2: Properties and Reactions of Alkanes
- Page ID
- 23366
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Chapter 3: Reactions of Alkanes
Strength of Alkane Bonds and Radicals
Structure of Alkyl Radicals and Hyperconjugation
Chlorination of Methane and the Radical Chain Mechanism
Other Radical Halogenations of Methane
Chlorination of Higher Alkanes
Selectivity in Radical Halogenation with Fluorine and Bromine
Synthetic Radical Halogenation
Combustion and the Relative Stabilities of Alkanes
Chapter 4: Cycloalkanes
Naming Cycloalkanes
Physical Properties of Cycloalkanes
Ring Strain and the Structure of Cycloalkanes
Cyclohexane
Substituted Cyclohexanes
Larger Cycloalkanes
Polycyclic Alkanes
Chapter 6: Properties and Reactions of Haloalkanes
Physical Properties of Haloalkanes
Nucleophilic Substitution
Using Electron-Pushing Arrows
Kinetics of Nucleophilic Substitution Reactions
SN2Reactions-Stereochemistry
SN2 Reactions-The Leaving Group
SN2 Reactions-The Nucleophile
SN2 Reactions-The Substrate
Solvolysis of Secondary and Tertiary Haloalkanes
Unimolecular Nucleophilic Substitution
Stereochemical Consequences of SN1 Reactions
Effects of Solvent, Leaving Group, and Nucleophile on Unimolecular Substitution
Effect of the Alkyl Group on the SN1 Reaction-Carbocation Stability
Unimolecular Elimination-E1
Unimolecular Elimination-E2
Competition Between Substitution and Elimination-Structure Determines Function