T2: Extended Thermodynamic Properties of Substances
- Page ID
- 2191
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Under standard Conditions-
| Substance (form) | Enthalpy \(\Delta_fH^o\; \left(\frac{\text{kJ}}{\text{ mol}}\right)\) |
Gibbs \(\Delta_fG^o\; \left(\frac{\text{kJ}}{\text{ mol}}\right)\) |
Entropy \(S^o \; \left(\frac{\text{J}}{\text{ mol K}}\right)\) |
Heat capacity \(c_P\;\left(\frac{\text{J}}{\text{ mol K}}\right)\) |
Volume \( V (\;\text{cm}^3) \) |
|---|---|---|---|---|---|
| Al (s) | 0 | 0 | 28.33 | 24.35 | 9.99 |
| Al2SiO5 (kyanite) | -2594.29 | -2443.88 | 83.81 | 121.71 | 44.09 |
| Al2SiO5 (andalusite) | -2590.27 | -2442.66 | 93.22 | 122.72 | 51.53 |
| Al2SiO5 (sillimanite) | -2587.76 | -2440.99 | 96.11 | 124.52 | 49.90 |
| Ar (g) | 0 | 0 | 154.84 | 20.79 | - |
| C (graphite) | 0 | 0 | 5.74 | 8.53 | 5.30 |
| C (diamond) | 1.895 | 2.900 | 2.38 | 6.11 | 3.42 |
| CH4 (g) | -74.81 | -50.72 | 186.26 | 35.31 | - |
| C2H6 (g) | -84.68 | -32.82 | 229.60 | 52.63 | - |
| C3H8 (g) | -103.85 | -23.49 | 269.91 | 73.5 | - |
| C2H5OH (l) | -277.69 | -174.78 | 160.7 | 111.46 | 58.4 |
| C6H12O6 (glucose) | -1268 | -910 | 212 | 115 | - |
| CO (g) | -110.53 | -137.17 | 197.67 | 29.14 | - |
| CO2 (g) | -393.51 | -394.36 | 213.74 | 37.11 | - |
| H2CO3 (aq) | -699.65 | -623.08 | 187.4 | - | - |
| HCO3- (aq) | -691.99 | -586.77 | 91.2 | - | - |
| Ca2+ (aq) | -542.83 | -553.58 | -53.1 | - | - |
| CaCO3 (calcite) | -1206.9 | -1128.8 | 92.9 | 81.88 | 36.93 |
| CaCO3 (aragonite) | -1207.1 | -1127.8 | 88.7 | 81.25 | 34.15 |
| CaCl2 (s) | -795.8 | -748.1 | 104.6 | 72.59 | 51.6 |
| Cl2 (g) | 0 | 0 | 223.07 | 33.91 | - |
| Cl- (aq) | -167.16 | -131.23 | 56.5 | -136.4 | 17.3 |
| Cu (s) | 0 | 0 | 33.150 | 24.44 | 7.12 |
| Fe (s) | 0 | 0 | 27.28 | 25.10 | 7.11 |
| H2 (g) | 0 | 0 | 130.68 | 28.82 | - |
| H (g) | 217.97 | 203.25 | 114.71 | 20.78 | - |
| H+ (aq) | 0 | 0 | 0 | 0 | - |
| H2O (l) | -285.83 | -237.13 | 69.91 | 75.29 | 18.068 |
| H2O (g) | -241.82 | -228.57 | 188.83 | 33.58 | - |
| He (g) | 0 | 0 | 126.15 | 20.79 | - |
| Hg (l) | 0 | 0 | 76.02 | 27.98 | 14.81 |
| N2 (g) | 0 | 0 | 191.61 | 29.12 | - |
| NH3 (g) | -46.11 | -16.45 | 192.45 | 35.06 | - |
| Na+(aq) | -240.12 | -261.91 | 59.0 | 46.4 | -1.2 |
| NaCl (s) | -411.15 | -384.14 | 72.13 | 50.50 | 27.01 |
| NaAlSi3O8 (albite) | -3935.1 | -3711.5 | 207.40 | 205.10 | 100.07 |
| NaAlSi2O6 (jadeite) | -3030.9 | -2852.1 | 133.5 | 160.0 | 60.40 |
| Ne (g) | 0 | 0 | 146.33 | 20.79 | - |
| O2 (g) | 0 | 0 | 205.14 | 29.38 | - |
| O2 (aq) | -11.7 | 16.4 | 110.9 | - | - |
| OH- (aq) | -229.99 | -157.24 | -10.75 | -148.5 | - |
| Pb (s) | 0 | 0 | 64.81 | 26.44 | 18.3 |
| PbO2(s) | -277.4 | -217.33 | 68.6 | 64.64 | - |
| PbSO4(s) | -920.0 | -813.0 | 148.5 | 103.2 | - |
| SO42- (aq) | -909.27 | -744.53 | 20.1 | -293 | - |
| HSO4- (aq) | -887.34 | -755.91 | 131.8 | -84 | - |
| SiO2 (a quartz) | -910.94 | -856.64 | 41.84 | 44.43 | 22.69 |
| H4SiO4(aq) | -1449.36 | -1307.67 | 215.13 | 468.98 | - |