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Chemistry LibreTexts

4.2: Understanding Atomic Spectra

  • Page ID
    85153
  • Skills to Develop

    • Differentiate between a continuous and discontinuous spectrum
    • Classify all types of radiation as being ionizing or nonionizing.
    • Understand that ionizing radiation can knock electrons off DNA.
    • Know that radiation of short wavelength is toxic.
    • Understand the processes of absorption and emission.
    • Explain the science behind fireworks.
    • Realize that chemists and other scientists use AA/AE in quantitative and qualitative analyses

    Continuous Spectrum

    A rainbow is an example of a continuous spectrum. Here, the colors displayed are within the visible spectrum (between 380-760 nm). Light in this wavelength range is visible to the naked eye. Unlike the visible spectrum, light that is of different wavelengths (see the electromagnetic spectrum below) is not visible. Looking at Figure \(\PageIndex{1}\), note the different areas of the light (or electromagnetic spectrum). Areas of light that possess short wavelengths are located on the left of the spectrum. All wavelengths from UV (ultraviolet) to \(γ\) (gamma) range have the potential to ionize tissues and/or DNA. As a result, individuals who have been exposed to large amounts of these types of radiation in acute time periods could develop cancer. In contrast, visible light (see the rainbow area in Figure \(\PageIndex{1}\) ) and radiation on the right side of the spectrum has longer wavelengths and does not have the potential to ionize tissues and/or DNA. Visible, infrared (labeled IR), microwave, and radio waves are classified as being nonionizing radiation and have not been linked to cancer.

    800px-EM_spectrumrevised.png

    Figure \(\PageIndex{1}\): The electromagnetic spectrum is an example of a continous spectrum. It contains various frequencies (cycle/time) and wavelengths. Image used with permission (CC BY-SA 3.0; Philip Ronan, Gringer).

    Please be aware of what types of light are ionizing and nonionizing. Do not memorize the wavelengths or frequencies of the electromagnetic spectrum. It is important that you know that the electromagnetic spectrum is an example of a continuous spectrum.

    Figure \(\PageIndex{2}\): Lower frequency, lower-energy electromagnetic radiation is nonionizing, and higher frequency, higher-energy electromagnetic radiation is ionizing. Image used with permission (CC BY-SA, OpenStax).

    Examples of Radiation

    For each section of the electromagnetic spectrum, be sure to know a source or application of each type (example for radio waves would be cell phones).  Also, also have a good understanding of how the UV portion can be expanded.  Review UV information, by clicking on this link.  Please do not memorize the ABCDE's of cancer nor the types of skin cancer that occur.  

    Atomic Emission Spectra

    The electrons in an atom tend to be arranged in such a way that the energy of the atom is as low as possible. The ground state of an atom is the lowest energy state of the atom. When those atoms are given energy, the electrons absorb the energy and move to a higher energy level. These energy levels of the electrons in atoms are quantized, meaning again that the electron must move from one energy level to another in discrete steps rather than continuously. An excited state of an atom is a state where its potential energy is higher than the ground state. An atom in the excited state is not stable. When it returns back to the ground state (Figure \(\PageIndex{3}\)), it releases the energy that it had previously gained often in the form of electromagnetic radiation (although it can be released via heat).

    4706021793_6b29efdcdb_z.jpg

    Figure \(\PageIndex{3}\): Atomic absorption and emission in excited and ground states. Image used with permission (CC BY-SA-NC 4.0; MIT OpenCourseWare).

    Atoms can gain energy to induce these transitions from various sources. The gases in the image below have been excited with the use of electrical current. The atoms in each of these noble gases produce distinctive colors that can be used to identify the elements (Figure \(\PageIndex{4}\)). Each of these species contains a different number of electrons that can undergo different types of excitations. In turn, each gas produces a signature color.

    Figure \(\PageIndex{4}\): Gas discharge tubes are enclosed glass tubes filled with a gas at low pressure through which an electric current is passed. Electrons in the gaseous atoms first become excited, and then fall back to lower energy levels, emitting light of a distinctive color in the process. Shown ar gas discharge tubes of helium, neon, argon, krypton, and xenon.

    Flames can be utilized to excite atoms as well. During a flame test experiment, metal chlorides are directly placed into a flame. The intense heat will promote the metal's electrons to an excited state. Upon emission, this extra energy is released in the form of visible light. If a reference panel is provided, the flame color can be used to identify a metal atom (Table \(\PageIndex{1}\)).

    Video \(\PageIndex{1}\): Burning Salts/Flame Test demonstration: Sully Science

    Table \(\PageIndex{1}\): Flame colors corresponding to elements
    Metal Ion Flame Color   Metal Ion Flame Color
    Li Red   K Light Purple
    Na Orange   Ba Light Green
    Ca Orange-Red   Cu Blue
    Sr Red      

    Fireworks are similar to flame test experiments. Firework manufacturers select certain metal atoms to produce desired colors for these devices. Individual detonators will explode the metal compounds to emit radiant colors of light. Watch the video below to see the largest aerial firework shell explode over the United Arab Emirates on December 31, 2017. While watching the video, compare the colors you see to the chart above to identify the atoms that were used in the display.

    Video \(\PageIndex{2}\): Guinness World Record For World’s Largest Aerial Firework Shell

    Discontinous Spectra

    If the light emitted from the excited atoms is viewed through a prism, then individual patterns of lines will be produced. These lines are called spectra and correspond to fingerprint wavelengths (symbol for wavelength is \(\lambda\) ) for a specific element. Figure \(\PageIndex{5}\) illustrates how the light from excited electrons can be diffracted to produce line spectra for the elements of hydrogen, helium, and iron. The specific elements produce wavelengths within the visible spectrum (between 400-700 nm) and can be seen by the naked eye. In order to obtain the numerical wavelengths (in nanometers), one would need to employ some type of detector.

    Figure \(\PageIndex{5}\): When light from a hydrogen gas discharge tube is passed through a prism, the light is split into four visible lines. Each of these spectral lines corresponds to a different electron transition from a higher energy state to a lower energy state. Every element has a unique atomic emission spectrum, as shown by the examples of helium \(\left( \ce{He} \right)\) and iron \(\left( \ce{Fe} \right)\).

    Atomic Absorption Spectra

    In addition to emission studies, chemists will also use atomic absorption to identify and quantify. Noting the energy changes from ground to excited states, chemists can obtain another type of discontinuous spectrum (see image below). Once again, a fingerprint wavelength pattern is produced that can be used to identify an atom. Academia and Industry could employ either an AA (atomic absorption) or AE (atomic emission) spectrometer to analyze the atoms within a sample.

    Spectral_lines_en.png

    Figure \(\PageIndex{6}\): Spectral lines. Image used with permission (Public Domain; Jhausauer).

     

    Example \(\PageIndex{1}\):

    Which statements is/are true?

    1. Microwaves can give you cancer.
    2. When exploding fireworks, you will see the color when the metal atoms absorb energy from the detonater.
    3. When using an AA or an AE spectrometer, a scientist will obtain a line spectra, not continuous spectra.
    4. The flame test gives specific colors for metal atoms.
    5. Gamma rays are ionizing and can cause cancer.
    6. In the light spectrum, you can see IR and visible with only your eyes.
    7. Continuous spectra can be used to identify an atom.
    Answer a

    False, they do not possess enough energy to knock electrons off tissues or DNA

    Answer b

    False, the color is given off during the emission or falling back process.

    Answer c

    True, scientists need those fingerprint wavelengths to identify atoms.

    Answer d

    True, the metals are the species that become excited and eventually emit the visible light.

    Answer e

    True, ultraviolet, gamma, and x-ray are powerful forms of radiation that can cause cancer.

    Answer f

    False, you can only see images in the visible spectrum (people who are colorblind are even more limited).

    Answer g

    False, chemists need those specific wavelengths to identify atoms, not a spectrum that shows a continuous flow of wavelengths.

    Summary

    Atomic emission spectra are produced when excited electrons return to the ground state.

    • When electrons return to a lower energy level, they emit energy in the form of light.
    • Bohr's model suggests each atom has a set of unchangeable energy levels and electrons in the electron cloud of that atom must be in one of those energy levels.
    • Bohr's model suggests that the atomic spectra of atoms are produced by electrons gaining energy from some source, jumping up to a higher energy level, then immediately dropping back to a lower energy level and emitting the energy difference between the two energy levels.
    • The existence of the atomic spectra is support for Bohr's model of the atom.
    • Bohr's model was only successful in calculating energy levels for the hydrogen atom.
    • The emitted light corresponds to energies of the specific electrons.

    Vocabulary

    • Emission spectrum (or atomic spectrum): The unique pattern of light given off by an element when it is given energy
    • Ground state: to be in the lowest energy level possible.
    • Excited state: to be in a higher energy level.

    Contributors