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7: Substitution Reactions

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Jun 23, 2019
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- 6.E: Chemical Reactivity and Mechanisms (Exercises)
- 7.1: 7-2 The $S_{N}2$ Reaction

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Topic hierarchy

7.1: 7-2 The $S_{N}2$ Reaction
7.2: 7-3 Characteristics of the $S_{N}2$ Reaction
7.3: 7-4 The $S_{N}1$ Reaction
7.4: 7-5 Characteristics of the $S_{N}1$ Reaction
7.5: Introduction to Substitution Reactions
7.6: Alkyl Halides
7.7: Possible Mechanisms for Substitution Reactions
7.8: The SN2 Mechanism
7.9: The SN1 Mechanism
7.10: Drawing the Complete Mechanism of an SN1 Reaction
7.11: Drawing the Complete Mechanism of an SN2 Reaction
7.12: Determining Which Mechanism Predominates
7.13: Selecting Reagents to Accomplish Functional Group Transformation
7.14: 7-7 When Is the Mechanism $S_{N}1$ or $S_{N}2$ ?
7.15: 7-1 Introduction to Nucleophilic Substitution Reactions
7.16: 7-8 Carbocation Structure and Stability
7.17: 7-9 Carbocation Stability
7.18: 7-6 Structural and Solvent Effects in $S_N$ Reactions
We shall consider first the relationship between the structures of alkyl derivatives and their reaction rates toward a given nucleophile. This will be followed by a discussion of the relative reactivities of various nucleophiles toward a given alkyl derivative. Finally, we shall comment in more detail on the role of the solvent in nucleophilic substitution reactions.
7.E: Substitution Reactions (Exercises)

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