4.19: Extra Problems

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Name: ______________________________

Section: _____________________________

Student ID#:__________________________

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Problem NS19.1.

Fill in the missing items in the following synthesis. Includes: aliphatic nucleophilic substitution, carboxylic substitution, enolates, addition to carbonyl (anionic nucleophiles).

Problem NS19.2.

Fill in the missing items in the following synthesis. Includes: addition to carbonyls (anionic nucleophiles, neutral nucleophiles, aliphatic nucleophilic substitution, Mitsunobu reaction).

Problem NS19.3.

Fill in the missing items in the following synthesis. Includes: aliphatic nucleophilic substitution,sulfonate substitution, Mitsunobu reaction, silyl ether cleavage, nucleophilic substitution of epoxides, elimination / dehydration.

Problem NS19.4.

Fill in the missing items in the following synthesis. Includes: addition to carbonyls (ylides), nucleophilic substitution of epoxides, carboxylic substitution.

Problem NS19.5.

Fill in the missing items in the following synthesis. Includes: aliphatic nucleophilic substitution, carboxylic substitution, sulfonate substitution, addition to nitriles, addition to carbonyls (ylides).

Problem NS19.6.

Fill in the missing items in the following synthesis. Includes: aliphatic nucleophilic substitution, carbonyl addition (anionic nucleophiles, acetals, ylides), carboxylic substitution, silyl ethers.