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4.8 Infrared Spectroscopy Problems

  • Page ID
    432185
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    Learning Objectives

    After completing this section, you should be able to

    • determine functional groups in an IR spectrum

    Here are some problems for IR analysis. 

    Exercise \(\PageIndex{1}\)

    What functional group is present in the spectrum below? 

    clipboard_e510210f9e24dbe40e9f97c8f13ae8777.png

    Answer

    Alkyne

    Exercise \(\PageIndex{2}\)

    What functional group is present in the spectrum below? 

    clipboard_ec984425219fcc9e8c55050d63ee8bbf5.png

    Answer

    Carboxylic Acid

     
    Exercise \(\PageIndex{3}\)

    Which IR spectrum goes with which molecule below?

    Molecule A: unknownIR.svg

    Molecule B: carvone.svg

    IR spectrum 1: 

    clipboard_ec26fb7b5b5fc44623f95979d7f59ded7.png

    IR spectrum 2: 

    clipboard_ec5047387a92f30c64c8563e19588bdfe.png

    Answer

    Molecule A is Spectrum 2. 

    Molecule B is Spectrum 1. 

    Exercise \(\PageIndex{4}\)

    What notable peaks in the IR spectrum verify that benzaldehyde is present? 

    benzaldehyde.svg

    clipboard_e607a3370595d5a6c4331f169539569c7.png

    Answer
    Frequency (cm-1) Functional Group
    3063 Csp2-H
    2818 and 2736 aldehyldic proton
    1695 C=O
    1653-1455 aromatic ring

     

     


    4.8 Infrared Spectroscopy Problems is shared under a not declared license and was authored, remixed, and/or curated by Lauren Reutenauer.

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