2: Unit 2
- Page ID
- 492124
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)- 2.1: In Your Room
- Matter is any substance that has mass and takes up space. Matter includes atoms and anything made of atoms, but not other energy phenomena or waves such as light or sound. While this simple definition is easily applied, the way people view matter is often broken down into two characteristic length scales: the macroscopic and the microscopic.
- 2.2: What is Matter?
- Matter is anything that has mass and volume (takes up space). For most common objects that we deal with every day, it is fairly simple to demonstrate that they have mass and take up space. You might be able to imagine, however, the difficulty for people several hundred years ago to demonstrate that air has mass and volume. Air (and all other gases) are invisible to the eye, have very small masses compared to equal amounts of solids and liquids, and are quite easy to compress (change volume).
- 2.3: Classifying Matter According to Its State—Solid, Liquid, and Gas
- Three states of matter exist—solid, liquid, and gas. Solids have a definite shape and volume. Liquids have a definite volume, but take the shape of the container. Gases have no definite shape or volume.
- 2.4: Classifying Matter According to Its Composition
- One useful way of organizing our understanding of matter is to think of a hierarchy that extends down from the most general and complex, to the simplest and most fundamental. Matter can be classified into two broad categories: pure substances and mixtures. A pure substance is a form of matter that has a consistent composition and properties that are constant throughout the sample. A material composed of two or more substances is a mixture.
- 2.5: Differences in Matter- Physical and Chemical Properties
- A physical property is a characteristic of a substance that can be observed or measured without changing the identity of the substance. Physical properties include color, density, hardness, melting points, and boiling points. A chemical property describes the ability of a substance to undergo a specific chemical change.
- 2.6: Changes in Matter - Physical and Chemical Changes
- Change is happening all around us all of the time. Just as chemists have classified elements and compounds, they have also classified types of changes. Changes are either classified as physical or chemical changes. Chemists learn a lot about the nature of matter by studying the changes that matter can undergo. Chemists make a distinction between two different types of changes that they study—physical changes and chemical changes.
- 2.7: Conservation of Mass - There is No New Matter
- The law of conservation of mass states that matter can not be created or destroyed in a chemical reaction. So the mass of the product equals the mass of the reactant. The reactant is the chemical interaction of two or more elements to make a new substance, and the product is the substance that is formed as the result of a chemical reaction. Matter and its corresponding mass may not be able to be created or destroyed, but can change forms to other substances like liquids, gases, and solids.
- 2.8: Cutting Aluminum until you get Atoms
- Take some aluminum foil. Cut it in half. Now you have two smaller pieces of aluminum foil. Cut one of the pieces in half again. Cut one of those smaller pieces in half again. Continue cutting, making smaller and smaller pieces of aluminum foil.
- 2.9: Indivisible - The Atomic Theory
- You learned earlier how all matter in the universe is made out of tiny building blocks called atoms. All modern scientists accept the concept of the atom, but when the concept of the atom was first proposed about 2,500 years ago, ancient philosophers laughed at the idea. It has always been difficult to convince people of the existence of things that are too small to see. We will spend some time considering the evidence (observations) that convince scientists of the existence of atoms.
- 2.10: The Nuclear Atom
- While Dalton's Atomic Theory held up well, J. J. Thomson demonstrate that his theory was not the entire story. He suggested that the small, negatively charged particles making up the cathode ray were actually pieces of atoms. He called these pieces "corpuscles," although today we know them as electrons. Thanks to his clever experiments and careful reasoning, J. J. Thomson is credited with the discovery of the electron.
- 2.11: The Properties of Protons, Neutrons, and Electrons
- Electrons are extremely small. The mass of an electron is only about 1/2000 the mass of a proton or neutron, so electrons contribute virtually nothing to the total mass of an atom. Electrons have an electric charge of −1, which is equal but opposite to the charge of a proton, which is +1. All atoms have the same number of electrons as protons, so the positive and negative charges "cancel out", making atoms electrically neutral.
- 2.12: Elements- Defined by Their Number of Protons
- Scientists distinguish between different elements by counting the number of protons in the nucleus. Since an atom of one element can be distinguished from an atom of another element by the number of protons in its nucleus, scientists are always interested in this number, and how this number differs between different elements. The number of protons in an atom is called its atomic number (Z). This number is very important because it is unique for atoms of a given element.
- 2.13: Looking for Patterns - The Periodic Table
- Certain elemental properties become apparent in a survey of the periodic table as a whole. Every element can be classified as either a metal, a nonmetal, or a metalloid (or semi metal). A metal is a substance that is shiny, typically (but not always) silvery in color, and an excellent conductor of electricity and heat. Metals are also malleable (they can be beaten into thin sheets) and ductile (they can be drawn into thin wires).
- 2.14: Ions - Losing and Gaining Electrons
- Atom may lose valence electrons to obtain a lower shell that contains an octet. Atoms that lose electrons acquire a positive charge as a result. Some atoms have nearly eight electrons in their valence shell, and can gain additional valence electrons until they have an octet. When these atoms gain electrons, they acquire a negative charge.
- 2.15: Isotopes - When the Number of Neutrons Varies
- All atoms of the same element have the same number of protons, but some may have different numbers of neutrons. For example, all carbon atoms have six protons, and most have six neutrons as well. But some carbon atoms have seven or eight neutrons instead of the usual six. Atoms of the same element that differ in their numbers of neutrons are called isotopes. Many isotopes occur naturally.
- 2.16: Atomic Mass - The Average Mass of an Element’s Atoms
- In chemistry, we very rarely deal with only one isotope of an element. We use a mixture of the isotopes of an element in chemical reactions and other aspects of chemistry, because all of the isotopes of an element react in the same manner. That means that we rarely need to worry about the mass of a specific isotope, but instead need to know the average mass of the atoms of an element.
- 2.17: Sugar and Salt
- Both salt and sugar have radically different properties (both physical and chemical) than the constituent elements that make up these compounds. This difference in properties, of constituent elements and compounds, is a central feature of chemical reactions.
- 2.18: Compounds Display Constant Composition
- A compound is a substance that contains two or more elements chemically combined in a fixed proportion. The elements carbon and hydrogen combine to form many different compounds. One of the simplest is called methane, in which there are always four times as many hydrogen particles as carbon particles. Methane is a pure substance because it always has the same composition. However, it is not an element because it can be broken down into simpler substances—carbon and hydrogen.
- 2.19: Chemical Formulas - How to Represent Compounds
- A chemical formula is an expression that shows the elements in a compound and the relative proportions of those elements. A molecular formula is a chemical formula of a molecular compound that shows the kinds and numbers of atoms present in a molecule of the compound. An empirical formula is a formula that shows the elements in a compound in their lowest whole-number ratio.
- 2.20: A Molecular View of Elements and Compounds
- Most elements exist with individual atoms as their basic unit. It is assumed that there is only one atom in a formula if there is no numerical subscript on the right side of an element’s symbol. There are many substances that exist as two or more atoms connected together so strongly that they behave as a single particle. These multi-atom combinations are called molecules. A molecule is the smallest part of a substance that has the physical and chemical properties of that substance.
- 2.21: Writing Formulas for Ionic Compounds
- Formulas for ionic compounds contain the symbols and number of each atom present in a compound in the lowest whole number ratio.
- 2.22: Nomenclature- Naming Compounds
- The primary function of chemical nomenclature is to ensure that a spoken or written chemical name leaves no ambiguity concerning which chemical compound the name refers to—each chemical name should refer to a single substance. A less important aim is to ensure that each substance has a single name, although a limited number of alternative names is acceptable in some cases. Preferably, the name also conveys some information about the structure or chemistry of a compound.
- 2.23: Naming Ionic Compounds
- Ionic compounds are named by stating the cation first, followed by the anion. Positive and negative charges must balance. Some anions have multiple forms and are named accordingly with the use of roman numerals in parentheses. Ternary compounds are composed of three or more elements.
- 2.24: Naming Molecular Compounds
- Molecular compounds are inorganic compounds that take the form of discrete molecules. Examples include such familiar substances as water and carbon dioxide. These compounds are very different from ionic compounds like sodium chloride. Ionic compounds are formed when metal atoms lose one or more of their electrons to nonmetal atoms. The resulting cations and anions are electrostatically attracted to each other.
- 2.25: Naming Acids
- An acid can be defined in several ways. The most straightforward definition is: an acid is a molecular compound that contains one or more hydrogen atoms and produces hydrogen ions when dissolved in water.
- 2.26: Nomenclature Summary
- Brief overview of chemical nomenclature.