Table of Contents Last updated Save as PDF Page ID204640 Atoms, Compounds, Molecules, Intermolecular Attractions, Structure-Property RelationshipsAcknowledgements1: Introduction to Atoms1.1: From Democritus to the 19th Century- Historical Developments in Chemistry1.2: Old Quantum Mechanics- Basic Developments1.3: New Quantum Mechanics1.4: Quantum Numbers1.5: The Aufbau Process1.6: The Periodic Table and Periodic Trends1.7: Atoms- Solutions to Selected Problems2: Metals2.1: Introduction to Metals2.2: A Layer of Metal Atoms2.3: Building Metal Atoms in Three Dimensions2.4: Application Problems with Metals2.5: Metals- Solutions to Selected Problems3: Ionic Compounds3.1: Ionic Atoms3.2: Counterions3.3: Physical Properties3.4: Solubility3.5: Structures of Ionic Solids3.6: Application Problems3.7: Naming Ionic Compounds3.8: Ionic Compounds- Solutions for Selected Problems4: Introduction to Molecules4.1: Why do Molecules Matter?4.2: Lewis Structures4.3: Lewis Structures and Multiple Bonding4.4: Lewis Structures and Polyatomic Molecules4.5: Lewis and Formal Charge4.6: The Need for Resonance Structures4.7: Which Bonds are Ionic and Which are Covalent?4.8: Line Drawings4.9: Three Dimensional Drawings4.10: Other Geometries4.11: Controversial Lewis Structures4.12: Organic Functional Groups4.13: Common Biomolecules4.14: Drawings for Large Biological Compounds4.15: Application Problems4.16: Solutions to Selected Problems5: Stereochemistry5.1: Introduction5.2: Stereoisomers5.3: Stereochemistry - Extra Problems.5.4: Enantiomers5.5: Simple Organic Enantiomers- R and S configurations5.6: Biological Small Molecules5.7: Optical Rotation5.8: The Polarimetry Experiment5.9: Carbohydrates and Diastereomers5.10: Diastereomers and Physical Properties5.11: Carbohydrates in Cyclic Form5.12: Biological Building Blocks- Amino Acids5.13: Macromolecular Structures- Alpha-Helices5.14: Optical Resolution5.15: Another Kind of Stereochemistry- Alkene Isomers5.16: E and Z Alkene Isomers5.17: Stereoisomers in Other Geometries- Octahedra5.18: Enantiomers in Octahedral Complexes5.19: Chiral Catalysts for Production of Enantiomerically Pure Compounds5.20: Solutions to Selected Problems5.21: Biological Building Blocks- Carbohydrates6: Conformational Analysis6.1: Introduction to Conformation6.2: Simple Molecules6.3: Conformation of Butane6.4: The Basis Set6.5: Molecular Modeling6.6: Cyclic System6.7: Cyclohexane6.8: Diamond Lattice Drawings6.9: Substituted Cyclohexanes6.10: Disubstituted Cyclohexanes6.11: Other Rings6.12: Rings with Heteroatoms6.13: More Practice with Conformation6.14: Application Problems6.15: Solutions to Selected Problems7: Structure-Property Relationships7.1: The Properties of Water7.2: Changes of State7.3: Kinetic-molecular Theory7.4: London Interactions7.5: Dipole Interactions7.6: Hydrogen Bonding7.7: Ionic Attractions7.8: Comparing Properties of Isomers7.9: Miscibility7.10: Solubility7.11: Hydrogen Bond Acceptors7.12: Heterogenous Mixtures7.13: Intermolecular Attractions and Protein Structure7.14: Application Problems7.15: Solutions to Selected Problems8: Introduction to Biomolecules8.1: Lipids8.2: Proteins8.3: Nucleic Acids8.4: Carbohydrates8.5: Biomolecule Application Problems9: Cell Tutorial9.1: The Cell- An Overview9.2: The Cell- Lipids9.3: The Cell - Proteins9.4: The Cell- Nucleic Acids9.5: The Cell- Carbohydrates10: Network Solids10.1: A Network Solid - Diamond10.2: Other Forms of Carbon10.3: Silicates and Silica10.4: Aluminosilicates10.5: Solutions to Selected Problems11: Transition Metal Complexes11.1: Introduction11.2: Building Blocks- Metal Ions and Ligands in Transition Metal Complexes11.3: Electron Counting11.4: Chelation11.5: Isomers11.6: Naming Transition Metal Complexes11.7: Geometry in Transition Metal Complexes11.8: Solutions for Selected Problems12: Macromolecules and Supramolecular Assemblies12.1: What are Macromolecules?12.2: Viscosity12.3: Glass Transition12.4: Polymer Architecture12.5: Morphology and Microphase Separation12.6: Polymer Synthesis12.7: Molecular Weight12.8: Supramolecular Assemblies12.9: Solutions for Selected Problems13: Molecular Orbital Theory13.1: Introductions13.2: Wave Behavior and Bonding in the Hydrogren Molecule13.3: Molecular Orbitals- Lessons from Dihydrogen13.4: Sigma Bonding with p Orbitals13.5: Pi Bonding with p Orbitals13.6: Assembling the Complete Diagram and Electron Population13.7: Experimental Evidence for Molecular Orbital Results13.8: Symmetry and Mixing13.9: When Different Atoms Bond Together13.10: Another Complication in HF- Orbital Mixing13.11: Geometry and Orbital Contribution to Bonding13.12: Approximations in More Complicated Structures13.13: Building a Molecule from Pieces13.14: Delocalization13.15: Polyenes13.16: Delocalization in Aromatics13.17: Heteroaromatics13.18: Frontier Orbitals13.19: Solutions to Selected Problems14: Concepts of Acidity14.1: General Acidity and Basicity14.2: Lewis Bases14.3: Lewis Acids14.4: Lewis Acid-Base Complexes and Molecular Orbitals14.5: Reversibility of the Dative Bond14.6: Coordination Complexes14.7: Proton as a Common Lewis Acid14.8: Proton Transfer from One Basic Site to Another and Molecular Orbital Interactions in Proton Transfers14.9: Proton Donor Strength- pKa14.10: The Relationship Between Structure and Bronsted-Lowry Acidity14.11: Factors Affecting Bronsted-Lowry Acidity- Local Factors14.12: Factors affecting Bronsted-Lowry Acidity- Distal Factors14.13: Effects on Basicity (Attraction for Proton)14.14: The Direction of Proton Transfer14.15: Amino Acids and Peptides14.16: Relative Conditions and pKa14.17: The Meaning of pKa- Product-to-Reactant Ratio and Equilibrium Constant14.18: pH and Buffers14.19: Application Problems14.20: Solutions to Selected ProblemsBack MatterIndexGlossary
