4: Compounds and Molecules
- Page ID
- 279974
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Chemical Compounds
Exercise \(\PageIndex{1.a}\)
Using the periodic table, predict whether the following chlorides are ionic or covalent: KCl, NCl3, ICl, MgCl2, PCl5, and CCl4.
- Answer
-
Ionic: KCl, MgCl2
Covalent: NCl3, ICl, PCl5, CCl4
Exercise \(\PageIndex{1.b}\)
Using the periodic table, predict whether the following chlorides are ionic or covalent: KCl, NCl3, ICl, MgCl2, PCl5, and CCl4.
- Answer
-
Ionic: KCl, MgCl2
Covalent: NCl3, ICl, PCl5, CCl4
Exercise \(\PageIndex{1.c}\)
For each of the following compounds, state whether it is ionic or covalent. If it is ionic, write the symbols for the ions involved:
- NF3
- BaO
- IBr
- Na2O
- Answer a
-
covalent
- Answer b
-
ionic, Ba2+, O−2
- Answer c
-
covalent
- Answer d
-
ionic, Na+, O−2
Molecular Compounds
Exercise \(\PageIndex{2.a}\)
Explain why the symbol for an atom of the element oxygen and the formula for a molecule of oxygen differ.
- Answer
-
The symbol for the element oxygen, O, represents both the element and one atom of oxygen. A molecule of oxygen, O2, contains two oxygen atoms; the subscript 2 in the formula must be used to distinguish the diatomic molecule from two single oxygen atoms.
Ionic Compounds and Formulas
Exercise \(\PageIndex{3.a}\)
For each of the following pairs of ions, write the formula of the compound they will form:
- Ca2+, S2−
- \(NH_{4}^{+}\), \(SO_{4}^{2-}\)
- Al3+, Br−
- Na+, \(HPO_{4}^{2-}\)
- Mg2+, \(PO_{4}^{3-}\)
- Answer a
-
CaS
- Answer b
-
(NH4)2SO4
- Answer c
-
AlBr3
- Answer d
-
Na2HPO4
- Answer e
-
Mg3(PO4)2
Polyatomic Ions
Nomenclature
Exercise \(\PageIndex{5.a}\)
Name the following compounds:
- CsCl
- BaO
- K2S
- BeCl2
- HBr
- AlF3
- Answer a
-
cesium chloride
- Answer b
-
barium oxide
- Answer c
-
potassium sulfide
- Answer d
-
beryllium chloride
- Answer e
-
hydrogen bromide
- Answer f
-
aluminum fluoride
Exercise \(\PageIndex{5.b}\)
Each of the following compounds contains a metal that can exhibit more than one ionic charge. Name these compounds:
- Cr2O3
- FeCl2
- CrO3
- TiCl4
- CoO
- MoS2
- Answer a
-
chromium(III) oxide
- Answer b
-
iron(II) chloride
- Answer c
-
chromium(VI) oxide
- Answer d
-
titanium(IV) chloride
- Answer e
-
cobalt(II) oxide
- Answer f
-
molybdenum(IV) sulfide
Exercise \(\PageIndex{5.c}\)
Write the formulas of the following compounds:
- rubidium bromide
- magnesium selenide
- sodium oxide
- calcium chloride
- hydrogen fluoride
- gallium phosphide
- aluminum bromide
- ammonium sulfate
- Answer a
- RbBr
- Answer b
- MgSe
- Answer c
- Na2O
- Answer d
- CaCl2
- Answer e
- HF
- Answer f
- GaP
- Answer g
- AlBr3
- Answer h
- (NH4)2SO4
Exercise \(\PageIndex{5.d}\)
Write the formulas of the following compounds:
- chlorine dioxide
- dinitrogen tetraoxide
- potassium phosphide
- silver(I) sulfide
- aluminum nitride
- silicon dioxide
- Answer a
- ClO2
- Answer b
- N2O4
- Answer c
- K3P
- Answer d
- Ag2S
- Answer e
- AlN
- Answer f
- SiO2
Exercise \(\PageIndex{5.e}\)
The following ionic compounds are found in common household products. Write the formulas for each compound:
- potassium phosphate
- copper(II) sulfate
- calcium chloride
- titanium dioxide
- ammonium nitrate
- sodium bisulfate (the common name for sodium hydrogen sulfate)
- Answer a
- K3PO4
- Answer b
- CuSO4
- Answer c
- CaCl2
- Answer d
- TiO2
- Answer e
- NH4NO3
- Answer f
- NaHSO4