4
Appel's salt		C₂Cl₃NS₂	4,5-dichloro-1,2,3-dithiazolium chloride	75318-43-3
Bestmann ylide		C₂₀H₁₅OP	2-(triphenylphosphoranylidene)ethenone	15596-07-3
Brady's reagent		C₆H₆N₄O₄	(2,4-dinitrophenyl)hydrazine	119-26-6
Brassard's diene		C₁₁H₂₂O₃Si	(E)-((1,3-diethoxybuta-1,3-dien-1-yl)oxy)trimethylsilane
Bredereck's reagent		C₉H₂₂N₂O	tert-Butoxy bis(dimethylamino)methane	5815-08-7
Burgess reagent		C₈H₁₈N₂O₄S	1-methoxy-N-triethylammoniosulfonyl-methanimidate	29684-56-8
Caro's acid		H₂O₅S	Peroxymonosulfuric acid	7722-86-3
Collins reagent		C₁₀H₁₀N₂CrO₃	Dipyridine chromium(VI) oxide	20492-50-6
Comins' reagent		C₇H₃ClF₆N₂O₄S₂	2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine	145100-51-2
Corey-Bakshi-Shibata catalyst		C₁₈H₂₀BNO	(R)-(+)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole (S)-(-)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole	112022-83-0 112022-81-8
Corey-Chaykovsky reagent		C₃H₈OS	Dimethylsulfoxonium methylide	5367-24-8
Corey lactone		C₈H₁₂O₄	(3aR,4S,5R,6aS)-(−)-Hexahydro-5-hydroxy-4-(hydroxymethyl)-2H-cyclopenta[b]furan-2-one (3aS,4R,5S,6aR)-(+)-Hexahydro-5-hydroxy-4-(hydroxymethyl)-2H-cyclopenta[b]furan-2-one	32233-40-2 76704-05-7
Cornforth reagent		C₁₀H₁₂N₂Cr₂O₇	Pyridinium dichromate	20039-37-6
Danishefsky's diene		C₈H₁₆O₂Si	(E)-1-Methoxy-3-trimethylsilyloxy-1,3-butadiene	54125-02-9
Dess-Martin periodinane		C₁₃H₁₃IO₈	1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one	87413-09-0
Echavarren's gold complex		C₂₂H₃₀AuF₆NPSb	(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate	866641-66-9
Eschenmoser's salt		C₃H₈NI	Dimethylmethylideneammonium iodide	33797-51-2
Fétizon's reagent		N/A	Silver carbonate on Celite	N/A
Fort's base		N/A	N/A	N/A
Frémy's salt		K₂NO₇S₂	Potassium nitrosodisulfonate	14293-70-0
Garner's aldehyde		C₁₁H₁₉NO₄	(S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate (R)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate	102308-32-7 95715-87-0
Glauber's salt		H₂₀O₁₄Na₂S	Sodium sulfate decahydrate	7727-73-3
Gold's reagent		C₆H₁₄ClN₃	(Dimethylaminomethyleneaminomethylene)dimethylammonium chloride	20353-93-9
Grubbs catalyst (1^st generation)		C₄₃H₇₂Cl₂P₂Ru	Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium	172222-30-9
Grubbs catalyst (2^nd generation)		C₄₆H₆₅Cl₂N₂PRu	(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium	246047-72-3
Guindon's reagent		C₂H₆BBr	Dimethylboron bromide	5158-50-9
Hajos-Parrish ketone		C₁₀H₁₂O₂	(S)-7a-methyl-2,3,7,7a-tetrahydro-1H-indene-1,5(6H)-dione (R)-7a-methyl-2,3,7,7a-tetrahydro-1H-indene-1,5(6H)-dione	17553-86-5 17553-89-8
Hantzsch's ester		C₁₃H₁₉NO₄	Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate	214-561-6
Hatakeyama's catalyst		C₁₉H₂₂N₂O₂	(9S)-3α,9-Epoxy-10,11-dihydrocinchonan-6'-ol	253430-48-7
Hermann-Beller catalyst		C₄₆H₄₆O₄P₂Pd₂	trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)	172418-32-5
Hieber anion		C₃FeNO₄	N/A	N/A
Hoveyda-Grubbs catalyst (1^st generation)		C₂₈H₄₅Cl₂OPRu	Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)	203714-71-0
Hoveyda-Grubbs catalyst (2^nd generation)		C₃₁H₃₈Cl₂N₂ORu	(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium	301224-40-8
Hünig's base		C₈H₁₉N	N,N-Diisopropylethylamine	7087-68-5
Kagan's reagent		SmI₂	Samarium diiodide	32248-43-4
Kemp's triacid		C₁₂H₁₈O₆	cis,cis-1,3,5-Trimethylcyclohexane-1,3,5-tricarboxylic acid	79410-20-1
Koser's reagent		C₁₃H₁₃IO₄S	[Hydroxy(tosyloxy)iodo]benzene	27126-76-7
Lawesson's reagent		C₁₄H₁₄O₂P₂S₄	2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide	19172-47-5
Leuchs' anhydrides		N/A	N/A	N/A
Lindlar catalyst		N/A	Pd/CaCO₃ poisoned with Lead (Pb(OAc)₂ or PbO)	N/A
Mander's reagent		C₃H₃NO₂	Methyl cyanoformate	17640-15-2
Martin's sulfurane		C₃₀H₂₀F₁₂O₂S	Bis[α,α-bis(trifluoromethyl)benzyloxy]diphenylsulfur	32133-82-7
Meerwein's reagent		C₃H₉OBF₄	Trimethyloxonium tetrafluoroborate	420-37-1
Meldrum's acid		C₆H₈O₄	2,2-Dimethyl-1,3-dioxane-4,6-dione	2033-24-1
Mosher's acid		C₁₀H₉F₃O₃	(R)-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoic acid (S)-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoic acid	20445-31-2 17257-71-5
Pearlman's Catalyst		N/A	Palladium hydroxide on carbon	12135-22-7
Ohira-Bestmann reagent		C₅H₉N₂O₄P	Dimethyl (1-diazo-2-oxopropyl)phosphonate	90965-06-3
Roche ester		C₅H₁₀O₃	Methyl (S)-(+)-3-hydroxy-2-methylpropionate Methyl (R)-(+)-3-hydroxy-2-methylpropionate	80657-57-4 72657-23-9
Schlosser's base		N/A	N/A	N/A
Schwartz reagent		C₁₀H₁₁ClZr	Bis(cyclopentadienyl)zirconium(IV) chloride hydride	37342-97-5
Seyferth-Gilbert reagent		C₃H₇N₂O₃P	Dimethyl (diazomethyl)phosphonate	27491-70-9
Shiina's reagent		C₁₆H₁₂N₂O₇	2-Methyl-6-nitrobenzoic anhydride	434935-69-0
Stryker's reagent		C₁₀₈H₉₆Cu₆P₆	(Triphenylphosphine)copper hydride hexamer	33636-93-0
Tebbe reagent		C₁₃H₁₈AlClTi	N/A	67719-69-1
Togni's reagent		C₁₀H₁₀F₃IO	3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole	887144-97-0
Tröger's base		C₁₇H₁₈N₂	(+)-(5R)-2,8-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine (-)-(5S)-2,8-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine	529-81-7 14645-24-0
Wieland–Miescher ketone		C₁₁H₁₄O₂	(S)-(+)-8a-Methyl-3,4,8,8a-tetrahydro-2H-naphthalene-1,6-dione (R)-(–)-8a-Methyl-3,4,8,8a-tetrahydro-2H-naphthalene-1,6-dione	33878-99-8 100348-93-4
Wood's metal	50% Bi / 26.7% Pb / 13.3% Sn / 10% Cd by weight	N/A	N/A	8049-22-7
Woollins' reagent		C₁₂H₁₀P₂Se₄	2,4-Diphenyl-1,3,2,4-diselenadiphosphetan-2,4-diselenide	122039-27-4

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