This page looks at the mechanism for the acid catalysed dehydration of a simple primary alcohol like ethanol to give an alkene like ethene.
The dehydration of ethanol
Ethanol can be dehydrated to give ethene by heating it with an excess of concentrated sulphuric acid at about 170°C.
Concentrated phosphoric(V) acid, H3PO4, can be used instead.
The acids aren't written into the equation because they serve as catalysts. If you like, you could write, for example, "conc H2SO4" over the top of the arrow.
You will find two versions of the mechanism for the dehydration of primary alcohols on the web and in various textbooks.
One of these is exactly the same as the mechanism for the reaction involving propan-2-ol and other secondary or tertiary alcohols (known technically as an E1 mechanism), but the other is different (known as an E2 mechanism).
The more reliable sources give the E2 mechanism for the dehydration of primary alcohols including ethanol. I am going to treat this as the "correct" version.
The correct version in full
If you have read the page on the dehydration of propan-2-ol, you will know that it involves the formation of a carbocation (a carbonium ion).
If ethanol used the same mechanism, you would get a primary carbocation formed, CH3CH2+, but this is much less stable than a secondary or tertiary carbocation.
That would lead to a very high activation energy for the reaction.
The alternative mechanism avoids the formation of the carbocation, and so avoids the high activation energy.
We are going to discuss the mechanism using sulphuric acid.
In the first stage, one of the lone pairs of electrons on the oxygen picks up a hydrogen ion from the sulphuric acid. The alcohol is said to be protonated. That is exactly the same as happens with propan-2-ol and the other secondary and tertiary alcohols.
In the mechanism we have already looked at with propan-2-ol, the next thing to happen was loss of water to form a carbocation, followed by removal of a hydrogen ion from the carbocation and the formation of a double bond.
In this case, instead of happening in two separate steps, this all happens at the same time in one smooth operation. By doing that, you avoid the formation of an unstable primary carbocation.
No simplified version of this!
I am not giving a simplified version of this mechanism just in terms of hydrogen ions. If you don't show something removing the hydrogen ion from the protonated alcohol, you are really missing an important feature of the reaction.
The other mechanism that you might come across
This is the mechanism that looks justs like the one involving propan-2-ol, and involves the formation of an unstable primary carbocation.
This is the version that you would have found on Chemguide up to December 2012, and was originally included because it was the one wanted by one of the UK Exam Boards at the time I wrote the page in 2000.
It is possible that your examiners may still want it. As far as I am aware, the only syllabus which I track which still asks this topic is IB, and one of their mark schemes gave the version below. If you need to know about this, you need to check what your examiners are currently expecting.