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15.8: Preparation of Esters

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    Learning Objectives

    • To identify and describe the substances from which most esters are prepared.

    Some esters can be prepared by esterification, a reaction in which a carboxylic acid and an alcohol, heated in the presence of a mineral acid catalyst, form an ester and water:


    The reaction is reversible. As a specific example of an esterification reaction, butyl acetate can be made from acetic acid and 1-butanol.

    butyl acetate.jpg

    A Closer Look: Condensation Polymers

    A commercially important esterification reaction is condensation polymerization, in which a reaction occurs between a dicarboxylic acid and a dihydric alcohol (diol), with the elimination of water. Such a reaction yields an ester that contains a free (unreacted) carboxyl group at one end and a free alcohol group at the other end. Further condensation reactions then occur, producing polyester polymers.

    The most important polyester, polyethylene terephthalate (PET), is made from terephthalic acid and ethylene glycol monomers:


    Polyester molecules make excellent fibers and are used in many fabrics. A knitted polyester tube, which is biologically inert, can be used in surgery to repair or replace diseased sections of blood vessels. PET is used to make bottles for soda pop and other beverages. It is also formed into films called Mylar. When magnetically coated, Mylar tape is used in audio- and videocassettes. Synthetic arteries can be made from PET, polytetrafluoroethylene, and other polymers.


    Esters are made by the reaction of a carboxylic acid with an alcohol, a process that is called esterification.

    Concept Review Exercises

    1. From what carboxylic acid and what alcohol can the ester isopropyl nonanoate be made?
    2. From what carboxylic acid and what alcohol can the ester cyclobutyl butyrate be made?


    1. nonanoic acid and isopropyl alcohol
    2. butyric acid and cyclobutyl alcohol


    1. Write the equation for the reaction of acetic acid with each compound.

      1. ethanol
      2. 1-butanol in the presence of a mineral acid catalyst
    2. Write the equation for the reaction of benzoic acid with each compound.

      1. methanol
      2. 1-propanol in the presence of a mineral acid catalyst


      1. 1a.jpg
      2. 1b.jpg

    15.8: Preparation of Esters is shared under a not declared license and was authored, remixed, and/or curated by LibreTexts.

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