- Basic Electronic Structure of Atoms
- This page explores how you write electronic structures for atoms using s, p, and d notation. It assumes that you know about simple atomic orbitals - at least as far as the way they are named, and their relative energies.
- Electronic Configurations Intro
- The electron configuration of an atom is the representation of the arrangement of electrons distributed among the orbital shells and subshells. Commonly, the electron configuration is used to describe the orbitals of an atom in its ground state, but it can also be used to represent an atom that has ionized into a cation or anion by compensating with the loss of or gain of electrons in their subsequent orbitals. Many of the physical and chemical properties of elements can be correlated to electro
- Hund's Rules
- Hund's rule states that: Every orbital in a sublevel is singly occupied before any orbital is doubly occupied. All of the electrons in singly occupied orbitals have the same spin (to maximize total spin). When assigning electrons to orbitals, an electron first seeks to fill all the orbitals with similar energy (also referred to as degenerate orbitals) before pairing with another electron in a half-filled orbital. Atoms at ground states tend to have as many unpaired electrons as possible.
- Pauli Exclusion Principle
- The Pauli Exclusion Principle states that, in an atom or molecule, no two electrons can have the same four electronic quantum numbers. As an orbital can contain a maximum of only two electrons, the two electrons must have opposing spins. This means if one is assigned an up-spin ( +1/2), the other must be down-spin (-1/2).
- Spin Pairing Energy
- Spin pairing energy refers to the energy associated with paired electrons sharing one orbital and its effect on the molecules surrounding it. Electron pairing determining the direction of spin depends on several laws founded by chemists over the years such as Hund's law, the Aufbau principle, and Pauli's exclusion principle. An overview of the different types laws associated with the electron pairing rules.
- Spin Quantum Number
- The Spin Quantum Number (s) is a value (of 1/2) that describes the angular momentum of an electron. An electron spins around an axis and has both angular momentum and orbital angular momentum. Because angular momentum is a vector, the Spin Quantum Number (s) has both a magnitude (1/2) and direction (+ or -). This vector is called the magnetic spin quantum number (ms).
- The Aufbau Process
- The Aufbau model lets us take an atom and make predictions about its properties. All we need to know is how many protons it has (and how many electrons, which is the same as the number of protons for a neutral atom). We can predict the properties of the atom based on our vague idea of where its electrons are and, more importantly, the energy of those electrons.
- The Order of Filling 3d and 4s Orbitals
- This page looks at some of the problems with the usual way of explaining the electronic structures of the d-block elements based on the order of filling of the d and s orbitals. The way that the order of filling of orbitals is normally taught gives an easy way of working out the electronic structures of elements. However, it does throw up problems when you come to explain various properties of the transition elements.
Michigan State Virtual Textbook of Organic Chemistry
Carey 4th Edition On-Line Activity