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10.12: Summary of Reactions

Last updated

Sep 30, 2024
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- 10.11: Summary
- 11: Reactions of Alkyl Halides- Nucleophilic Substitutions and Eliminations

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No stereochemistry is implied unless specifically indicated with wedged, solid, and dashed lines.

Preparation of alkyl halides
1. From alkenes by allylic bromination (Section 10.4)
2. From alcohols (Section 10.6)
  1. Reaction with HX
  2. Reaction of 1° and 2° alcohols with SOCl₂
  3. Reaction of 1° and 2° alcohols with PBr₃
  4. Reaction of 1° and 2° alcohols with HF–pyridine
Reactions of alkyl halides
1. Formation of Grignard (organomagnesium) reagents (Section 10.7)
2. Formation of Gilman (diorganocopper) reagents (Section 10.8)
3. Organometallic coupling (Section 10.8)
  (1) Diorganocopper reaction
  
  (2) Palladium-catalyzed Suzuki–Miyaura reaction

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