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4: Conformation and Stability

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    170429
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    • 4.1: Prelude to Conformations and Stereochemistry
      In 1848, a 25 year old chemist named Louis Pasteur made a startling - and some thought brash - claim to the scientific community. Pasteur was inexperienced, to say the least: he had only earned his doctorate the previous year, and had just started his first job as an assistant to a professor at the Ecole normale superieure, a university in Paris.
    • 4.2: Conformations of open-chain organic molecules
      Before we begin our exploration of stereochemistry and chirality, we first need to consider the subject of conformational isomerism, which has to do with rotation about single bonds.
    • 4.3: Conformations of cyclic organic molecules
      Browse through a biochemistry textbook and you will see any number of molecules with cyclic structures. Many of these cyclic structures are aromatic, and therefore planar. Many others, though, are composed of sp3-hybridized atoms, and it is these cyclic structures that are the topic of discussion in this section.


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