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- https://chem.libretexts.org/Courses/Oregon_Institute_of_Technology/OIT%3A_CHE_333_-_Organic_Chemistry_III_(Lund)/17%3A_The_Organic_Chemistry_of_Vitamins/17.1%3A_Pyridoxal_Phosphate_(Vitamin_B6)The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the va...The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the various amino acid biosynthetic and degradation pathways. The essential function of PLP is to act as an 'electron sink', stabilizing a negative formal charge that develops on key reaction intermediates.
- https://chem.libretexts.org/Courses/SUNY_Oneonta/Organic_Chemistry_with_a_Biological_Emphasis_(SUNY_Oneonta)/18%3A_The_Organic_Chemistry_of_Vitamins/18.02%3A_Pyridoxal_Phosphate_(Vitamin_B6)The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the va...The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the various amino acid biosynthetic and degradation pathways. The essential function of PLP is to act as an 'electron sink', stabilizing a negative formal charge that develops on key reaction intermediates.
- https://chem.libretexts.org/Courses/Oregon_Institute_of_Technology/OIT%3A_CHE_333_-_Organic_Chemistry_III_(Lund)/13%3A_Reactions_at_the_-Carbon_Part_II/13.4%3A_Conjugate_Addition_and_EliminationIn this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two ca...In this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two carbons of an alkene which is conjugated to a carbonyl (i.e. in the α−β position). an β -elimination step, the reverse process occurs.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.06%3A_Metal-Carbon_Bonds/6.6.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Courses/SUNY_Oneonta/Organic_Chemistry_with_a_Biological_Emphasis_(SUNY_Oneonta)/13%3A_Reactions_at_the_-Carbon_Part_II/13.05%3A_Conjugate_Addition_and_EliminationIn this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two ca...In this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two carbons of an alkene which is conjugated to a carbonyl (i.e. in the α−β position). an β -elimination step, the reverse process occurs.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/19%3A_Organometallic_Bonding_(Epic_Ligand_Survey)/19.08%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Courses/Oregon_Institute_of_Technology/OIT_(Lund)%3A_Organic_Chemistry_with_a_Biological_Emphasis_(Soderberg)/13%3A_Reactions_at_the_-Carbon_Part_II/13.04%3A_Conjugate_Addition_and_EliminationIn this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two ca...In this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two carbons of an alkene which is conjugated to a carbonyl (i.e. in the α−β position). an β -elimination step, the reverse process occurs.
- https://chem.libretexts.org/Courses/SUNY_Oneonta/Chem_322_Lecture_Content/08%3A_Reactions_at_the_-Carbon_Part_II/8.05%3A_Conjugate_Addition_and_EliminationIn this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two ca...In this section, we will look at two more common biochemical reactions that proceed through enolate intermediates. In a typical conjugate addition, a nucleophile and a proton are 'added' to the two carbons of an alkene which is conjugated to a carbonyl (i.e. in the α−β position). an β -elimination step, the reverse process occurs.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.03%3A_Metal-Carbon_Bonds/10.2.3.01%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
- https://chem.libretexts.org/Courses/SUNY_Oneonta/Chem_322_Lecture_Content/10%3A_The_Organic_Chemistry_of_Vitamins/10.02%3A_Pyridoxal_Phosphate_(Vitamin_B6)The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the va...The coenzyme pyridoxal phosphate (commonly abbreviated PLP) is the active form of vitamin B6 , or pyridoxine. PLP is required for over 100 different reactions in human metabolism, primarily in the various amino acid biosynthetic and degradation pathways. The essential function of PLP is to act as an 'electron sink', stabilizing a negative formal charge that develops on key reaction intermediates.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/02%3A_Organometallic_Ligands/2.05%3A_Metal_AlkylsMetal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alky...Metal alkyls feature a metal-carbon σ bond and are usually actor ligands, although some alkyl ligands behave as spectators. Our aim will be to understand the general dependence of the behavior of alkyl ligands on the metal center and the ligand’s substituents. Using this knowledge, we can make meaningful comparisons between related metal alkyl complexes and educated predictions about their likely behavior.
