Named Reagents
- Page ID
- 15009
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)| Named reagent | Structure | Formula | Other Name | CAS number |
|---|---|---|---|---|
| Adam's catalyst |
 |
PtO2 | Platinum(IV) oxide | 1314-15-4 |
| Appel's salt |
 |
C2Cl3NS2 | 4,5-dichloro-1,2,3-dithiazolium chloride | 75318-43-3 |
| Bestmann ylide |
 |
C20H15OP | 2-(triphenylphosphoranylidene)ethenone | 15596-07-3 |
| Brady's reagent |
 |
C6H6N4O4 | (2,4-dinitrophenyl)hydrazine | 119-26-6 |
| Brassard's diene |
 |
C11H22O3Si | (E)-((1,3-diethoxybuta-1,3-dien-1-yl)oxy)trimethylsilane | |
| Bredereck's reagent |
 |
C9H22N2O | tert-Butoxy bis(dimethylamino)methane | 5815-08-7 |
| Burgess reagent |
 |
C8H18N2O4S | 1-methoxy-N-triethylammoniosulfonyl-methanimidate | 29684-56-8 |
| Caro's acid |
 |
H2O5S | Peroxymonosulfuric acid | 7722-86-3 |
| Collins reagent |
 |
C10H10N2CrO3 | Dipyridine chromium(VI) oxide | 20492-50-6 |
| Comins' reagent |
 |
C7H3ClF6N2O4S2 | 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine | 145100-51-2 |
| Corey-Bakshi-Shibata catalyst |
 |
C18H20BNO | (R)-(+)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole
(S)-(-)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole |
112022-83-0
112022-81-8 |
| Corey-Chaykovsky reagent |
 |
C3H8OS | Dimethylsulfoxonium methylide | 5367-24-8 |
| Corey lactone |
 |
C8H12O4 | (3aR,4S,5R,6aS)-(−)-Hexahydro-5-hydroxy-4-(hydroxymethyl)-2H-cyclopenta[b]furan-2-one
(3aS,4R,5S,6aR)-(+)-Hexahydro-5-hydroxy-4-(hydroxymethyl)-2H-cyclopenta[b]furan-2-one |
32233-40-2
76704-05-7 |
| Cornforth reagent |
 |
C10H12N2Cr2O7 | Pyridinium dichromate | 20039-37-6 |
| Danishefsky's diene |
 |
C8H16O2Si | (E)-1-Methoxy-3-trimethylsilyloxy-1,3-butadiene | 54125-02-9 |
| Dess-Martin periodinane |
 |
C13H13IO8 | 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one | 87413-09-0 |
| Echavarren's gold complex |
 |
C22H30AuF6NPSb | (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | 866641-66-9 |
| Eschenmoser's salt |
 |
C3H8NI | Dimethylmethylideneammonium iodide | 33797-51-2 |
| Fétizon's reagent |
 |
N/A | Silver carbonate on Celite | N/A |
| Fort's base |
 |
N/A | N/A | N/A |
| Frémy's salt |
 |
K2NO7S2 | Potassium nitrosodisulfonate | 14293-70-0 |
| Garner's aldehyde |
 |
C11H19NO4 | (S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
(R)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate |
102308-32-7
95715-87-0 |
| Glauber's salt |
 |
H20O14Na2S | Sodium sulfate decahydrate | 7727-73-3 |
| Gold's reagent |
 |
C6H14ClN3 | (Dimethylaminomethyleneaminomethylene)dimethylammonium chloride | 20353-93-9 |
| Grubbs catalyst (1st generation) |
 |
C43H72Cl2P2Ru | Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium | 172222-30-9 |
| Grubbs catalyst (2nd generation) |
 |
C46H65Cl2N2PRu | (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium | 246047-72-3 |
| Guindon's reagent |
 |
C2H6BBr | Dimethylboron bromide | 5158-50-9 |
| Hajos-Parrish ketone |
 |
C10H12O2 | (S)-7a-methyl-2,3,7,7a-tetrahydro-1H-indene-1,5(6H)-dione
(R)-7a-methyl-2,3,7,7a-tetrahydro-1H-indene-1,5(6H)-dione |
17553-86-5
17553-89-8 |
| Hantzsch's ester |
 |
C13H19NO4 | Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate | 214-561-6 |
| Hatakeyama's catalyst |
 |
C19H22N2O2 | (9S)-3α,9-Epoxy-10,11-dihydrocinchonan-6'-ol | 253430-48-7 |
| Hermann-Beller catalyst |
 |
C46H46O4P2Pd2 | trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) | 172418-32-5 |
| Hieber anion |
 |
C3FeNO4 | N/A | N/A |
| Hoveyda-Grubbs catalyst (1st generation) |
 |
C28H45Cl2OPRu | Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) | 203714-71-0 |
| Hoveyda-Grubbs catalyst (2nd generation) |
 |
C31H38Cl2N2ORu | (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium | 301224-40-8 |
| Hünig's base |
 |
C8H19N | N,N-Diisopropylethylamine | 7087-68-5 |
| Kagan's reagent |
 |
SmI2 | Samarium diiodide | 32248-43-4 |
| Kemp's triacid |
 |
C12H18O6 | cis,cis-1,3,5-Trimethylcyclohexane-1,3,5-tricarboxylic acid | 79410-20-1 |
| Koser's reagent |
 |
C13H13IO4S | [Hydroxy(tosyloxy)iodo]benzene | 27126-76-7 |
| Lawesson's reagent |
 |
C14H14O2P2S4 | 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide | 19172-47-5 |
| Leuchs' anhydrides |
 |
N/A | N/A | N/A |
| Lindlar catalyst |
 |
N/A | Pd/CaCO3 poisoned with Lead (Pb(OAc)2 or PbO) | N/A |
| Mander's reagent |
 |
C3H3NO2 | Methyl cyanoformate | 17640-15-2 |
| Martin's sulfurane |
 |
C30H20F12O2S | Bis[α,α-bis(trifluoromethyl)benzyloxy]diphenylsulfur | 32133-82-7 |
| Meerwein's reagent |
 |
C3H9OBF4 | Trimethyloxonium tetrafluoroborate | 420-37-1 |
| Meldrum's acid |
 |
C6H8O4 | 2,2-Dimethyl-1,3-dioxane-4,6-dione | 2033-24-1 |
| Mosher's acid |
 |
C10H9F3O3 | (R)-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoic acid
(S)-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoic acid |
20445-31-2
17257-71-5 |
| Pearlman's Catalyst |
 |
N/A | Palladium hydroxide on carbon | 12135-22-7 |
| Ohira-Bestmann reagent |
 |
C5H9N2O4P | Dimethyl (1-diazo-2-oxopropyl)phosphonate | 90965-06-3 |
| Roche ester |
 |
C5H10O3 | Methyl (S)-(+)-3-hydroxy-2-methylpropionate
Methyl (R)-(+)-3-hydroxy-2-methylpropionate |
80657-57-4
72657-23-9 |
| Schlosser's base |
 |
N/A | N/A | N/A |
| Schwartz reagent |
 |
C10H11ClZr | Bis(cyclopentadienyl)zirconium(IV) chloride hydride | 37342-97-5 |
| Seyferth-Gilbert reagent |
 |
C3H7N2O3P | Dimethyl (diazomethyl)phosphonate | 27491-70-9 |
| Shiina's reagent |
 |
C16H12N2O7 | 2-Methyl-6-nitrobenzoic anhydride | 434935-69-0 |
| Stryker's reagent |
 |
C108H96Cu6P6 | (Triphenylphosphine)copper hydride hexamer | 33636-93-0 |
| Tebbe reagent |
 |
C13H18AlClTi | N/A | 67719-69-1 |
| Togni's reagent |
 |
C10H10F3IO | 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole | 887144-97-0 |
| Tröger's base |
 |
C17H18N2 | (+)-(5R)-2,8-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine
(-)-(5S)-2,8-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine |
529-81-7
14645-24-0 |
| Wieland–Miescher ketone |
 |
C11H14O2 | (S)-(+)-8a-Methyl-3,4,8,8a-tetrahydro-2H-naphthalene-1,6-dione
(R)-(–)-8a-Methyl-3,4,8,8a-tetrahydro-2H-naphthalene-1,6-dione |
33878-99-8
100348-93-4 |
| Wood's metal | 50% Bi / 26.7% Pb / 13.3% Sn / 10% Cd by weight |
N/A | N/A | 8049-22-7 |
| Woollins' reagent |
 |
C12H10P2Se4 | 2,4-Diphenyl-1,3,2,4-diselenadiphosphetan-2,4-diselenide | 122039-27-4 |