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Chemistry LibreTexts

Glossary

  • Page ID
    279536
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    Glossary Entries
    Word(s)DefinitionImageCaptionLinkSource
    Acid Dissociation ConstantsThe equilibrium constants for the dissociation of acids into hydrogen ions and their conjugate base in solution.    
    Activity EffectsThe changes in the effective concentration of ions in a solution, accounting for interactions between ions that influence their behavior.    
    Amperometric MethodsElectrochemical techniques where the current is measured as a function of applied voltage to analyze a sample.    
    Buoyancy of AirThe correction needed for mass measurements, considering the density of air when weighing objects in a laboratory balance.    
    Calibration CurveA graphical representation of the relationship between the known concentrations of standards and their corresponding analytical responses.    
    Chemical KineticsThe study of the rates at which chemical reactions occur and the factors influencing these rates.    
    ChromatographyA separation technique based on the differential affinities of compounds in a mixture to stationary and mobile phases.    
    Column ChromatographyA chromatographic method where the stationary phase is packed in a column and the mobile phase carries the sample through it.    
    Complexation TitrationsA type of titrimetric method where the analyte forms a complex with a reagent, which is used to determine its concentration.    
    Critical Values for t-TestThe values used to determine statistical significance in hypothesis testing using the t-distribution.    
    Detection LimitsThe smallest quantity of an analyte that can be reliably detected but not necessarily quantified in a sample.    
    DeterminationThe process of quantifying the amount of analyte in a sample.    
    Dixon's Q-TestA statistical test used to identify outliers in a set of data points.    
    ElectrophoresisA separation technique where charged particles move through a gel under the influence of an electric field.    
    ElectrochemistryThe study of chemical processes that involve the movement of electrons, often used in potentiometry, coulometry, and voltammetry.    
    Emission SpectroscopyA spectroscopic method in which atoms or molecules emit light at characteristic wavelengths after being excited.    
    Excel and RSoftware tools used for statistical analysis, data visualization, and conducting various types of analytical chemistry computations.    
    Formation ConstantsThe equilibrium constants for the formation of complex ions from a metal and a ligand.    
    F-TestA statistical test used to compare two variances to determine if they are significantly different.    
    Gravimetric MethodsAnalytical methods based on the measurement of mass, typically involving the precipitation of a compound.    
    Grubb's TestA statistical test used for detecting outliers in small data sets.    
    High-Performance Liquid Chromatography, HPLCA modern chromatographic technique that uses high-pressure pumps to force solvents through a column to separate compounds in a liquid sample.    
    Hydrogen Ion ConcentrationA measure of the concentration of H⁺ ions in a solution, typically used to determine the pH of a solution.    
    Instrumental MethodsAnalytical techniques that involve the use of instruments, such as spectrometers or chromatographs, to measure the concentration of analytes.    
    InterferentsSubstances that affect the accuracy of the analysis by interfering with the measurement of the analyte.    
    Kinetic MethodsTechniques that rely on the measurement of the rate of a chemical reaction to determine the concentration of analytes.    
    Le Chatelier’s PrincipleA principle in chemistry that states that a system at equilibrium will adjust to counteract any changes imposed on it.    
    Linear RegressionA statistical method for modeling the relationship between a dependent variable and one or more independent variables, often used for calibration curves.    
    Liquid-Liquid ExtractionsA separation technique where two immiscible liquids are used to separate components based on their solubilities.    
    Method ValidationThe process of confirming that an analytical method produces accurate, reliable, and consistent results within defined limits.    
    Measurement UncertaintyThe doubt that exists about the result of any measurement due to possible errors and variability in the process.    
    Normal DistributionA symmetric, bell-shaped probability distribution, often used to model the distribution of experimental errors.    
    NormalityA concentration unit for acids and bases in solution, defined as the gram equivalent weight per liter of solution.    
    Precipitation GravimetryA gravimetric method where a substance is precipitated out of a solution and weighed to determine its concentration.    
    PreconcentrationThe process of increasing the concentration of an analyte in a sample prior to measurement to improve detection.    
    Propagation of UncertaintyThe process of calculating the uncertainty of a result derived from multiple measurements with associated uncertainties.    
    Quality AssuranceThe systematic processes implemented to ensure the quality of laboratory results, including calibration, validation, and verification of methods.    
    Quality ControlA set of procedures to ensure that analytical measurements meet predefined standards and specifications.    
    Redox TitrationsTitrations based on the transfer of electrons between the analyte and the titrant, often used to determine the concentration of oxidizing or reducing agents.    
    Regression AnalysisA statistical method for modeling the relationship between a dependent variable and one or more independent variables, especially useful in analytical chemistry for creating calibration curves.    
    Reagent BlankA sample containing all the components of the test except the analyte, used to correct for the interference from reagents.    
    Solubility ProductsEquilibrium constants for the dissolution of sparingly soluble salts in water.    
    Spectroscopic MethodsTechniques that measure the interaction of light with matter to identify or quantify substances based on their absorption, emission, or scattering properties.    
    Standard Reduction PotentialsThe tendency of a substance to gain electrons, used in electrochemical analysis.    
    StoichiometryThe calculation of the quantities of reactants and products involved in chemical reactions.    
    TitrimetryA quantitative analytical method where a reagent of known concentration is added to a solution of the analyte until the reaction reaches a known endpoint.    
    Titration CurvesGraphs used in titrimetry to show the change in a property (like pH or conductivity) as a titrant is added.    
    UncertaintyA parameter that characterizes the dispersion of the values attributed to a measured quantity, often arising from instrumental limitations or experimental error.    
    VoltammetryAn electrochemical technique where the current is measured as a function of applied voltage to study the concentration of an analyte.    
    Weighing by DifferenceA method for determining the mass of a substance by subtracting the mass of the container from the total mass after the substance is added.    
    X-ray FluorescenceA type of spectroscopic technique that uses X-rays to analyze the elemental composition of materials.    
    Zero-Order ReactionsReactions where the rate of reaction is independent of the concentration of the reactants.    
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