# 7.1: Acids and Bases - Experimental Definitions

Learning Objectives

• Examine properties of acids and bases.

Many people enjoy drinking coffee. A cup first thing in the morning helps start the day. But keeping the coffee maker clean can be a problem. Lime deposits build up after a while and slow down the brewing process. The best cure for this is to put vinegar (dilute acetic acid) in the pot and run it through the brewing cycle. The vinegar dissolves the deposits and cleans the maker, which will speed up the brewing process back to its original rate. Just be sure to run water through the brewing process after the vinegar, or you will get some really horrible coffee.

Perhaps you have eaten too much pizza and felt very uncomfortable hours later. This feeling is due to excess stomach acid being produced. The discomfort can be dealt with by taking an antacid. The base in the antacid will react with the $$\ce{HCl}$$ in the stomach and neutralize it, taking care of that unpleasant feeling. Figure $$\PageIndex{1}$$ provides some examples of acids and bases.

Figure $$\PageIndex{1}$$ Some examples of common household acids and bases.

## Acids

Acids are very common in some of the foods that we eat. Citrus fruits such as oranges and lemons contain citric acid and ascorbic acid, which is better known as vitamin C. Carbonated sodas contain phosphoric acid. Vinegar contains acetic acid. Your own stomach utilizes hydrochloric acid to digest food. Acids are a distinct class of compounds because of the properties of their aqueous solutions as outlined below:

1. Aqueous solutions of acids are electrolytes, meaning that they conduct electrical current. Some acids are strong electrolytes because they ionize completely in water, yielding a great many ions. Other acids are weak electrolytes that exist primarily in a non-ionized form when dissolved in water.
2. Acids have a sour taste. Lemons, vinegar, and sour candies all contain acids.
3. Acids change the color of certain acid-base indicators. Two common indicators are litmus and phenolphthalein. Blue litmus turns red in the presence of an acid, while phenolphthalein turns colorless.
4. Acids react with active metals to yield hydrogen gas. Recall that an activity series is a list of metals in descending order of reactivity. Metals that are above hydrogen in the activity series will replace the hydrogen from an acid in a single-replacement reaction, as shown below:
$\ce{Zn} \left( s \right) + \ce{H_2SO_4} \left( aq \right) \rightarrow \ce{ZnSO_4} \left( aq \right) + \ce{H_2} \left( g \right) \label{eq1}$
5. Acids react with bases to produce a salt compound and water. When equal moles of an acid and a base are combined, the acid is neutralized by the base. The products of this reaction are an ionic compound, which is labeled as a salt, and water.

Common examples: Lemons, oranges, vinegar, urine, sulfuric acid, hydrochloric acid

## Bases

Bases have properties that mostly contrast with those of acids.

1. Aqueous solutions of bases are also electrolytes. Bases can be either strong or weak, just as acids can.
2. Bases often have a bitter taste and are found in foods less frequently than acids. Many bases, like soaps, are slippery to the touch.
3. Bases also change the color of indicators. Litmus turns blue in the presence of a base while phenolphthalein turns pink.
4. Bases do not react with metals in the way that acids do.
5. Bases react with acids to produce a salt and water.

Common Examples: Soap, toothpaste, bleach, cleaning agents, limewater, ammonia water, sodium hydroxide.

Warning

Tasting chemicals and touching them are NOT good lab practices and should be avoided - in other words, don't do this at home.

## Summary

• A brief summary of properties of acids and bases are given.
• Properties of acids and bases mostly contrast each other.