Glossary
- Page ID
- 279536
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)
\( \newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\)
( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\)
\( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)
\( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\)
\( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)
\( \newcommand{\Span}{\mathrm{span}}\)
\( \newcommand{\id}{\mathrm{id}}\)
\( \newcommand{\Span}{\mathrm{span}}\)
\( \newcommand{\kernel}{\mathrm{null}\,}\)
\( \newcommand{\range}{\mathrm{range}\,}\)
\( \newcommand{\RealPart}{\mathrm{Re}}\)
\( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)
\( \newcommand{\Argument}{\mathrm{Arg}}\)
\( \newcommand{\norm}[1]{\| #1 \|}\)
\( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)
\( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\AA}{\unicode[.8,0]{x212B}}\)
\( \newcommand{\vectorA}[1]{\vec{#1}} % arrow\)
\( \newcommand{\vectorAt}[1]{\vec{\text{#1}}} % arrow\)
\( \newcommand{\vectorB}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vectorC}[1]{\textbf{#1}} \)
\( \newcommand{\vectorD}[1]{\overrightarrow{#1}} \)
\( \newcommand{\vectorDt}[1]{\overrightarrow{\text{#1}}} \)
\( \newcommand{\vectE}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{\mathbf {#1}}}} \)
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)
\( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)
\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Words (or words that have the same definition) | The definition is case sensitive | (Optional) Image to display with the definition [Not displayed in Glossary, only in pop-up on pages] | (Optional) Caption for Image | (Optional) External or Internal Link | (Optional) Source for Definition |
---|---|---|---|---|---|
(Eg. "Genetic, Hereditary, DNA ...") | (Eg. "Relating to genes or heredity") | ![]() | The infamous double helix | https://bio.libretexts.org/ | CC-BY-SA; Delmar Larsen |
Word(s) | Definition | Image | Caption | Link | Source |
---|---|---|---|---|---|
Acid Dissociation Constants | The equilibrium constants for the dissociation of acids into hydrogen ions and their conjugate base in solution. | ||||
Activity Effects | The changes in the effective concentration of ions in a solution, accounting for interactions between ions that influence their behavior. | ||||
Amperometric Methods | Electrochemical techniques where the current is measured as a function of applied voltage to analyze a sample. | ||||
Buoyancy of Air | The correction needed for mass measurements, considering the density of air when weighing objects in a laboratory balance. | ||||
Calibration Curve | A graphical representation of the relationship between the known concentrations of standards and their corresponding analytical responses. | ||||
Chemical Kinetics | The study of the rates at which chemical reactions occur and the factors influencing these rates. | ||||
Chromatography | A separation technique based on the differential affinities of compounds in a mixture to stationary and mobile phases. | ||||
Column Chromatography | A chromatographic method where the stationary phase is packed in a column and the mobile phase carries the sample through it. | ||||
Complexation Titrations | A type of titrimetric method where the analyte forms a complex with a reagent, which is used to determine its concentration. | ||||
Critical Values for t-Test | The values used to determine statistical significance in hypothesis testing using the t-distribution. | ||||
Detection Limits | The smallest quantity of an analyte that can be reliably detected but not necessarily quantified in a sample. | ||||
Determination | The process of quantifying the amount of analyte in a sample. | ||||
Dixon's Q-Test | A statistical test used to identify outliers in a set of data points. | ||||
Electrophoresis | A separation technique where charged particles move through a gel under the influence of an electric field. | ||||
Electrochemistry | The study of chemical processes that involve the movement of electrons, often used in potentiometry, coulometry, and voltammetry. | ||||
Emission Spectroscopy | A spectroscopic method in which atoms or molecules emit light at characteristic wavelengths after being excited. | ||||
Excel and R | Software tools used for statistical analysis, data visualization, and conducting various types of analytical chemistry computations. | ||||
Formation Constants | The equilibrium constants for the formation of complex ions from a metal and a ligand. | ||||
F-Test | A statistical test used to compare two variances to determine if they are significantly different. | ||||
Gravimetric Methods | Analytical methods based on the measurement of mass, typically involving the precipitation of a compound. | ||||
Grubb's Test | A statistical test used for detecting outliers in small data sets. | ||||
High-Performance Liquid Chromatography, HPLC | A modern chromatographic technique that uses high-pressure pumps to force solvents through a column to separate compounds in a liquid sample. | ||||
Hydrogen Ion Concentration | A measure of the concentration of H⁺ ions in a solution, typically used to determine the pH of a solution. | ||||
Instrumental Methods | Analytical techniques that involve the use of instruments, such as spectrometers or chromatographs, to measure the concentration of analytes. | ||||
Interferents | Substances that affect the accuracy of the analysis by interfering with the measurement of the analyte. | ||||
Kinetic Methods | Techniques that rely on the measurement of the rate of a chemical reaction to determine the concentration of analytes. | ||||
Le Chatelier’s Principle | A principle in chemistry that states that a system at equilibrium will adjust to counteract any changes imposed on it. | ||||
Linear Regression | A statistical method for modeling the relationship between a dependent variable and one or more independent variables, often used for calibration curves. | ||||
Liquid-Liquid Extractions | A separation technique where two immiscible liquids are used to separate components based on their solubilities. | ||||
Method Validation | The process of confirming that an analytical method produces accurate, reliable, and consistent results within defined limits. | ||||
Measurement Uncertainty | The doubt that exists about the result of any measurement due to possible errors and variability in the process. | ||||
Normal Distribution | A symmetric, bell-shaped probability distribution, often used to model the distribution of experimental errors. | ||||
Normality | A concentration unit for acids and bases in solution, defined as the gram equivalent weight per liter of solution. | ||||
Precipitation Gravimetry | A gravimetric method where a substance is precipitated out of a solution and weighed to determine its concentration. | ||||
Preconcentration | The process of increasing the concentration of an analyte in a sample prior to measurement to improve detection. | ||||
Propagation of Uncertainty | The process of calculating the uncertainty of a result derived from multiple measurements with associated uncertainties. | ||||
Quality Assurance | The systematic processes implemented to ensure the quality of laboratory results, including calibration, validation, and verification of methods. | ||||
Quality Control | A set of procedures to ensure that analytical measurements meet predefined standards and specifications. | ||||
Redox Titrations | Titrations based on the transfer of electrons between the analyte and the titrant, often used to determine the concentration of oxidizing or reducing agents. | ||||
Regression Analysis | A statistical method for modeling the relationship between a dependent variable and one or more independent variables, especially useful in analytical chemistry for creating calibration curves. | ||||
Reagent Blank | A sample containing all the components of the test except the analyte, used to correct for the interference from reagents. | ||||
Solubility Products | Equilibrium constants for the dissolution of sparingly soluble salts in water. | ||||
Spectroscopic Methods | Techniques that measure the interaction of light with matter to identify or quantify substances based on their absorption, emission, or scattering properties. | ||||
Standard Reduction Potentials | The tendency of a substance to gain electrons, used in electrochemical analysis. | ||||
Stoichiometry | The calculation of the quantities of reactants and products involved in chemical reactions. | ||||
Titrimetry | A quantitative analytical method where a reagent of known concentration is added to a solution of the analyte until the reaction reaches a known endpoint. | ||||
Titration Curves | Graphs used in titrimetry to show the change in a property (like pH or conductivity) as a titrant is added. | ||||
Uncertainty | A parameter that characterizes the dispersion of the values attributed to a measured quantity, often arising from instrumental limitations or experimental error. | ||||
Voltammetry | An electrochemical technique where the current is measured as a function of applied voltage to study the concentration of an analyte. | ||||
Weighing by Difference | A method for determining the mass of a substance by subtracting the mass of the container from the total mass after the substance is added. | ||||
X-ray Fluorescence | A type of spectroscopic technique that uses X-rays to analyze the elemental composition of materials. | ||||
Zero-Order Reactions | Reactions where the rate of reaction is independent of the concentration of the reactants. |