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Chemistry LibreTexts

9.2: Physical Observables

  • Page ID
    5218
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    Physical observables are represented by linear, hermitian operators that act on the vectors of the Hilbert space. If \(A\) is such an operator, and \(\vert\phi\rangle\) is an arbitrary vector in the Hilbert space, then \(A\) might act on \(\vert\phi\rangle\) to produce a vector \(\vert\phi ' \rangle\), which we express as

    \[A\vert\phi\rangle = \vert\phi'\rangle \nonumber \]

    Since \(\vert\phi\rangle\) is representable as a column vector, \(A\) is representable as a matrix with components

    \[A = \left(\matrix{A_{11} & A_{12} & A_{13} & \cdots \cr A_{21} & A_{22} & A_{23} & \cdots \cr\cdot & \cdot & \cdot & \cdots }\right) \nonumber \]

    The condition that \(A\) must be hermitian means that

    \[A^{\dagger} = A \nonumber \]

    or

    \[A_{ij} = A_{ji}^* \nonumber \]


    This page titled 9.2: Physical Observables is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Mark Tuckerman.

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