10: Organohalides
After you have completed Chapter 10, you should be able to
- fulfill all of the detailed objectives listed under each individual section.
- design a multistep synthesis to prepare a given compound from a given starting material using any of the reactions studied up to this point in the course, including those which involve alkyl halides.
- solve road-map problems requiring a knowledge of any of the reactions or concepts studied up to this point, including those introduced in this chapter.
- define, and use in context, the key terms introduced.
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- 10.7: Reactions of Alkyl Halides - Grignard Reagents
- The organomagnesium compounds formed by the reaction of an alkyl or aryl halide with magnesium are called Grignard reagents. As you will see throughout the remainder of this course, Grignard reagents can be used to synthesize a wide range of organic compounds and are extremely useful to the organic chemist.
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- 10.9: Oxidation and Reduction in Organic Chemistry
- In organic chemistry, redox reactions look a little different. Electrons in an organic redox reaction often are transferred in the form of a hydride ion - a proton and two electrons. Because they occur in conjunction with the transfer of a proton, these are commonly referred to as hydrogenation and dehydrogenation reactions: a hydride plus a proton adds up to a hydrogen (H2) molecule. Be careful - do not confuse the terms hydrogenation and dehydrogenation with hydration and dehydration.