Skip to main content
Chemistry LibreTexts

Noncrystallographic symmetry

  • Page ID
    17417
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    A symmetry operation that is not compatible with the periodicity of a crystal pattern (in two or three dimensions) is called a noncrystallographic symmetry. Rotations other than 1, 2, 3, 4, and 6 (in E2 and E3) belong to this type of symmetry. Rotations 5, 8, 10 and 12 are compatible with a translation in higher-dimensional spaces, but they are commonly considered noncrystallographic. For example、in quasicrystals fivefold or tenfold rotational axes are incapable of tiling space through the application of three-dimensional lattice translations, but they act as normal symmetry axes in a higher-dimensional space. Continuous rotations, which give rise to the Curie groups contained in the cylindrical system and in the spherical system, are noncrystallographic in any dimension.


    Noncrystallographic symmetry is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Online Dictionary of Crystallography.