10.13: Standard Reduction Potentials
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- Feb 11, 2024
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\newcommand{\avec}{\mathbf a} \newcommand{\bvec}{\mathbf b} \newcommand{\cvec}{\mathbf c} \newcommand{\dvec}{\mathbf d} \newcommand{\dtil}{\widetilde{\mathbf d}} \newcommand{\evec}{\mathbf e} \newcommand{\fvec}{\mathbf f} \newcommand{\nvec}{\mathbf n} \newcommand{\pvec}{\mathbf p} \newcommand{\qvec}{\mathbf q} \newcommand{\svec}{\mathbf s} \newcommand{\tvec}{\mathbf t} \newcommand{\uvec}{\mathbf u} \newcommand{\vvec}{\mathbf v} \newcommand{\wvec}{\mathbf w} \newcommand{\xvec}{\mathbf x} \newcommand{\yvec}{\mathbf y} \newcommand{\zvec}{\mathbf z} \newcommand{\rvec}{\mathbf r} \newcommand{\mvec}{\mathbf m} \newcommand{\zerovec}{\mathbf 0} \newcommand{\onevec}{\mathbf 1} \newcommand{\real}{\mathbb R} \newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]} \newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]} \newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]} \newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]} \newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]} \newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]} \newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]} \newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]} \newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]} \newcommand{\laspan}[1]{\text{Span}\{#1\}} \newcommand{\bcal}{\cal B} \newcommand{\ccal}{\cal C} \newcommand{\scal}{\cal S} \newcommand{\wcal}{\cal W} \newcommand{\ecal}{\cal E} \newcommand{\coords}[2]{\left\{#1\right\}_{#2}} \newcommand{\gray}[1]{\color{gray}{#1}} \newcommand{\lgray}[1]{\color{lightgray}{#1}} \newcommand{\rank}{\operatorname{rank}} \newcommand{\row}{\text{Row}} \newcommand{\col}{\text{Col}} \renewcommand{\row}{\text{Row}} \newcommand{\nul}{\text{Nul}} \newcommand{\var}{\text{Var}} \newcommand{\corr}{\text{corr}} \newcommand{\len}[1]{\left|#1\right|} \newcommand{\bbar}{\overline{\bvec}} \newcommand{\bhat}{\widehat{\bvec}} \newcommand{\bperp}{\bvec^\perp} \newcommand{\xhat}{\widehat{\xvec}} \newcommand{\vhat}{\widehat{\vvec}} \newcommand{\uhat}{\widehat{\uvec}} \newcommand{\what}{\widehat{\wvec}} \newcommand{\Sighat}{\widehat{\Sigma}} \newcommand{\lt}{<} \newcommand{\gt}{>} \newcommand{\amp}{&} \definecolor{fillinmathshade}{gray}{0.9}The following table provides Eo and Eo ́ values for selected reduction reactions. Values are from the following sources (primarily the first two):
- Bard, A. J.; Parsons, B.; Jordon, J., eds. Standard Potentials in Aqueous Solutions, Dekker: New York, 1985
- Milazzo, G.; Caroli, S.; Sharma, V. K. Tables of Standard Electrode Potentials, Wiley: London, 1978;
- Swift, E. H.; Butler, E. A. Quantitative Measurements and Chemical Equilibria, Freeman: New York, 1972.
- Bratsch, S. G. "Standard Electrode Potentials and Temperature Coefficients in Water at 298.15K, J. Phys. Chem. Ref. Data, 1989, 18, 1–21.
- Latimer, W. M. Oxidation Potentials, 2nd. Ed., Prentice-Hall: Englewood Cliffs, NJ, 1952
Solids, gases, and liquids are identified; all other species are aqueous. Reduction reactions in acidic solution are written using H+ in place of H3O+. You may rewrite a reaction by replacing H+ with H3O+ and adding to the opposite side of the reaction one molecule of H2O per H+; thus
H3AsO4 + 2H+ +2e– \rightleftharpoons HAsO2 +2H2O
becomes
H3AsO4 + 2H3O+ +2e– \rightleftharpoons HAsO2 +4H2O
Conditions for formal potentials (Eo ́) are listed next to the potential.
For most of the reduction half-reactions gathered here, there are minor differences in values provided by the references above. In most cases, these differences are small and will not affect calculations. In a few cases the differences are not insignificant and the user may find discrepancies in calculations. For example, Bard, Parsons, and Jordon report an Eo value of –1.285 V for
\text{Zn(OH)}_4^{2-} + 2e^- \rightleftharpoons \text{Zn}(s) + 4\text{OH}^-\nonumber
while Milazzo, Caroli, and Sharma report the value as –1.214 V, Swift reports the value as –1.22, Bratsch reports the value as –1.199 V, and Latimer reports the value as –1.216 V.
Aluminum | E (V) | Eo ́ (V) |
---|---|---|
\text{Al}^{3+} + 3e^- \rightleftharpoons \text{Al}(s) |
–1.676 | |
\text{Al(OH)}_4^- + 3e^- \rightleftharpoons \text{Al}(s) + 4\text{OH}^- | –2.310 | |
\text{AlF}_6^{3-} + 3e^- \rightleftharpoons \text{Al}(s) + 6\text{F}^- |
–2.07 |
Antimony | E (V) | Eo ́ (V) |
---|---|---|
\text{Sb} + 3\text{H}^+ + 3e^- \rightleftharpoons \text{SbH}_3(g) | –0.510 | |
\text{Sb}_2\text{O}_5 + 6\text{H}^+ + 4e^- \rightleftharpoons 2\text{SbO}^+ + 3\text{H}_2\text{O}(l) | 0.605 | |
\text{SbO}^+ + 2\text{H}^+ + 3e^- \rightleftharpoons \text{Sb}(s) + \text{H}_2\text{O}(l) | 0.212 |
Arsenic | E (V) | Eo ́ (V) |
---|---|---|
\text{As}(s) + 3\text{H}^+ + 3e^- \rightleftharpoons \text{AsH}_3(g) | –0.225 | |
\text{H}_3\text{AsO}_4 + 2\text{H}^+ + 2e^- \rightleftharpoons \text{HAsO}_2 + 2\text{H}_2\text{O}(l) | 0.560 | |
\text{HAsO}_2 + 3\text{H}^+ + 3e^- \rightleftharpoons \text{As}(s) + 2\text{H}_2\text{O}(l) | 0.240 |
Barium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ba}^{2+} + 2e^- \rightleftharpoons \text{Ba}(s) |
–2.92 | |
\text{BaO}(s) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{Ba}(s) + \text{H}_2\text{O}(l) |
–2.166 |
Beryllium | E (V) | Eo ́ (V) |
---|---|---|
\text{Be}^{2+} + 2e^- \rightleftharpoons \text{Be}(s) |
–1.99 |
Bismuth | E (V) | Eo ́ (V) |
---|---|---|
\text{Bi}^{3+} + 3e^- \rightleftharpoons \text{Bi}(s) |
0.317 |
|
\text{BiCl}_4^- + 3e^- \rightleftharpoons \text{Bi}(s) + 4\text{Cl}^- |
0.199 |
Boron | E (V) | Eo ́ (V) |
---|---|---|
\text{B(OH)}_3 + 3\text{H}^+ + 3e^- \rightleftharpoons \text{B}(s) + 3\text{H}_2\text{O}(l) |
–0.890 |
|
\text{B(OH)}_4^- + 3e^- \rightleftharpoons \text{B}(s) + 4\text{OH}^- |
–1.811 |
Bromine | E (V) | Eo ́ (V) |
---|---|---|
\text{Br}_2(l) + 2e^- \rightleftharpoons 2\text{Br}^- |
1.087 |
|
\text{HOBr} + \text{H}^+ + 2e^- \rightleftharpoons \text{Br}^- + \text{H}_2\text{O}(l) |
1.341 |
|
\text{HOBr} + \text{H}^+ + e^- \rightleftharpoons \frac{1}{2} \text{Br}_2 + \text{H}_2\text{O}(l) |
1.604 |
|
\text{BrO}^- + \text{H}_2\text{O}(l) + 2e^- \rightleftharpoons \text{Br}^- + 2\text{OH}^- |
0.76 in 1 M NaOH |
|
\text{BrO}_3^- +6\text{H}^+ + 5e^- \rightleftharpoons \frac{1}{2} \text{Br}_2(l) + 3\text{H}_2\text{O}(l) |
1.5 |
|
\text{BrO}_3^- + 6\text{H}^+ +6e^- \rightleftharpoons \text{Br}^- + 3\text{H}_2\text{O}(l) |
1.478 |
Cadmium | E (V) | Eo ́ (V) |
---|---|---|
\text{Cd}^{2+} + 2e^- \rightleftharpoons \text{Cd}(s) |
–0.4030 |
|
\text{Cd(CN)}_4^{2-} + 2e^- \rightleftharpoons \text{Cd}(s) + 4\text{CN}^- |
–0.943 |
|
\text{Cd(NH}_3)_4^{2+} + 2e^- \rightleftharpoons \text{Cd}(s) + 4\text{NH}_3 |
–0.622 |
Calcium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ca}^{2+} + 2e^- \rightleftharpoons \text{Ca}(s) |
–2.84 |
Carbon | E (V) | Eo ́ (V) |
---|---|---|
\text{CO}_2(g) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{CO}(g) + \text{H}_2\text{O}(l) |
–0.106 |
|
\text{CO}_2(g) + 2\text{H}^+ +2e^- \rightleftharpoons \text{HCO}_2\text{H} |
–0.20 |
|
2\text{CO}_2(g) + 2\text{H}^+ +2e^- \rightleftharpoons \text{H}_2\text{C}_2\text{O}_4 |
–0.481 |
|
\text{HCHO} + 2\text{H}^+ + 2e^- \rightleftharpoons \text{CH}_3\text{OH} |
0.2323 |
Cerium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ce}^{3+} + 3e^- \rightleftharpoons \text{Ce}(s) |
–2.336 |
|
\text{Ce}^{4+} + e^- \rightleftharpoons \text{Ce}^{3+} |
1.72 |
1.70 in 1 M HClO4 1.44 in 1 M H2SO4 1.61 in 1 M HNO3 1.28 in 1 M HCl |
Chlorine | E (V) | Eo ́ (V) |
---|---|---|
\text{Cl}_2(g) + 2e^- \rightleftharpoons 2\text{Cl}^- |
1.396 |
|
\text{ClO}^- + \text{H}_2\text{O}(l) + e^- \rightleftharpoons \frac{1}{2} \text{Cl}_2(g) + 2\text{OH}^- |
0.421 in 1 M NaOH |
|
\text{ClO}^- + \text{H}_2\text{O}(l) + 2e^- \rightleftharpoons \text{Cl}^- + 2\text{OH}^- |
0.890 in 1 M NaOH |
|
\text{HClO}_2 + 2\text{H}^+ + 2e^- \rightleftharpoons \text{HOCl} + \text{H}_2\text{O}(l) |
1.64 |
Chlorine | E (V) | Eo ́ (V) |
---|---|---|
\text{ClO}_3^- + 2\text{H}^+ + e^- \rightleftharpoons \text{ClO}_2(g) + \text{H}_2\text{O}(l) |
1.175 |
|
\text{ClO}_3^- + 3\text{H}^+ + 2e^- \rightleftharpoons \text{HClO}_2 + \text{H}_2\text{O}(l) |
1.181 |
|
\text{ClO}_4^- + 2\text{H}^+ +2e^- \rightleftharpoons \text{ClO}_3^- + \text{H}_2\text{O}(l) |
1.201 |
Chromium | E (V) | Eo ́ (V) |
---|---|---|
\text{Cr}^{3+} + 3e^- \rightleftharpoons \text{Cr}(s) |
–0.424 |
|
\text{Cr}^{2+} + 2e^- \rightleftharpoons \text{Cr}(s) |
–0.90 |
|
\text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ + 6e^- \rightleftharpoons 2\text{Cr}^{3+} + 7\text{H}_2\text{O}(l) |
1.36 |
|
\text{CrO}_4^{2-} + 4\text{H}_2\text{O}(l) + 3e^- \rightleftharpoons \text{Cr(OH)}_4^- + 4\text{OH}^- |
–0.13 in 1 M NaOH |
Cobalt | E (V) | Eo ́ (V) |
---|---|---|
\text{Co}^{2+} + 2e^- \rightleftharpoons \text{Co}(s) |
–0.277 |
|
\text{Co}^{3+} + 3e^- \rightleftharpoons \text{Co}(s) |
1.92 |
|
\text{Co(NH}_3)_6^{3+} + e^- \rightleftharpoons \text{Co(NH}_3)_6^{2+} |
0.1 |
|
\text{Co(OH)}_3(s) + e^- \rightleftharpoons \text{Co(OH)}_2(s) + \text{OH}^- |
0.17 |
|
\text{Co(OH)}_2(s) + 2e^- \rightleftharpoons \text{Co}(s) + 2\text{OH}^- |
–0.746 |
Copper | E (V) | Eo ́ (V) |
---|---|---|
\text{Cu}^+ + e^- \rightleftharpoons \text{Cu}(s) |
0.520 |
|
\text{Cu}^{2+} + e^- \rightleftharpoons \text{Cu}^+ |
0.159 |
|
\text{Cu}^{2+} + 2e^- \rightleftharpoons \text{Cu}(s) |
0.3419 |
|
\text{Cu}^{2+} + \text{I}^- + e^- \rightleftharpoons \text{CuI}(s) |
0.86 |
|
\text{Cu}^{2+} + \text{Cl}^- + e^- \rightleftharpoons \text{CuCl}(s) |
0.559 |
Fluorine | E (V) | Eo ́ (V) |
---|---|---|
\text{F}_2(g) + 2\text{H}^+ + 2e^- \rightleftharpoons 2\text{HF}(g) |
3.053 |
|
\text{F}_2(g) + 2e^- \rightleftharpoons 2\text{F}^- |
2.87 |
Gallium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ga}^{3+} + 3e^- \rightleftharpoons \text{Ga}(s) |
–0.529 |
Gold | E (V) | Eo ́ (V) |
---|---|---|
\text{Au}^+ + e^- \rightleftharpoons \text{Au}(s) |
1.83 |
|
\text{Au}^{3+} + 2e^- \rightleftharpoons \text{Au}^+ |
1.36 |
|
\text{Au}^{3+} + 3e^- \rightleftharpoons \text{Au}(s) |
1.52 |
|
\text{AuCl}_4^- + 3e^- \rightleftharpoons \text{Au}(s) + 4\text{Cl}^- |
1.002 |
Hydrogen | E (V) | Eo ́ (V) |
---|---|---|
2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_2 (g) |
0.00000 |
|
\text{H}_2\text{O}(l) + e^- \rightleftharpoons \frac{1}{2} \text{H}_2(g) + \text{OH}^- |
–0.828 |
Iodine | E (V) | Eo ́ (V) |
---|---|---|
\text{I}_2(s) + 2e^- \rightleftharpoons 2\text{I}^- |
0.5355 |
Iodine | E (V) | Eo ́ (V) |
---|---|---|
\text{I}_3^- + 2e^- \rightleftharpoons 3\text{I}^- |
0.536 |
|
\text{HIO} + \text{H}^+ + 2e^- \rightleftharpoons \text{I}^- + \text{H}_2\text{O}(l) |
0.985 |
|
\text{IO}_3^- + 6\text{H}^+ + 5e^- \rightleftharpoons \frac{1}{2} \text{I}_2(s) + 3\text{H}_2\text{O}(l) |
1.195 |
|
\text{IO}_3^- + 3\text{H}_2\text{O}(l) + 6e^- \rightleftharpoons \text{I}^- +6\text{OH}^- |
0.257 |
Iron | E (V) | Eo ́ (V) |
---|---|---|
\text{Fe}^{2+} + 2e^- \rightleftharpoons \text{Fe}(s) |
–0.44 |
|
\text{Fe}^{3+} + 3e^- \rightleftharpoons \text{Fe}(s) |
–0.037 |
|
\text{Fe}^{3+} + e^- \rightleftharpoons \text{Fe}^{2+} |
0.771 |
0.70 in 1 M HCl 0.767 in 1 M HClO4 0.746 in 1 M HNO3 0.68 in 1 M H2SO4 0.44 in 0.3 M H3PO4 |
\text{Fe(CN)}_6^{3-} + e^- \rightleftharpoons \text{Fe(CN)}_6^{4-} |
0.356 |
|
\text{Fe(phen)}_3^{3+} + e^- \rightleftharpoons \text{Fe(phen)}_3^{2+} |
1.147 |
Lanthanum | E (V) | Eo ́ (V) |
---|---|---|
\text{La}^{3+} + 3e^- \rightleftharpoons \text{La}(s) |
–2.38 |
Lead | E (V) | Eo ́ (V) |
---|---|---|
\text{Pb}^{2+} + 2e^- \rightleftharpoons \text{Pb}(s) |
–0.126 |
|
\text{PbO}_2(s) + 4\text{H}^+ + 2e^- \rightleftharpoons \text{Pb}^{2+} + 2\text{H}_2\text{O}(l) |
1.46 |
|
\text{PbO}_2(s) + \text{SO}_4^{2-} + 4\text{H}^+ + 2e^- \rightleftharpoons \text{PbSO}_4(s) + 2\text{H}_2\text{O}(l) |
1.690 |
|
\text{PbSO}_4(s) + 2e^- \rightleftharpoons \text{Pb}(s) + \text{SO}_4^{2-} |
–0.356 |
Lithium | E (V) | Eo ́ (V) |
---|---|---|
\text{Li}^+ + e^- \rightleftharpoons \text{Li}(s) |
–3.040 |
Magnesium | E (V) | Eo ́ (V) |
---|---|---|
\text{Mg}^{2+} + 2e^- \rightleftharpoons \text{Mg}(s) |
–2.356 |
|
\text{Mg(OH)}_2(s) + 2e^- \rightleftharpoons \text{Mg}(s) + 2\text{OH}^- |
–2.687 |
Manganese | E (V) | Eo ́ (V) |
---|---|---|
\text{Mn}^{2+} + 2e^- \rightleftharpoons \text{Mn}(s) |
–1.17 |
|
\text{Mn}^{3+} + e^- \rightleftharpoons \text{Mn}^{2+} |
1.5 |
|
\text{MnO}_2(s) + 4\text{H}^+ + 2e^- \rightleftharpoons \text{Mn}^{2+} + 2\text{H}_2\text{O}(l) |
1.23 |
|
\text{MnO}_4^- + 4\text{H}^+ +3e^- \rightleftharpoons \text{MnO}_2(s) + 2\text{H}_2\text{O}(l) |
1.70 |
|
\text{MnO}_4^- + 8\text{H}^+ + 5e^- \rightleftharpoons \text{Mn}^{2+} + 4\text{H}_2\text{O}(l) |
1.51 |
|
\text{MnO}_4^- + 2\text{H}_2\text{O}(l) + 3e^- \rightleftharpoons \text{MnO}_2(s) + 4\text{OH}^- |
0.60 |
Mercury | E (V) | Eo ́ (V) |
---|---|---|
\text{Hg}^{2+} + 2e^- \rightleftharpoons \text{Hg}(l) |
0.8535 |
|
2\text{Hg}^{2+} +2e^- \rightleftharpoons \text{Hg}_2^{2+} |
0.911 |
Mercury | E (V) | Eo ́ (V) |
---|---|---|
\text{Hg}_2^{2+} + 2e^- \rightleftharpoons 2\text{Hg}(l) |
0.7960 |
|
\text{Hg}_2\text{Cl}_2(s) + 2e^- \rightleftharpoons 2\text{Hg}(l) + 2\text{Cl}^- |
0.2682 |
|
\text{HgO}(s) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{Hg}(l) + \text{H}_2\text{O}(l) |
0.926 |
|
\text{Hg}_2\text{Br}_2(s) + 2e^- \rightleftharpoons 2\text{Hg}(l) + 2\text{Br}^- |
1.392 |
|
\text{Hg}_2\text{I}_2(s) + 2e^- \rightleftharpoons 2\text{Hg}(l) + 2\text{I}^- |
–0.0405 |
Molybdenum | E (V) | Eo ́ (V) |
---|---|---|
\text{Mo}^{3+} + 3e^- \rightleftharpoons \text{Mo}(s) |
–0.2 |
|
\text{MoO}_2(s) + 4\text{H}^+ + 4e^- \rightleftharpoons \text{Mo}(s) + 2\text{H}_2\text{O}(l) |
–0.152 |
|
\text{MoO}_4^{2-} + 4\text{H}_2\text{O}(l) + 6e^- \rightleftharpoons \text{Mo}(s) + 8\text{OH}^- |
–0.913 |
Nickel | E (V) | Eo ́ (V) |
---|---|---|
\text{Ni}^{2+} + 2e^- \rightleftharpoons \text{Ni}(s) |
–0.257 |
|
\text{Ni(OH)}_2(s) + 2e^- \rightleftharpoons \text{Ni}(s) + 2\text{OH}^- |
–0.72 |
|
\text{Ni(NH}_3)_6^{2+} + 2e^- \rightleftharpoons \text{Ni}(s) + 6\text{NH}_3 |
–0.49 |
Nitrogen | E (V) | Eo ́ (V) |
---|---|---|
\text{N}_2(g) + 5\text{H}^+ + 4e^- \rightleftharpoons \text{N}_2\text{H}_5^+ |
–0.23 |
|
\text{N}_2\text{O}(g) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{N}_2(g) + \text{H}_2\text{O}(l) |
1.77 |
|
2\text{NO}(g) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{N}_2\text{O}(g) + \text{H}_2\text{O}(l) |
1.59 |
|
\text{HNO}_2 + \text{H}^+ + e^- \rightleftharpoons \text{NO}(g) + \text{H}_2\text{O}(l) |
0.996 |
|
2\text{HNO}_2 + 4\text{H}^+ + 4e^- \rightleftharpoons \text{N}_2\text{O}(g) + 3\text{H}_2\text{O}(l) |
1.297 |
|
\text{NO}_3^- + 3\text{H}^+ + 2e^- \rightleftharpoons \text{HNO}_2 + \text{H}_2\text{O}(l) |
0.94 |
Oxygen | E (V) | Eo ́ (V) |
---|---|---|
\text{O}_2(g) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_2\text{O}_2 |
0.695 |
|
\text{O}_2(g) + 4\text{H}^+ + 4e^- \rightleftharpoons 2\text{H}_2\text{O}(l) |
1.229 |
|
\text{H}_2\text{O}_2 + 2\text{H}^+ + 2e^- \rightleftharpoons 2\text{H}_2\text{O}(l) |
1.763 |
|
\text{O}_2(g) + 2\text{H}_2\text{O}(l) + 4e^- \rightleftharpoons 4\text{OH}^- |
0.401 |
|
\text{O}_3(g) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{O}_2(g) + \text{H}_2\text{O}(l) |
2.07 |
Phosphorous | E (V) | Eo ́ (V) |
---|---|---|
\text{P}(s, white) + 3\text{H}^+ + 3e^- \rightleftharpoons \text{PH}_3(g) |
–0.063 |
|
\text{H}_3\text{PO}_3 + 2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_3\text{PO}_2 + \text{H}_2\text{O}(l) |
–0.499 |
|
\text{H}_3\text{PO}_4 + 2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_3\text{PO}_3 + \text{H}_2\text{O}(l) |
–0.276 |
Platinum | E (V) | Eo ́ (V) |
---|---|---|
\text{Pt}^{2+} + 2e^- \rightleftharpoons \text{Pt}(s) |
1.188 |
|
\text{PtCl}_4^{2-} + 2e^- \rightleftharpoons \text{Pt}(s) + 4\text{Cl}^- |
0.758 |
Potasium | E (V) | Eo ́ (V) |
---|---|---|
\text{K}^+ + e^- \rightleftharpoons \text{K}(s) |
–2.924 |
Ruthenium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ru}^{3+} + 3e^- \rightleftharpoons \text{Ru}(s) |
0.249 |
|
\text{RuO}_2(s) + 4\text{H}^+ + 4e^- \rightleftharpoons \text{Ru}(s) + 2\text{H}_2\text{O}(l) |
0.68 |
|
\text{Ru(NH}_3)_6^{3+} + e^- \rightleftharpoons \text{Ru(NH}_3)_6^{2+} |
0.10 |
|
\text{Ru(CN)}_6^{3-} + e^- \rightleftharpoons \text{Ru(CN)}_6^{4-} |
0.86 |
Selenium | E (V) | Eo ́ (V) |
---|---|---|
\text{Se}(s) + 2e^- \rightleftharpoons \text{Se}^{2-} |
–0.67 in 1 M NaOH |
|
\text{Se}(s) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_2\text{Se}(g) |
–0.115 |
|
\text{H}_2\text{SeO}_3 + 4\text{H}^+ + 4e^- \rightleftharpoons \text{Se}(s) + 3\text{H}_2\text{O}(l) |
0.74 |
|
\text{SeO}_4^{3-} + 4\text{H}^+ + e^- \rightleftharpoons \text{H}_2\text{SeO}_3 + \text{H}_2\text{O}(l) |
1.151 |
Silicon | E (V) | Eo ́ (V) |
---|---|---|
\text{SiF}_6^{2-} + 4e^- \rightleftharpoons \text{Si}(s) + 6\text{F}^- |
–1.37 |
|
\text{SiO}_2(s) + 4\text{H}^+ + 4e^- \rightleftharpoons \text{Si}(s) + 2\text{H}_2\text{O}(l) |
–0.909 |
|
\text{SiO}_2(s) + 8\text{H}^+ + 8e^- \rightleftharpoons \text{SiH}_4(g) + 2\text{H}_2\text{O}(l) |
–0.516 |
Silver | E (V) | Eo ́ (V) |
---|---|---|
\text{Ag}^+ + e^- \rightleftharpoons \text{Ag}(s) |
0.7996 |
|
\text{AgBr}(s) + e^- \rightleftharpoons \text{Ag}(s) + \text{Br}^- |
0.071 |
|
\text{Ag}_2\text{C}_2\text{O}_4(s) + 2e^- \rightleftharpoons 2\text{Ag}(s) + \text{C}_2\text{O}_4^{2-} |
0.47 |
|
\text{AgCl}(s) + e^- \rightleftharpoons \text{Ag}(s) + \text{Cl}^- |
0.2223 |
|
\text{AgI}(s) + e^- \rightleftharpoons \text{Ag}(s) + \text{I}^- |
–0.152 |
|
\text{Ag}_2\text{S}(s) + 2e^- \rightleftharpoons 2\text{Ag}(s) + \text{S}^{2-} |
–0.71 |
|
\text{Ag(NH}_3)_2^+ + e^- \rightleftharpoons \text{Ag}(s) + 2\text{NH}_3 |
–0.373 |
Sodium | E (V) | Eo ́ (V) |
---|---|---|
\text{Na}^+ + e^- \rightleftharpoons \text{Na}(s) |
–2.713 |
Strontium | E (V) | Eo ́ (V) |
---|---|---|
\text{Sr}^{2+} + 2e^- \rightleftharpoons \text{Sr}(s) |
–2.89 |
Sulfur | E (V) | Eo ́ (V) |
---|---|---|
\text{S}(s) + 2e^- \rightleftharpoons \text{S}^{2-} |
–0.407 |
|
\text{S}(s) + 2\text{H}^+ + 2e^- \rightleftharpoons \text{H}_2\text{S}(g) |
0.144 |
|
\text{S}_2\text{O}_6^{2-} + 4\text{H}^+ + 2e^- \rightleftharpoons 2\text{H}_2\text{SO}_3 |
0.569 |
|
\text{S}_2\text{O}_8^{2-} + 2e^- \rightleftharpoons 2\text{SO}_4^{2-} |
1.96 |
|
\text{S}_4\text{O}_6^{2-} + 2e^- \rightleftharpoons 2\text{S}_2\text{O}_3^{2-} |
0.080 |
|
2\text{SO}_3^{2-} + 2\text{H}_2\text{O}(l) + 2e^- \rightleftharpoons \text{S}_2\text{O}_4^{2-} + 4\text{OH}^- |
–1.13 |
|
2\text{SO}_3^{2-} + 3\text{H}_2\text{O}(l) + 4e^- \rightleftharpoons \text{S}_2\text{O}_3^{2-} + 6\text{OH}^- |
–0.576 in 1 M NaOH |
|
2\text{SO}_4^{2-} + 4\text{H}^+ + 2e^- \rightleftharpoons \text{S}_2\text{O}_6^{2-} + 2\text{H}_2\text{O}(l) |
–0.25 |
|
\text{SO}_4^{2-} + \text{H}_2\text{O}(l) + 2e^- \rightleftharpoons \text{SO}_3^{2-} + 2\text{OH}^- |
–0.936 |
|
\text{SO}_4^{2-} + 4\text{H}^+ + 2e^- \rightleftharpoons \text{H}_2\text{SO}_3 + \text{H}_2\text{O}(l) |
0.172 |
Thallium | E (V) | Eo ́ (V) |
---|---|---|
\text{Tl}^{3+} + 2e^- \rightleftharpoons \text{Tl}^+ |
1.25 in 1 M HClO4 0.77 in 1 M HCl |
|
\text{Tl}^{3+} + 3e^- \rightleftharpoons \text{Tl}(s) |
0.742 |
Tin | E (V) | Eo ́ (V) |
---|---|---|
\text{Sn}^{2+} + 2e^- \rightleftharpoons \text{Sn}(s) |
–0.19 in 1 M HCl |
|
\text{Sn}^{4+} + 2e^- \rightleftharpoons \text{Sn}^{2+} |
0.154 |
0.139 in 1 M HCl |
Titanium | E (V) | Eo ́ (V) |
---|---|---|
\text{Ti}^{2+} + 2e^- \rightleftharpoons \text{Ti}(s) |
–0.163 |
|
\text{Ti}^{3+} + e^- \rightleftharpoons \text{Ti}^{2+} |
–0.37 |
Tungsten | E (V) | Eo ́ (V) |
---|---|---|
\text{WO}_2(s) + 4\text{H}^+ + 4e^- \rightleftharpoons \text{W}(s) + 2\text{H}_2\text{O}(l) |
–0.119 |
|
\text{WO}_3(s) + 6\text{H}^+ + 6e^- \rightleftharpoons \text{W}(s) + 3\text{H}_2\text{O}(l) |
–0.090 |
Uranium | E (V) | Eo ́ (V) |
---|---|---|
\text{U}^{3+} + 3e^- \rightleftharpoons \text{U}(s) |
–1.66 |
|
\text{U}^{4+} + e^- \rightleftharpoons \text{U}^{3+} |
–0.52 |
|
\text{UO}_2^+ + 4\text{H}^+ + e^- \rightleftharpoons \text{U}^{4+} + 2\text{H}_2\text{O}(l) |
0.27 |
|
\text{UO}_2^{2+} + e^- \rightleftharpoons \text{UO}_2^+ |
0.16 |
|
\text{UO}_2^{2+} + 4\text{H}^+ + 2e^- \rightleftharpoons \text{U}^{4+} + 2\text{H}_2\text{O}(l) |
0.327 |
Vanadium | E (V) | Eo ́ (V) |
---|---|---|
\text{V}^{2+} + 2e^- \rightleftharpoons \text{V}(s) |
–1.13 |
|
\text{V}^{3+} + e^- \rightleftharpoons \text{V}^{2+} |
–0.255 |
|
\text{VO}^{2+} + 2\text{H}^+ + e^- \rightleftharpoons \text{V}^{3+} + \text{H}_2\text{O}(l) |
0.337 |
|
\text{VO}_2^{+} + 2\text{H}^+ + e^- \rightleftharpoons \text{VO}^{2+} + \text{H}_2\text{O}(l) |
1.000 |
Zinc | E (V) | Eo ́ (V) |
---|---|---|
\text{Zn}^{2+} + 2e^- \rightleftharpoons \text{Zn}(s) |
–0.7618 |
|
\text{Zn(OH)}_4^{2-} + 2e^- \rightleftharpoons \text{Zn}(s) + 4\text{OH}^- |
–1.285 |
|
\text{Zn(NH}_3)_4^{2+} + 2e^- \rightleftharpoons \text{Zn}(s) + 4\text{NH}_3 |
–1.04 |
|
\text{Zn(CN)}_4^{2-} + 2e^- \rightleftharpoons \text{Zn}(s) + 4\text{CN}^- |
–1.34 |