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- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Instrumental_Analysis_(LibreTexts)/22%3A_An_Introduction_to_Electroanalytical_ChemistryThe simplest division of electrochemical techniques is between bulk techniques, in which we measure a property of the solution in the electrochemical cell, and interfacial techniques, in which the pot...The simplest division of electrochemical techniques is between bulk techniques, in which we measure a property of the solution in the electrochemical cell, and interfacial techniques, in which the potential, current, or charge depends on the species present at the interface between an electrode and the solution in which it sits.
- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Instrumental_Analysis_(LibreTexts)/25%3A_Voltammetry/25.02%3A_Voltammetric_InstrumentationAlthough early voltammetric methods used only two electrodes, a modern voltammeter makes use of a three-electrode potentiostat. The potential of the working electrode is measured relative to a constan...Although early voltammetric methods used only two electrodes, a modern voltammeter makes use of a three-electrode potentiostat. The potential of the working electrode is measured relative to a constant-potential reference electrode that is connected to the working electrode through a high-impedance potentiometer. The auxiliary electrode generally is a platinum wire and the reference electrode usually is a SCE or a Ag/AgCl electrode.
- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Analytical_Chemistry_2.1_(Harvey)/11%3A_Electrochemical_Methods/11.01%3A_Overview_of_ElectrochemistryThis chapter focuses on analytical electrochemistry, which uses measurements of potential, current, or charge to determine analyte concentration or chemical reactivity. Key concepts include the relati...This chapter focuses on analytical electrochemistry, which uses measurements of potential, current, or charge to determine analyte concentration or chemical reactivity. Key concepts include the relationship between electrode potential and analyte form, differences in surface and bulk concentrations, current's role in measuring redox rates, and the balance between controlling current and potential.