3: Organic Compounds- Alkanes and Their Stereochemistry
After you have completed Chapter 3, you should be able to
- fulfill the detailed objectives listed under each section.
- identify some of the commonest functional groups.
- write the structures and names of the first ten straight-chain alkanes.
- recognize and name the simple alkyl substituents, and give the systematic names for branched-chain alkanes.
- briefly describe some of the processes used during the refining of petroleum.
- briefly describe the physical properties of alkanes.
- draw a number of possible conformations of some simple alkanes and alkane-like compounds, and represent the energies of such conformations on energy versus rotation diagrams.
- define, and use in context, the key terms introduced in this chapter.
This chapter begins with an introduction to the concept of the functional group, a concept that facilitates the systematic study of organic chemistry. Next, we introduce the fundamentals of organic nomenclature (i.e., the naming of organic chemicals) through examination of the alkane family of compounds. We then discuss, briefly, the occurrence and properties of alkanes, and end with a description of cis - trans isomerism in cycloalkanes.
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- 3.2: Functional Groups
- Functional groups are atoms or small groups of atoms (two to four) that exhibit a characteristic reactivity. A particular functional group will almost always display its characteristic chemical behavior when it is present in a compound. Because of their importance in understanding organic chemistry, functional groups have characteristic names that often carry over in the naming of individual compounds incorporating specific groups
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- 3.3: Alkanes and Alkane Isomers
- Alkanes are organic compounds that consist entirely of single-bonded carbon and hydrogen atoms and lack any other functional groups. Alkanes have the general formula CnH2n+2 and can be subdivided into the following three groups: the linear straight-chain alkanes, branched alkanes, and cycloalkanes. Alkanes are also saturated hydrocarbons. Cycloalkanes are cyclic hydrocarbons, meaning that the carbons of the molecule are arranged in the form of a ring.
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- 3.4: Alkyl Groups
- The IUPAC system requires first that we have names for simple unbranched chains, as noted above, and second that we have names for simple alkyl groups that may be attached to the chains. Examples of some common alkyl groups are given in the following table. Note that the "ane" suffix is replaced by "yl" in naming groups. The symbol R is used to designate a generic (unspecified) alkyl group.
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- 3.7: Conformations of Ethane
- Conformational isomerism involves rotation about sigma bonds, and does not involve any differences in the connectivity or geometry of bonding. Two or more structures that are categorized as conformational isomers, or conformers, are really just two of the exact same molecule that differ only in terms of the angle about one or more sigma bonds.
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- 3.9: Gasoline - A Deeper Look
- The petroleum that is pumped out of the ground at locations around the world is a complex mixture of several thousand organic compounds, including straight-chain alkanes, cycloalkanes, alkenes, and aromatic hydrocarbons with four to several hundred carbon atoms. The identities and relative abundances of the components vary depending on the source.