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- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/07%3A_Organometallic_Reactions_and_Catalysis/7.02%3A_Reactions_Invloving_Modification_of_Unsaturated_Ligands/7.2.04%3A_-Elimination_ReactionsIn organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair)...In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.05%3A_Organometallic_Reactions_and_Catalysis/10.5.02%3A_Reactions_Invloving_Modification_of_Unsaturated_Ligands/10.5.2.04%3A_-Elimination_ReactionsIn organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair)...In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.06%3A_Metal-Carbon_Bonds/6.6.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/19%3A_Organometallic_Bonding_(Epic_Ligand_Survey)/19.08%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/14%3A_Organometallic_Reactions_and_Catalysis/14.02%3A_Reactions_Invloving_Modification_of_Unsaturated_Ligands/14.2.04%3A_-Elimination_ReactionsIn organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair)...In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so.
- https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/11%3A_Organometallic_Reactions_and_Catalysis/11.02%3A_Reactions_Invloving_Modification_of_Unsaturated_Ligands/11.2.04%3A_-Elimination_ReactionsIn organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair)...In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.03%3A_Metal-Carbon_Bonds/10.2.3.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/02%3A_Organometallic_Ligands/2.05%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/04%3A_Fundamentals_of_Organometallic_Chemistry/4.01%3A_-Elimination_ReactionsIn organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair)...In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/13%3A_Organometallic_Chemistry/13.06%3A_Metal-Carbon_Bonds/13.6.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/06%3A_Catalysis/6.06%3A_Metal-Carbon_Bonds/6.6.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
