III. Organosilanes
- Page ID
- 24668
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Difficulties associated with use of tri-n-butyltin hydride have prompted chemists to search for alternative, hydrogen-atom sources, ones that avoid the problems associated with organotin compounds. Most attention has focused on organosilanes, compounds that do not have the toxicity associated with organotin reagents.4 Initially, the outlook was not promising because simple organosilanes are poor hydrogen-atom transfers when reacting with alkyl radicals and do not support chain reactions under normal conditions.4 Innovative ideas, however, have overcome these problems.