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5.9: Acids

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    289379
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    A spot test for gold has been in use for decades. The sample is first treated with nitric acid. Other metals may react or dissolve in this acid, but gold will not. Then the sample is added to a mixture of nitric acid and hydrochloric acid. Gold will only dissolve in this mixture. The term "acid test" arose from the California gold rush in the late 1840's when this combination was used to test for the presence of real gold. It has since come to mean "tested and approved" in a number of fields.
     

    Acids

    An acid can be defined in several ways. The most straightforward definition is that an acid is a molecular compound that contains one or more hydrogen atoms and produces hydrogen ions (H+) when dissolved in water.
     

    Bottles of vinegar at a supermarket
                     
    Citrus paradisi (Grapefruit, pink) white bg

    Figure \(\PageIndex{1}\): (A) Vinegar comes in a variety of types, but all contain acetic acid. (B) Citrus fruits like grapefruit contain citric and ascorbic acids.


    This is a different type of compound than the others we have seen thus far. Acids are molecular, which means that in their pure state they are individual molecules and do not adopt the extended three-dimensional structures of ionic compounds like NaCl. However, when these molecules are dissolved in water, the chemical bond between the hydrogen atom and the rest of the molecule breaks, leaving a positively-charged hydrogen ion and an anion. This can be symbolized in a chemical equation:

    \[\ce{HCl} \rightarrow \ce{H^+} + \ce{Cl^-}\]

    Since acids produce H+ cations upon dissolving in water, the H of an acid is written first in the formula. The remainder of the acid (other than the H) is the anion after the acid dissolves. 
     

    Binary Acids

    The name of an acid is based on the other elements with which it is combined. A binary acid is an acid that consists of hydrogen combined with one other element. The most common binary acids contain a halogen. The convention for naming binary acids is

    hydro- + root name of the other element + -ic acid

    In other words, the acid name begins with the prefix hydro-, followed immediately by the root name of the other element, which is then followed by the suffix -ic acid. It should also be noted that binary acids are only assigned their acid name when they are dissolved in water, which we designate with a phase label of (aq), which stands for aqueous (pronounced AY-quee-us).

    Therefore, the name of HCl (aq) is hydrochloric acid, since the root name of chlorine is chlor- and we are showing that the HCl is dissolved in water. As a gas, HCl (g) is called hydrogen chloride. While this distinction is important, the phase label is usually left off and the correct name is usually based on the context in which it is used. In the absence of a phase label, one is usually safe to assume that a binary acid is named as an acid, in which the hydro- prefix and -ic acid suffix are used.

    When writing the formula of an acid, the formula of a hydrogen ion, H+, is combined with the formula and charge of the nonmetal anion in the acid. To write the formula of hydroiodic acid, H+ would be combined with I, since iodine is located in Group VIIA of the periodic table (see Figure 5.5.1). The charges H+ and I are already balanced, so the formula of hydroiodic acid is HI (aq). The formula could also be simply written as HI, since we know the context in which it was used (as an acid, according to its name).
     

    ✅ Example \(\PageIndex{1}\): Binary Acids

    If the chemical formula is provided, write the name. If the name is provided, write the formula.

    1. HF (aq)
    2. hydrosulfuric acid

    Solution

    1. Since there are just two elements and the first element in the formula is H, this a binary acid. Binary acids have a hydro- prefix and an -ic acid suffix. The root name of fluorine is fluor-. HF (aq) is hydrofluoric acid.
           
    2. The name has a hydro- prefix and an -ic acid suffix, making it a binary acid. H+ would be combined with S2–. The charge on sulfide is 2– based on its position (Group VIA) on the periodic table. Charge is balanced with two H+ for every one S2–. Hydrosulfuric acid is H2S (aq) or simply H2S.


    Oxyacids

    An acid always contains the element hydrogen and the H is always written at the front of the chemical formula. An oxyacid is an acid that also contains the element oxygen, along with a third (and occasionally fourth) element. The third element is almost always a nonmetal. Oxyacids may also be thought of as a compound where H+ has combined with an oxyanion. As we recall, the most common oxyanions end with an -ate suffix, while other oxyanions end with an -ite suffix.

    The convention for naming oxyacids:

    • Identify and name the oxyanion present in the acid.
    • If the oxyanion name ends with -ate, drop the -ate suffix from the anion name and replace with an -ic acid suffix.
    • If the oxyanion name ends with -ite, drop the -ite suffix from the anion name and replace with an -ous acid suffix. 
       

    ✅ Example \(\PageIndex{2}\): Naming Oxyacids

    Write the name for each acid.

    1. HNO3
    2. HNO2
       

    Solution

      HNO3 HNO2
    1. Identify the oxyanion present in the acid.
    NO3 NO2
    1. Name the oxyanion.
    nitrate nitrite
    1. Drop -ate or -ite from the anion name.
    nitr- nitr-
    1. Replace -ate with -ic acid.
      Replace -ite with -ous acid.
    nitric acid nitrous acid
     

     

    ✅ Example \(\PageIndex{3}\): Writing Formulas for Oxyacids

    Write the chemical formula for each acid.

    1. chlorous acid
    2. chloric acid
       

    Solution

    The process of arriving at a name now needs to be reversed.

      chlorous acid chloric acid
    1. Identify suffix as -ic acid or -ous acid.
    chlorous acid chloric acid
    1. Replace -ic acid with -ate.
      Replace -ous acid with -ite.
    chlorite chlorate
    1. Since it is an acid, combine H+ with the formula of the oxyanion.
    H+ with ClO2 H+ with ClO3
    1. Balance charges.
    one H+ balances one ClO2 one H+ balances one ClO3
    1. Write the final formula. Charges are left off. 
    HClO2 HClO3
     

     

    ⚡️ Sulfur and Phosphorus

    When sulfur or phosphorus are present in acids, their root names are different than when they are present in anions. Everything else about naming acids that contain sulfur or phosphorus remains the same.

    Element Root Name in Anions Root Name in Acids
    sulfur sulf- sulfur-
    phosphorus phosph- phosphor-

     

     

    ✅ Example \(\PageIndex{4}\): Naming Oxyacids

    Write the name for H2SO4.

    Solution

      H2SO4
    1. Identify the oxyanion present in the acid.
    SO42
    1. Name the oxyanion.
    sulfate
    1. Drop -ate or -ite from the anion name.
    sulf-
    1. Replace -ate with -ic acid.
      Replace -ite with -ous acid.
      Sulfur has a root name of sulfur- in acids.
    sulfuric acid
     

     

    ✏️ Exercise \(\PageIndex{1}\)

    If the chemical formula is provided, write the name. If the name is provided, write the formula.

    1. sulfurous acid
    2. HBr (aq)
    3. acetic acid
    4. H2CO3
    Answer A
    H2SO3
    Answer B
    hydrobromic acid
    Answer C
    HC2H3O2
    Answer D
    carbonic acid


    Summary

    • Acids are molecular compounds that release hydrogen ions.
    • A binary acid consists of hydrogen and one other element.
    • Oxyacids contain hydrogen, oxygen, and at least one other element.
    • The name of the acid is based on the anion attached to the hydrogen.
       

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