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7.1: Representing Organic Reactions

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  • Organic reactions are often shown in the following way:

    Reactions are not usually balanced; the above should be considered a scheme rather than an equation.  In fact, by-products are often omitted completely, especially if they are inorganic. A “reagent” is a chemical used to change an organic reactant into the desired product.  There may be several steps, listing more than one reaction in one scheme, by showing each reagent/condition in sequence after (i), (ii), etc.

    Here the alcohol is first treated with PBr3 and heated, then (in a separate reaction) it is treated with KCN in ethanol.

    The value of this approach is seen when drawing out a multi-step synthesis.  In such a scheme, it shows a starting material A being acted upon by a sequence of reagents (X, Y, then Z) in order to turn it eventually into D:

    Notice that each arrow here represents a complete reaction, not just a step in a mechanism.

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