absolute zero | temperature at which the volume of a gas would be zero according to Charles’s law. | | | | |
Amontons’s law | (also, Gay-Lussac’s law) pressure of a given number of moles of gas is directly proportional to its kelvin temperature when the volume is held constant | | | | |
atmosphere (atm) | unit of pressure; 1 atm = 101,325 Pa | | | | |
Avogadro’s law | volume of a gas at constant temperature and pressure is proportional to the number of gas molecules | | | | |
bar | (bar or b) unit of pressure; 1 bar = 100,000 Pa | | | | |
barometer | device used to measure atmospheric pressure | | | | |
Boyle’s law | volume of a given number of moles of gas held at constant temperature is inversely proportional to the pressure under which it is measured | | | | |
Charles’s law | volume of a given number of moles of gas is directly proportional to its kelvin temperature when the pressure is held constant | | | | |
compressibility factor (Z) | ratio of the experimentally measured molar volume for a gas to its molar volume as computed from the ideal gas equation | | | | |
Dalton’s law of partial pressures | total pressure of a mixture of ideal gases is equal to the sum of the partial pressures of the component gases | | | | |
diffusion | movement of an atom or molecule from a region of relatively high concentration to one of relatively low concentration (discussed in this chapter with regard to gaseous species, but applicable to species in any phase) | | | | |
effusion | transfer of gaseous atoms or molecules from a container to a vacuum through very small openings | | | | |
Graham’s law of effusion | rates of diffusion and effusion of gases are inversely proportional to the square roots of their molecular masses | | | | |
hydrostatic pressure | pressure exerted by a fluid due to gravity | | | | |
ideal gas | hypothetical gas whose physical properties are perfectly described by the gas laws | | | | |
ideal gas constant (R) | constant derived from the ideal gas equation R = 0.08206 L atm mol–1 K–1 or 8.314 L kPa mol–1 K–1 | | | | |
ideal gas law | relation between the pressure, volume, amount, and temperature of a gas under conditions derived by combination of the simple gas laws | | | | |
kinetic molecular theory | theory based on simple principles and assumptions that effectively explains ideal gas behavior | | | | |
manometer | device used to measure the pressure of a gas trapped in a container | | | | |
mean free path | average distance a molecule travels between collisions | | | | |
mole fraction (X) | concentration unit defined as the ratio of the molar amount of a mixture component to the total number of moles of all mixture components | | | | |
partial pressure | pressure exerted by an individual gas in a mixture | | | | |
pascal (Pa) | SI unit of pressure; 1 Pa = 1 N/m2 | | | | |
pounds per square inch (psi) | unit of pressure common in the US | | | | |
pressure | force exerted per unit area | | | | |
rate of diffusion | amount of gas diffusing through a given area over a given time | | | | |
root mean square speed (urms) | measure of average speed for a group of particles calculated as the square root of the average squared speed | | | | |
standard conditions of temperature and pressure (STP) | 273.15 K (0 °C) and 1 atm (101.325 kPa) | | | | |
standard molar volume | volume of 1 mole of gas at STP, approximately 22.4 L for gases behaving ideally | | | | |
torr | unit of pressure; | | | | |
van der Waals equation | modified version of the ideal gas equation containing additional terms to account for non-ideal gas behavior | | | | |
vapor pressure of water | pressure exerted by water vapor in equilibrium with liquid water in a closed container at a specific temperature | | | | |