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Chemistry LibreTexts

5: Macronutrients - Carbohydrates

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  • 5.1: Carbohydrates
    Carbohydrates are an important group of biological molecules that includes sugars and starches. Photosynthesis is the process by which plants use energy from sunlight to synthesize carbohydrates. A monosaccharide is the simplest carbohydrate and cannot be hydrolyzed to produce a smaller carbohydrate molecule. Disaccharides contain two monosaccharide units, and polysaccharides contain many monosaccharide units.
  • 5.2: Classes of Monosaccharides and Handedness
    Monosaccharides can be classified by the number of carbon atoms in the structure and/or the type of carbonyl group they contain (aldose or ketose). Most monosaccharides contain at least one chiral carbon and can form stereoisomers. Enantiomers are a specific type of stereoisomers that are mirror images of each other.
  • 5.3: Important Hexoses
    Three abundant hexoses in living organisms are the aldohexoses D-glucose and D-galactose and the ketohexose D-fructose.
  • 5.4: Cyclic Structures of Monosaccharides
    Monosaccharides that contain five or more carbons atoms form cyclic structures in aqueous solution. Two cyclic stereoisomers can form from each straight-chain monosaccharide; these are known as anomers. In an aqueous solution, an equilibrium mixture forms between the two anomers and the straight-chain structure of a monosaccharide in a process known as mutarotation.
  • 5.5: Sugars and Cooking
    Monosaccharides are crystalline solids at room temperature and quite soluble in water.​​​​​​​ Monosaccharides are reducing sugars; they reduce mild oxidizing agents, such as Tollens’ or Benedict’s reagents.
  • 5.6: Disaccharides - Maltose, Lactose, and Sucrose
    Maltose is composed of two molecules of glucose joined by an α-1,4-glycosidic linkage. It is a reducing sugar that is found in sprouting grain. Lactose is composed of a molecule of galactose joined to a molecule of glucose by a β-1,4-glycosidic linkage. It is a reducing sugar that is found in milk. Sucrose is composed of a molecule of glucose joined to a molecule of fructose by an α-1,β-2-glycosidic linkage. It is a nonreducing sugar that is found in sugar cane and sugar beets.
  • 5.7: Polysaccharides - Starch, Glycogen, and Cellulose
    Starch is a storage form of energy in plants. It contains two polymers composed of glucose units: amylose (linear) and amylopectin (branched). Glycogen is a storage form of energy in animals. It is a branched polymer composed of glucose units. It is more highly branched than amylopectin. Cellulose is a structural polymer of glucose units found in plants. It is a linear polymer with the glucose units linked through β-1,4-glycosidic bonds.


5: Macronutrients - Carbohydrates is shared under a not declared license and was authored, remixed, and/or curated by LibreTexts.

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