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10.3.2: Law of Definite Proportions

  • Page ID
    476540
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    Learning Objectives
    • Recognize the Law of Definite Proportions

    The discovery that mass was always conserved in chemical reactions was soon followed by the law of definite proportions, which states that a given chemical compound always contains the same elements in the exact same proportions by mass. As an example, any sample of pure water contains \(11.19\%\) hydrogen and \(88.81\%\) oxygen by mass. It does not matter where the sample of water came from or how it was prepared. Its composition, like that of every other compound, is fixed.

    LAW OF DEFINITE PROPORTIONS

    Any sample of a chemical compound will always contain the same elements in the exact same proportion by mass.

    Water coming from the faucet.
    Figure \(\PageIndex{1}\): Water. (Credit: Jenn Durfey; Source: Flickr Photos, Water Faucet(opens in new window) [www.flickr.com]; License: CC by 2.0(opens in new window))

    Another example is carbon dioxide. This gas is produced from a variety of reactions, often by the burning of materials. The structure of the gas consists of one atom of carbon and two atoms of oxygen. Carbon dioxide production is of interest in many areas, from the amount we breathe to the amount of the gas produced by burning wood or fossil fuels. By knowing the exact composition of carbon dioxide, we can make predictions as to the effects of different chemical processes.

    Home burning down, with debris.
    Figure \(\PageIndex{2}\): Carbon dioxide is produced during the burning process. (Credit: Courtesy of Patsy Lynch, FEMA; Source: Commons Wikimedia, FEMA Photograph by Patsy Lynch taken on 04-17-2006 in Missouri(opens in new window) [commons.wikimedia.org]; License: Public Domain)

    Section Summary

    • The law of definite proportions states that a given chemical compound always contains the same elements in the exact same proportions by mass.

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